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Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi

Yıl 2013, Cilt: 28 Sayı: 3, 0 - , 03.03.2014

Ayhan Özçifçi Günay Özbay

Öz

Bu çalışmada, sarıçam (Pinus sylvestris L.) odun talaşı biyokütle kaynağı olarak değerlendirilmiş, sabit yataklı reaktörde, katalizörlü ve katalizörsüz (termal) pirolizi gerçekleştirilmiştir. Deneylerde piroliz ürünlerinin verimleri üzerine sıcaklık ve katalizör tipi gibi parametrelerin etkisi araştırılmıştır. 0,850-1,60 mm parçacık
boyutundaki deney örneklerinin pirolizi; 400, 500 ve 600 °C sıcaklıklarda, 5 °C/min ısıtma hızında ve 30 ml/min sürükleyici azot gazı (N2) akış hızında gerçekleştirilmiştir. Katalizör olarak Na2CO3 ve K2CO3 bazik tuzları ile FeCl3 Lewis asidi kullanılmıştır. Sonuç olarak, sıcaklık ve katalizör tipinin katı, sıvı ve gaz ürün verimlerinde etkili parametreler olduğu belirlenmiştir. Ayrıca odun talaşlarından katalitik piroliz yöntemi ile elde edilen sıvı ürünlerin biyoyakıt veya değerli kimyasal madde olarak kullanılabileceği tespit edilmiştir.

