Ultrasonik Ses Dalgası Ortamında Polielektrolit Varlığında Kalsiyum Karbonat Sentezi, Karakterizasyonu ve Deneysel Tasarım

Yıl 2017, , 59 - 69, 22.12.2017

Semra Kırboğa

https://doi.org/10.29109/http-gujsc-gazi-edu-tr.369221

Öz

Bu çalışmada ultrasonik
ses dalgası (USD) uygulanarak suda çözünebilir polielektrolit olan
polivinilsülfonik asit (PVS) varlığında kalsiyum karbonat (CaCO₃)
sentezlenmiştir. Sentezlenen CaCO₃ kristalleri XRD, taramaları
elektron mikroskobu (SEM), parçacık boyutu analizi ve termogravimetrik analiz
(TGA ve DTA) ile karakterize edilmiştir. 2^k Faktöriyel Tasarım
uygulanarak, sonikatör genliğinin, polimer konsantrasyonunun ve USD uygulama
zamanının elde edilen kalsiyum karbonat kristallerinin boyutuna etkisi
incelenmiştir.  Deneysel tasarım iki
seviyede gerçekleştirilmiştir. Seçilen tüm proses parametrelerinin PVS
varlığında elde edilen kalsiyum karbonatın parçacık boyutunda çok etkili olduğu
görülmüştür.  

Anahtar Kelimeler

Kalsiyum Karbonat, Deneysel Tasarım, Ultrasonik Ses Dalgası, Polielektrolit.

The Synthesize of Calcium Carbonate Its Characterization and Experimental Design in an Ultrasonic Sound Wave Environment and in the Presence of Polyelectrolyte

Öz

In this study, calcium carbonate (CaCO₃)
was synthesized by means of ultrasonic irradiation process in the presence of
the water-soluble polyelectrolyte Poly(Vinyl Sulfonic Acid) (PVS). Synthesized
CaCO₃ crystals were characterized by X-ray diffraction (XRD),
scanning electron microscopy (SEM), particle size and thermal analysis (TGA-DTA).
The effects of the amplitude of sonicator, polymer concentration and the
application time of ultrasound on the obtained CaCO₃ with respect to
particle size of final product was investigated by applying the 2^k
Factorial design. The experimental design was studied at two levels. All the
selected process parameters were found to be very effective on the particle
size of calcium carbonate obtained in the presence of PVS. 

Anahtar Kelimeler

Calcium Carbonate, Experimental Design, Ultrasonic Wave, Polyelectrolyte.

