Potential controlled electrochemical coating and characterization of nanocrystalline Sn-Zn based thin films

Begüm Ünveroğlu Abdioğlu

doi:10.17714/gumusfenbil.1269155

TR EN

Nanokristal Sn-Zn bazlı ince filmlerinin gerilim kontrollü elektrokimyasal kaplanması ve karakterizasyonu

Öz

Sn-Zn ince filmler endüstrinin birçok alanında yaygın olarak kullanılmaktadır ve bu katmanların kolay üretimi önem taşımaktadır. Bu çalışma, potansiyel olarak kontrollü elektrokimyasal olarak biriktirilmiş kaplamalar yoluyla Sn-Zn katmanları üretmeyi amaçlamaktadır. Potansiyel olarak kontrol edilen mod, elektrokimyasal işlemler sırasında şiddetli hidrojen oluşumu reaksiyonunu ortadan kaldırmak için kullanılmıştır. İlk olarak, elektrokimyasal indirgeme ve oksidasyon reaksiyonları, uygulanan potansiyel setlerini belirlemek için döngüsel voltametri ile araştırılmıştır. Daha sonra katmanların katodik darbe potansiyelli elektrokaplaması gerçekleştirilmiştir. Kaplanmış Sn-Zn ince filmlerin karakterizasyonu X-ışını kırınım cihazı (XRD), taramalı elektron mikroskobu (SEM), enerji dağılımlı spektroskopi (EDS), dört noktalı prob, potansiyodinamik polarizasyon ölçümleri ve elektrokimyasal empedans spektrometrisi ile gerçekleştirilmiştir. Katodik darbe potansiyeli değeri arttıkça Sn-Zn alaşımındaki Zn oranı artmış ve katmanların mikro yapısı da etkilenmiştir. Elektrokimyasal çalışmalar, Sn-Zn ince filmlerinin korozyon direncinin, kaplamadaki Zn miktarının artmasıyla arttığını göstermiştir.

Anahtar Kelimeler

Korozyon direnci , Elektrokimyasal kaplama , Darbeli potansiyel , Sn-Zn alaşımı

Potential controlled electrochemical coating and characterization of nanocrystalline Sn-Zn based thin films

Abstract

Sn-Zn thin films are commonly used in many areas of the industry, and the facile production of these layers is vital. This study aims to produce Sn-Zn layers via potentially controlled electrochemically deposited coatings. The potentially controlled mode was used to eliminate the extensive hydrogen evolution reaction during the electrochemical processes. The electrochemical reduction and oxidation reactions were first investigated with cyclic voltammetry to determine the applied potential sets. Later, cathodic pulse potential electrodeposition of the layers was performed. The characterization of the coated Sn-Zn thin films was performed with an X-ray diffraction device (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), four-point probe, potentiodynamic polarization measurements, and electrochemical impedance spectrometry. As the cathodic pulse potential value increased, the ratio of Zn in the Sn-Zn alloy increased, and the microstructure of the layers was also affected. Electrochemical studies showed that the corrosion resistance of the Sn-Zn thin films increased with the increasing Zn amount in the coating.

Keywords

Corrosion resistance , Electrochemical coating , Pulse potential , Sn-Zn alloy

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Begüm Ünveroğlu Abdioğlu ^*
0000-0003-2524-7803
Türkiye

Yayımlanma Tarihi

15 Haziran 2024

Gönderilme Tarihi

22 Mart 2023

Kabul Tarihi

7 Şubat 2024

Yayımlandığı Sayı

Yıl 2024 Cilt: 14 Sayı: 2

DOI

https://doi.org/10.17714/gumusfenbil.1269155

IZ

https://izlik.org/JA26SR78CM

APA

Ünveroğlu Abdioğlu, B. (2024). Potential controlled electrochemical coating and characterization of nanocrystalline Sn-Zn based thin films. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 14(2), 526-537. https://doi.org/10.17714/gumusfenbil.1269155

e-ISSN: 2146-538X Yayın Modeli: Sürekli Yayın Atıf Dizinleri: TR Dizin , SCOPUS

Nanokristal Sn-Zn bazlı ince filmlerinin gerilim kontrollü elektrokimyasal kaplanması ve karakterizasyonu

Öz

Anahtar Kelimeler

Potential controlled electrochemical coating and characterization of nanocrystalline Sn-Zn based thin films

Abstract

Keywords

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

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