Anahtar Kelimeler

Biyokütle biyoyakıt sarıçam (Pinus sylvestris L.) piroliz

Kaynakça

  • Calkins, M., “Materials for sustainable sites”, John
  • Wiley & Sons Inc., Hoboken, New Jersey, 14-24,
  • -
  • Inderwildi, O. R. and King, D. A., “Quo vadis
  • biofuels?”, Energy & Environmental Science, 2
  • (4): 343-346 ,2009.
  • Kantarelis, E. and Zabaniotou, A., “Valorization of
  • cotton stalks by fast pyrolysis and fixed bed air
  • gasification for syngas production as precursor of
  • second generation biofuels and sustainable
  • agriculture”, Bioresource Technology, 100 (2):
  • -947, 2009.
  • Qi, W. Y, Hu, C. W., Li, G. Y., Guo, L. H., Yang,
  • Y., Luo, J., Miao, X. and Du, Y., “Catalytic
  • pyrolysis of several kinds of bamboos over zeolite
  • NaY”, Green Chemistry, 8 (2): 183-190, 2006.
  • Wang, C., Du, Z., Pan, J., Li, J. and Yang, Z.,
  • “Direct conversion of biomass to bio-petroleum at low temperature”, Journal of Analytical and
  • Applied Pyrolysis, 78 (2): 438-444, 2007.
  • Tsai, W. T., Lee, M. K. and Chang, Y. M., “Fast
  • pyrolysis of rice husk: Product yields and
  • compositions”, Bioresource Technology, 98 (1):
  • -28, 2007.
  • Basu, P., “Biomass gasification and pyrolysis
  • practical design and theory”, Academic Press is an
  • imprint of Elsevier, USA, 75-78, 2010.
  • Nilsen, M. H., Antonakou, E., Bouzga, A.,
  • Lappas, A., Mathisen, K. and Stöcker, M.,
  • “Investigation of the effect of metal sites in Me-Al-
  • MCM-41 (Me=Fe, Cu or Zn) on the catalytic
  • behavior during the pyrolysis of wooden based
  • biomass”, Microporous and Mesoporous
  • Materials, 105 (1-2): 189-203, 2007.
  • Nakai, T., Kartal, S. N., Hata, T. and Imamura, Y.,
  • “Chemical characterization of pyrolysis liquids of
  • wood-based composites and evaluation of their
  • bio-efficiency”, Building and Environment, 42
  • (3): 1236-1241, 2007.
  • Şensöz, S., Angın, D. ve Demiral, İ., “Kızılçam
  • odun kabuğunun pirolizi ve ürünlerinin
  • incelenmesi”, Yenilebilir Enerji Kaynakları
  • Sempozyumu, İzmir, 147-151, 2001.
  • Gerçel, H. F., “Bio-oil production from
  • Onopordum acanthium L. by slow pyrolysis”,
  • Journal of Analytical and Applied Pyrolysis, 92
  • (1): 233-238, 2011.
  • Heo, S. H., Park, H. J., Park, Y.-K., Ryu, C., Suh,
  • D. J., Suh, Y.-W., Yim, J.-H. and Kim, S.-S.,
  • “Bio-oil production from fast pyrolysis of waste
  • furniture sawdust in a fluidized bed”,
  • Bioresource Technology, 101 (1): 91-96, 2010.
  • American Society for Testing and Materials,
  • “Standard test method for direct moisture content
  • measurement of wood and wood-base materials”,
  • ASTM Standards D 4442-92, Easton, M. D.,
  • USA, 1997.
  • American Society for Testing and Materials,
  • “Standard test method for volatile matter in
  • analysis sample refuse derived fuel”, ASTM
  • Standards E-897-88, Easton, M. D., USA, 2004.
  • American Society for Testing and Materials,
  • “Standard test method for ash in wood”, ASTM
  • Standards D-1102-84, Easton, M. D., USA,
  • -
  • Rowell, R. M., Pettersen, R., Han, J. S., Rowell, J.
  • S. and Tshabalala, M. A., “Handbook of wood
  • chemistry and wood composites”, CRC Press,
  • , 2005.
  • Wise, L. E. and John, E. C., “Wood chemistry”,
  • Reinhold Publication Co, New York, U.S.A., 1-
  • : 1330, 1952.
  • Technical Association of the Pulp and Paper
  • Industry, “Acid-insoluble lignin in wood and
  • pulp”, TAPPI T 222 om-02, Tappi Pres, Atlanta,
  • GA, U.S.A., 2002.
  • Technical Association of the Pulp and Paper
  • Industry, “Solvent extractives of wood and pulp”, TAPPI T 204 cm-97, Tappi Pres, Atlanta, GA,
  • USA, 1997.
  • Wang, Z., Cao, J. and Wang, J., “Pyrolytic
  • characteristics of pine wood in a slowly heating
  • and gas sweeping fixed-bed reactor”, Journal of
  • Analytical and Applied Pyrolysis, 84 (2): 179-
  • , 2009.
  • Fagbemi, L., Khezami, L. and Capart, R.,
  • “Pyrolysis products from different biomasses:
  • Application to the thermal cracking of tar”,
  • Applied Energy, 69 (4): 293-306, 2001.
  • Liaw, S.-S., Wang, Z., Ndegwa, P., Frear, C., Ha,
  • S., Li, C.-Z. and Garcia-Perez, M., “Effect of
  • pyrolysis temperature on the yield and properties
  • of bio-oils obtained from the auger pyrolysis of
  • Douglas Fir Wood”, Journal of Analytical and
  • Applied Pyrolysis, 93: 52-62, 2012.
  • Erşen, T. ve Pehlivan, D., “Yüksek yoğunluklu
  • polietilen–odun karışımlarının birlikte pirolizi”, J.
  • Fac. Eng. Arch. Gazi Univ., 26, (3): 607-612,
  • -
  • Aho, A., Kumar, N., Eränen, K., Salmi, T., Hupa,
  • M. and Murzin, D. Y., “Catalytic pyrolysis of
  • woody biomass in a fluidized bed reactor:
  • Influence of the zeolite structure”, Fuel, 87 (12):
  • -2501, 2008.
  • Zhong, C. and Wei, X., “A comparative
  • experimental study on the liquefaction of wood”,
  • Energy, 29 (11): 1731-1741, 2004.
  • Savage, P. E., Levine, R. B., and Huelsman, C.
  • M.,“Hydrothermal processing of biomass”,
  • Thermochemical Conversion of Biomass to Liquid
  • Fuels and Chemicals, Edited by Mark Crocker,
  • The Royal Society of Chemistry, Cambridge,
  • UK., 1: 192-220, 2010.
  • Qi, Z., Jie, C., Tiejun, W. and Ying, X., “Review
  • of biomass pyrolysis oil properties and upgrading research”, Energy Conversion and
  • Management, 48 (1): 87-92, 2007.
  • Branca, C., Giudicianni, P. and Di Blasi, C., “GCMS
  • characterization of liquid generated from lowtemperature
  • pyrolysis of wood”, Industrial &
  • Engineering Chemistry Research, 42 (14):
  • -3202, 2003.
  • Ingemarsson, A., Nilsson, U., Nilsson, M.,
  • Pedersen, J. R. and Olsson, J. O., “Slow pyrolysis
  • of spruce and pine samples studied with GC/MS
  • and GC/FTIR/FID”, Chemosphere, 36 (14):
  • -2889, 1998.
  • Zeitsch, K. J. “Applications of Furfural”, The
  • chemistry and technology of furfural and its many
  • by-products, Elsevier publication, Netherlands,
  • -103, 2000.
  • Lu, Q., Wang, Z., Dong, C., Zhang, Z., Zhang, Y.,
  • Yang, Y. and Zhu, X., “Selective fast pyrolysis of
  • biomass impregnated with ZnCl2: Furfural
  • production together with acetic acid and activated
  • carbon as by-products”, Journal of Analytical
  • and Applied Pyrolysis, 91 (1): 273-279, 2011.
  • Colombini, M. P., Orlandi, M., Modugno, F.,
  • Tolppa, E.-L., Sardelli, M., Zoia, L. and Crestini,
  • C., “Archaeological wood characterisation by
  • PY/GC/MS, GC/MS, NMR and GPC techniques”,
  • Microchemical Journal, 85 (1): 164-173, 2007.
  • Özbay, G., “Odun ve Odun Esaslı Kompozit
  • Malzeme Talaşlarının Termal ve Katalitik Piroliz
  • Yöntemi ile Sıvılaştırılması”, Doktora Tezi,
  • Karabük Üniversitesi Fen Bilimleri Enstitüsü,
  • Karabük, 89-95, 2012.
  • López, D., Acelas, N. and Mondragón, F.,
  • “Average structural analysis of tar obtained from
  • pyrolysis of wood”, Bioresource Technology,
  • (7): 2458-2465, 2010.