Kaynakça

• [1] Kirboga, S., and Oner, M., "Application of experimental design for the precipitation of calcium carbonate in the presence of biopolymer", Powder Technology 249: 95-104, (2013).
• [2] Kirboga, S., and Oner, M., "Effect of the Experimental Parameters on Calcium Carbonate Precipitation", Icheap-11: 11th International Conference on Chemical and Process Engineering, Pts 1-4 32, 2119-2124, (2013).
• [3] Kirboga, S., and Oner, M., "Investigation of calcium carbonate precipitation in the presence of carboxymethyl inulin" Crystengcomm 15: 3678-3686, (2013).
• [4] Kirboga, S., Oner, M., and Akyol, E., "The effect of ultrasonication on calcium carbonatecrystallization in the presence of biopolymer", Journal of Crystal Growth 401: 266-270, (2014).
• [5] Zhao, L., Zhang, Y., Miao, Y., and Nie, L., "Controlled synthesis, characterization and application of hydrophobic calcium carbonate nanoparticles in PVC", Powder Technology 288: 184-190, (2016).
• [6] Amjad, Z., "Precipitation of calcium carbonate in aqueous systems", Tenside Surfactants Detergents 36: 162-167, (1999).
• [7] Sonawane, S.H., Gumfekar, S.P., Meshram, S., Deosarkar, M.P., Mahajan, C.M., and Khanna, P., "Combined Effect of Surfactant and Ultrasound on Nano Calcium Carbonate Synthesized by Crystallization Process", International Journal of Chemical Reactor Engineering 7, (2009).
• [8] Price, G.J., Mahon, M.F., Shannon, J., and Cooper, C., "Composition of Calcium Carbonate Polymorphs Precipitated Using Ultrasound", Crystal Growth & Design 11: 39-44, (2011).
• [9 ] Dalas, E., "The effect of ultrasonic field on calcium carbonate scale formation", Journal of Crystal Growth 222: 287-292, (2001).
• [10] Mateescu, C.D., Mocioi, M., Sarbu, C., Isopescu, R., Chilibon, I., and Branzoi, F., "Calcium carbonate precipitation in ultrasonic field", 13th International Workshop on Industrial Crystallization, 193-200, (2006).
• [11] Nishida, I., "Precipitation of calcium carbonate by ultrasonic irradiation", Ultrasonics Sonochemistry 11: 423-428, (2004).
• [12] Wagterveld, R.M., Miedema, H., and Witkamp, G.-J., "Effect of Ultrasonic Treatment on Early Growth during CaCO3 Precipitation", Crystal Growth & Design 12: 4403-4410, (2012).
• [13] Stoica-Guzun, A., Stroescu, M., Jinga, S., Jipa, I., Dobre, T., and Dobre, L., "Ultrasound influence upon calcium carbonate precipitation on bacterial cellulose membranes", Ultrasonics Sonochemistry 19: 909-915, (2012).
• [14] Mori, Y., Enomae, T., and Isogai, A., "Preparation of vaterite type calcium carbonate by using ultrasound and application to ink-jet paper", 24th Internationational Conference on Digital Printing Technologies/Digital Fabrication, 761-764, (2008)
• [15] Kojima, Y., Kanai, M., and Nishimiya, N., "Synthesis of novel amorphous calcium carbonate by sono atomization for reactive mixing", Ultrasonics Sonochemistry 19: 325-329, (2012).
• [16] Kirboga, S., and Oner, M., "The role of vinyl sulfonic acid homopolymer in calcium oxalate crystallization", Colloids and Surfaces B-Biointerfaces 78: 357-362, (2010).
• [17] Malkaj, P., and Dalas, E., "Effect of metallocene dichlorides on the crystal growth of calcium carbonate", Journal of Crystal Growth 242: 405-411, (2002).
• [18] Garcia-Carmona, J., Morales, J.G., and Rodriguez-Clemente, R., "Morphological control of precipitated calcite obtained by adjusting the electrical conductivity in the Ca(OH)(2)-H2O-CO2 system", Journal of Crystal Growth 249: 561-571, (2003).
• [19] Akyol, E., Ongun, K., Kirboga, S., and Oner, M., "A kinetic study for calcium oxalate crystallization in the presence of Viburnum opulus extract" Biointerface Research in Applied Chemistry 6: 1064-1069, (2016).
• [20] Dalas, E., Klepetsanis, P.G., and Koutsoukos, P.G., "Calcium carbonate deposition on cellulose", Journal of Colloid and Interface Science 224: 56-62, (2000).
• [21] Shen, Y.H., Xie, A.J., Chen, Z.X., Xu, W.H., Yao, H., Li, S.K., Huang, L.C., Wu, Z.F., and Kong, X.Y., "Controlled synthesis of calcium carbonate nanocrystals with multi-morphologies in different bicontinuous microemulsions", Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing 443: 95-100, (2007).
• [22] Szczes, A., "Influence of the surfactant nature on the calcium carbonate synthesis in water-in-oil emulsion", Journal of Crystal Growth 311: 1129-1135, (2009).
• [23] Kanakis, J., and Dalas, E., "The crystallization of vaterite on fibrin", Journal of Crystal Growth 219: 277-282, (2000).
• [24] Manoli, F., and Dalas, E., "Calcium carbonate crystallization in the presence of glutamic acid", Journal of Crystal Growth 222: 293-297, (2001).
• [25] Nagaraja, A.T., Pradhan, S., and McShane, M.J., "Poly (vinylsulfonic acid) assisted synthesis of aqueous solution stable vaterite calcium carbonate nanoparticles", Journal of Colloid and Interface Science 418. 366-372, (2014).
• [26] Jonkers, L., Prins, M.A., Brummer, G.-J.A., Konert, M., and Lougheed, B.C., "Experimental insights into laser diffraction particle sizing of fine-grained sediments for use in palaeoceanography", Sedimentology 56: 2192-2206, (2009).
• [27] Kirboga, S., and Oner, M., "The inhibitory effects of carboxymethyl inulin on the seeded growth of calcium carbonate", Colloids and Surfaces B-Biointerfaces 91: 18-25, (2012).
• [28] Wang, G.C.S., and Jain, C.L., Regression Analysis: Modeling and Forecating. New York: Graceway Publishing Company Inc., (2003).