Farklı ışık kaynakları altında kristal viyole boyar maddesinin kaolin-BiFeO3 nanokompozit üzerinde fotobozunması

Eda Keleş Güner; Fatih İçer; Agah Özdemir; Bülent Çağlar

doi:10.17714/gumusfenbil.877702

EN TR

Photodegradation of crystal violet dyestuff on kaolinite-BiFeO3 nanocomposite under different light irradiations

Abstract

Kaolinite-BiFeO3 (KBFO) nanocomposite was prepared by decorating of perovskite structured BiFeO3 (BFO) nanoparticles on kaolinite surface. Photocatalytic activities of pure kaolin (K), bare BFO and obtained KBFO nanocomposite were evaluated by examining the photocatalytic degradation of cationic crystal violet dyestuff (CV) under UVA and visible light irradiations (GB). KBFO nanocomposite exhibited higher photocatalytic activity than other catalysts and it was determined that photodegradation followed pseudo first order kinetic. In addition, the optimal values were determined by investigating the effects of experimental parameters such as pH, initial dye concentration and catalyst amount values over photocatalysis, The photocatalytic degradation efficiencies of KV on KBFO at pH 9, presence of 10mgL-1 initial dye concentration and 100mg catalyst under UVA and GB light regions were determined as 84% and 89%, respectively. To determine the contribution of the reactive species responsible for the photocatalytic degradation of KV on the KBFO nanocomposite, radical scavenging experiments were performed and a possible mechanism was proposed. According to radical scavenging experiments, hydroxyl radicals have a major role in the photocatalytic degradation of CV.

Keywords

BiFeO3 , Photocatalysis , Kaolinite , Kinetic , Crystal violet , Crystal violet

Farklı ışık kaynakları altında kristal viyole boyar maddesinin kaolin-BiFeO3 nanokompozit üzerinde fotobozunması

Öz

Kaolin yüzeyine perovskit yapılı BiFeO3 (BFO) nanoparçacıklarının yerleştirilmesiyle Kaolin-BiFeO3 (KBFO) nanokompoziti hazırlandı. Saf kaolin (K), saf BFO ve hazırlanan KBFO nanokompozitin fotokatalitik aktiviteleri UVA ve görünür bölge ışımaları altında katyonik bir boyar madde olan kristal viyole (KV)’nin fotokatalitik bozunması incelenerek değerlendirildi. KBFO nanokompozitinin diğer katalizörlere nispeten daha yüksek fotokatalitik aktivite sergilediği ve fotobozunmanın yalancı birinci dereceden kinetik izlediği belirlendi. Ayrıca pH, başlangıç boya konsantrasyonu ve katalizör miktarı gibi deneysel parametrelerin fotokataliz reaksiyonuna etkileri incelenerek en uygun değerleri tespit edildi. pH 9’da 10mgL-1 başlangıç boya konsantrasyonunda ve 100 mg katalizör varlığında KV’nin KBFO katalizörü üzerindeki fotokatalitik bozunma verimleri UVA ve GB ışınları altında sırasıyla % 84 ve % 89 olarak belirlendi. KV'nin KBFO nanokompozit üzerindeki fotokatalitik bozunmasından sorumlu olan reaktif türlerinin katkısını belirlemek için radikal süpürücü deneyler yapıldı ve olası mekanizma önerildi. Yapılan radikal süpürücü deneylerine göre hidroksil radikallerinin KV’nin fotokatalitik bozunmasında başlıca role sahip olduğu tespit edildi.

Anahtar Kelimeler

BiFeO3 , Fotokataliz , Kaolin , Kinetik , Kristal Viyole

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Eda Keleş Güner ^*
0000-0002-4421-1315
Türkiye

Fatih İçer Bu kişi benim
0000-0003-1696-3197
Türkiye

Agah Özdemir
0000-0003-4488-746X
Türkiye

Bülent Çağlar Bu kişi benim
0000-0002-6087-3685
Türkiye

Yayımlanma Tarihi

15 Temmuz 2021

Gönderilme Tarihi

9 Şubat 2021

Kabul Tarihi

15 Mayıs 2021

Yayımlandığı Sayı

Yıl 2021 Cilt: 11 Sayı: 3

DOI

https://doi.org/10.17714/gumusfenbil.877702

IZ

https://izlik.org/JA46HP65LF

APA

Keleş Güner, E., İçer, F., Özdemir, A., & Çağlar, B. (2021). Farklı ışık kaynakları altında kristal viyole boyar maddesinin kaolin-BiFeO3 nanokompozit üzerinde fotobozunması. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 11(3), 815-827. https://doi.org/10.17714/gumusfenbil.877702

Cited By

TiO2 Nanoparçacık Kaplı Pamuklu Kumaşın Fotokatalitik ve Antibakteriyel Özelliklerinin İncelenmesi

Karadeniz Fen Bilimleri Dergisi

https://doi.org/10.31466/kfbd.1183521

Kobalt Ferrit Nanoparçacıkların Sentezi, Karakterizasyonu ve Fotokataliz Uygulamaları:Farklı Çöktürücü Maddelerin ve Yöntemlerin Etkisi

Journal of the Institute of Science and Technology

https://doi.org/10.21597/jist.1219411

e-ISSN: 2146-538X Yayın Modeli: Sürekli Yayın Atıf Dizinleri: TR Dizin , SCOPUS

Photodegradation of crystal violet dyestuff on kaolinite-BiFeO3 nanocomposite under different light irradiations

Abstract

Keywords

Farklı ışık kaynakları altında kristal viyole boyar maddesinin kaolin-BiFeO3 nanokompozit üzerinde fotobozunması

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster

Cited By

TiO2 Nanoparçacık Kaplı Pamuklu Kumaşın Fotokatalitik ve Antibakteriyel Özelliklerinin İncelenmesi

Kobalt Ferrit Nanoparçacıkların Sentezi, Karakterizasyonu ve Fotokataliz Uygulamaları:Farklı Çöktürücü Maddelerin ve Yöntemlerin Etkisi