Yıl 2013, Cilt: 28 Sayı: 3, 0 - , 03.03.2014

Ayhan Özçifçi Günay Özbay

Öz

Kaynakça

  • Calkins, M., “Materials for sustainable sites”, John
  • Wiley & Sons Inc., Hoboken, New Jersey, 14-24,
  • -
  • Inderwildi, O. R. and King, D. A., “Quo vadis
  • biofuels?”, Energy & Environmental Science, 2
  • (4): 343-346 ,2009.
  • Kantarelis, E. and Zabaniotou, A., “Valorization of
  • cotton stalks by fast pyrolysis and fixed bed air
  • gasification for syngas production as precursor of
  • second generation biofuels and sustainable
  • agriculture”, Bioresource Technology, 100 (2):
  • -947, 2009.
  • Qi, W. Y, Hu, C. W., Li, G. Y., Guo, L. H., Yang,
  • Y., Luo, J., Miao, X. and Du, Y., “Catalytic
  • pyrolysis of several kinds of bamboos over zeolite
  • NaY”, Green Chemistry, 8 (2): 183-190, 2006.
  • Wang, C., Du, Z., Pan, J., Li, J. and Yang, Z.,
  • “Direct conversion of biomass to bio-petroleum at low temperature”, Journal of Analytical and
  • Applied Pyrolysis, 78 (2): 438-444, 2007.
  • Tsai, W. T., Lee, M. K. and Chang, Y. M., “Fast
  • pyrolysis of rice husk: Product yields and
  • compositions”, Bioresource Technology, 98 (1):
  • -28, 2007.
  • Basu, P., “Biomass gasification and pyrolysis
  • practical design and theory”, Academic Press is an
  • imprint of Elsevier, USA, 75-78, 2010.
  • Nilsen, M. H., Antonakou, E., Bouzga, A.,
  • Lappas, A., Mathisen, K. and Stöcker, M.,
  • “Investigation of the effect of metal sites in Me-Al-
  • MCM-41 (Me=Fe, Cu or Zn) on the catalytic
  • behavior during the pyrolysis of wooden based
  • biomass”, Microporous and Mesoporous
  • Materials, 105 (1-2): 189-203, 2007.
  • Nakai, T., Kartal, S. N., Hata, T. and Imamura, Y.,
  • “Chemical characterization of pyrolysis liquids of
  • wood-based composites and evaluation of their
  • bio-efficiency”, Building and Environment, 42
  • (3): 1236-1241, 2007.
  • Şensöz, S., Angın, D. ve Demiral, İ., “Kızılçam
  • odun kabuğunun pirolizi ve ürünlerinin
  • incelenmesi”, Yenilebilir Enerji Kaynakları
  • Sempozyumu, İzmir, 147-151, 2001.
  • Gerçel, H. F., “Bio-oil production from
  • Onopordum acanthium L. by slow pyrolysis”,
  • Journal of Analytical and Applied Pyrolysis, 92
  • (1): 233-238, 2011.
  • Heo, S. H., Park, H. J., Park, Y.-K., Ryu, C., Suh,
  • D. J., Suh, Y.-W., Yim, J.-H. and Kim, S.-S.,
  • “Bio-oil production from fast pyrolysis of waste
  • furniture sawdust in a fluidized bed”,
  • Bioresource Technology, 101 (1): 91-96, 2010.
  • American Society for Testing and Materials,
  • “Standard test method for direct moisture content
  • measurement of wood and wood-base materials”,
  • ASTM Standards D 4442-92, Easton, M. D.,
  • USA, 1997.
  • American Society for Testing and Materials,
  • “Standard test method for volatile matter in
  • analysis sample refuse derived fuel”, ASTM
  • Standards E-897-88, Easton, M. D., USA, 2004.
  • American Society for Testing and Materials,
  • “Standard test method for ash in wood”, ASTM
  • Standards D-1102-84, Easton, M. D., USA,
  • -
  • Rowell, R. M., Pettersen, R., Han, J. S., Rowell, J.
  • S. and Tshabalala, M. A., “Handbook of wood
  • chemistry and wood composites”, CRC Press,
  • , 2005.
  • Wise, L. E. and John, E. C., “Wood chemistry”,
  • Reinhold Publication Co, New York, U.S.A., 1-
  • : 1330, 1952.
  • Technical Association of the Pulp and Paper
  • Industry, “Acid-insoluble lignin in wood and
  • pulp”, TAPPI T 222 om-02, Tappi Pres, Atlanta,
  • GA, U.S.A., 2002.
  • Technical Association of the Pulp and Paper
  • Industry, “Solvent extractives of wood and pulp”, TAPPI T 204 cm-97, Tappi Pres, Atlanta, GA,
  • USA, 1997.
  • Wang, Z., Cao, J. and Wang, J., “Pyrolytic
  • characteristics of pine wood in a slowly heating
  • and gas sweeping fixed-bed reactor”, Journal of
  • Analytical and Applied Pyrolysis, 84 (2): 179-
  • , 2009.
  • Fagbemi, L., Khezami, L. and Capart, R.,
  • “Pyrolysis products from different biomasses:
  • Application to the thermal cracking of tar”,
  • Applied Energy, 69 (4): 293-306, 2001.
  • Liaw, S.-S., Wang, Z., Ndegwa, P., Frear, C., Ha,
  • S., Li, C.-Z. and Garcia-Perez, M., “Effect of
  • pyrolysis temperature on the yield and properties
  • of bio-oils obtained from the auger pyrolysis of
  • Douglas Fir Wood”, Journal of Analytical and
  • Applied Pyrolysis, 93: 52-62, 2012.
  • Erşen, T. ve Pehlivan, D., “Yüksek yoğunluklu
  • polietilen–odun karışımlarının birlikte pirolizi”, J.
  • Fac. Eng. Arch. Gazi Univ., 26, (3): 607-612,
  • -
  • Aho, A., Kumar, N., Eränen, K., Salmi, T., Hupa,
  • M. and Murzin, D. Y., “Catalytic pyrolysis of
  • woody biomass in a fluidized bed reactor:
  • Influence of the zeolite structure”, Fuel, 87 (12):
  • -2501, 2008.
  • Zhong, C. and Wei, X., “A comparative
  • experimental study on the liquefaction of wood”,
  • Energy, 29 (11): 1731-1741, 2004.
  • Savage, P. E., Levine, R. B., and Huelsman, C.
  • M.,“Hydrothermal processing of biomass”,
  • Thermochemical Conversion of Biomass to Liquid
  • Fuels and Chemicals, Edited by Mark Crocker,
  • The Royal Society of Chemistry, Cambridge,
  • UK., 1: 192-220, 2010.
  • Qi, Z., Jie, C., Tiejun, W. and Ying, X., “Review
  • of biomass pyrolysis oil properties and upgrading research”, Energy Conversion and
  • Management, 48 (1): 87-92, 2007.
  • Branca, C., Giudicianni, P. and Di Blasi, C., “GCMS
  • characterization of liquid generated from lowtemperature
  • pyrolysis of wood”, Industrial &
  • Engineering Chemistry Research, 42 (14):
  • -3202, 2003.
  • Ingemarsson, A., Nilsson, U., Nilsson, M.,
  • Pedersen, J. R. and Olsson, J. O., “Slow pyrolysis
  • of spruce and pine samples studied with GC/MS
  • and GC/FTIR/FID”, Chemosphere, 36 (14):
  • -2889, 1998.
  • Zeitsch, K. J. “Applications of Furfural”, The
  • chemistry and technology of furfural and its many
  • by-products, Elsevier publication, Netherlands,
  • -103, 2000.
  • Lu, Q., Wang, Z., Dong, C., Zhang, Z., Zhang, Y.,
  • Yang, Y. and Zhu, X., “Selective fast pyrolysis of
  • biomass impregnated with ZnCl2: Furfural
  • production together with acetic acid and activated
  • carbon as by-products”, Journal of Analytical
  • and Applied Pyrolysis, 91 (1): 273-279, 2011.
  • Colombini, M. P., Orlandi, M., Modugno, F.,
  • Tolppa, E.-L., Sardelli, M., Zoia, L. and Crestini,
  • C., “Archaeological wood characterisation by
  • PY/GC/MS, GC/MS, NMR and GPC techniques”,
  • Microchemical Journal, 85 (1): 164-173, 2007.
  • Özbay, G., “Odun ve Odun Esaslı Kompozit
  • Malzeme Talaşlarının Termal ve Katalitik Piroliz
  • Yöntemi ile Sıvılaştırılması”, Doktora Tezi,
  • Karabük Üniversitesi Fen Bilimleri Enstitüsü,
  • Karabük, 89-95, 2012.
  • López, D., Acelas, N. and Mondragón, F.,
  • “Average structural analysis of tar obtained from
  • pyrolysis of wood”, Bioresource Technology,
  • (7): 2458-2465, 2010.
Toplam 148 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

Ayhan Özçifçi Bu kişi benim

Günay Özbay Bu kişi benim

Yayımlanma Tarihi 3 Mart 2014
Gönderilme Tarihi 3 Mart 2014
Yayımlandığı Sayı Yıl 2013 Cilt: 28 Sayı: 3

Kaynak Göster

APA Özçifçi, A., & Özbay, G. (2014). Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 28(3).
AMA Özçifçi A, Özbay G. Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi. GUMMFD. Mart 2014;28(3).
Chicago Özçifçi, Ayhan, ve Günay Özbay. “Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 28, sy. 3 (Mart 2014).
EndNote Özçifçi A, Özbay G (01 Mart 2014) Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 28 3
IEEE A. Özçifçi ve G. Özbay, “Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi”, GUMMFD, c. 28, sy. 3, 2014.
ISNAD Özçifçi, Ayhan - Özbay, Günay. “Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 28/3 (Mart 2014).
JAMA Özçifçi A, Özbay G. Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi. GUMMFD. 2014;28.
MLA Özçifçi, Ayhan ve Günay Özbay. “Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, c. 28, sy. 3, 2014.
Vancouver Özçifçi A, Özbay G. Mobilya Endüstrisi Atıklarından Katalitik Piroliz Yöntemi İle Biyoyakıt Üretimi. GUMMFD. 2014;28(3).