The Effect of Phosphogypsum Addition on Physical Properties of Wall Tile Opaque Glaze

Yıl 2020, Cilt: 10 Sayı: 1, 155 - 162, 15.01.2020

Lina İsrail , Kemal Köseoğlu

https://doi.org/10.17714/gumusfenbil.565039

Öz

The effects of addition
of phosphogypsum to wall tile opaque glaze receipe are investigated by
viscosity, thixpthropy and density tests before sintering. Tiles which are
prepared by dipping method are sintered seperately at 950°, 1050° and 1150°C
anda re subjected to impact resistence, thermal shock, resistance to chemicals
and color tests for searching physical properties of the tiles. The flow
behaviour of opaque glaze increased with DKOS1 sample and all mechanical tests
gave positive results after firing at 1150°C. The addition of phosphogypsum is
considered as an appropriate method for recycling phosphogypsum.

Anahtar Kelimeler

Phosphogypsum, Mechanical tets, Opaque glaze, Sintering

Fosfojips Katkısının Duvar Karosu Opak Sır Fiziksel Özelliklerine Etkisi

Öz

Bu
çalışmada, duvar karosu opak sır (DKOS) 
reçetesine farklı oranlarda katılan fosfojips (FJ) in pişirme öncesi
seramik çamurdaki etkileri viskozite, tiksotropi ve yoğunluk testleri incelenmiştir.
Daldırma yöntemiyle hazırlanmış sırlı karolar 950, 1050, 1150°C de ayrı ayrı
pişirilmiştir. Çarpmaya, ısıl şoka, kimyasallara dayanım ve renk testlerine
tabi tutularak fiziksel özellikleri araştırılmıştır. DKOS1 örneği ile opak
sırın akıcılığı artmış ve 1150°C pişirim sonrası tüm mekanik testler olumlu
sonuçlanmıştır. FJ in sır reçetesine katılmasının geri dönüştürülmesi açısından
uygun bir yöntem olduğu görülmüştür.

Anahtar Kelimeler

Fosfojips, Mekanik testler, Opak sır, Sinterleşme

Kaynakça

• Akın, I.A. ve Sert, Y., 2004. Utilization weathered phosphogypsum as set retarder in portland cement. Journal of Cement and Concrete Resolution. 34 (4), 677-680.
• Da Cunha, T.B., Wu, J.P., Peitl, O., Fokin, V.M., Zanotto E.D., Lanucci L. ve Boccaccini A.R. 2007. Mechanical properties and impact resistance of a new transparent glass-ceramic. Advanced Engineering Materials, 9 (3), 191-196.
• TS EN ISO 10545-16: 2000. Ceramic Tiles-Part 16: Determination of small colour differences. 1-13.
• Da Silva, R.C., Pianaro, S.A. ve Tebcherani, S.M., 2012. Preparation and characterization of glazes from combinations of different industrial wastes. Ceramics 38, 2725-2731.
• Değirmenci, N., Okucu, A. ve Turabi, A., 2007. Application of phosphogypsum in soil stabilization. Journal of Building and Environment. 42 (9), 3393-3398.
• Değirmenci, N., 2008. Utilization of phosphogypsum as raw and calcined material in manufacturing of building products. Construction of Building Materials. 22 (8) 1857-1862.
• Demirel, Y. ve Çağlar, Y., 2015. Atık fosfojipslerin yapı malzemesi olarak ekonomiye geri. kazandırılması. Gazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 30 (4), 743-750.
• DIN 53211. 1987. Paints, varnishes and similar coating metarials. Determination of flow time using the flow cup. 1-6.
• El-Didamony, H., Gado, H.S., Awwad, N.S., Fauzy M.M. ve Attallah M.F., 2013. Treatment of phosphogypsum waste produced from phosphate ore processing. Journal of Hazardous Materials. 244-245, 596-602.
• Ezz-Eldin, F.M. ve Nageeb, W.M., 2001. Chemical resistance of some irradiated ceramic glasses. Indian Journal of Pure and Applied Physics. 39, 514-524.
• Flinders, M., Ray D., Anderson, A. ve Cutler, R.A., 2005. High toughness silicon carbide as armor. Journal of American Ceramic Society. 88 (8), 2217-2226.
• Formosa, J., Chimenos, J.M., Lacasta, A.M. ve Niubo M., 2012. Interaction between low-grade magnesium oxide and boric acid in chemically bonded phosphate ceramics formulation. Ceramics International. 38 (3), 2483-2493.
• Gennari, R., Garcia, I., Medina, N.H. ve Silveira, M.A.G., 2011. Phosphogypsum Analysis: Total Content and Extractable Element Eoncentrations, October 2011, Belo Horizonte, Brasil.
• Jonker, A. ve Potgieter, J.H., 2005. An evaluation of selected waste resources for utilization in ceramic materials apllications. Journal of European Ceramic Society. 25, 3145-3149.
• Li, Y. ve Chen, B., 2013. Factors that affect the properties of magnesium phosphate cement. Journal of Cement and Construction Building Materials. 47 (7), 977-983.
• Lin, D.F., Lou, H.L. ve Sheen, Y.N. 2005. Glazed tiles manufactured from incinerated sewage ash and clay. Journal of Air and Waste Managment Assosiation. 55, 163-172.
• Mc Quillan, F., 1995. The Response of Silceram Glass-Ceramics to Projectile Impact. PhD thesis. Imperial Collage of London.
• Mejia, J.F., 2004. Understanding the Role of Fluxes in Single-fire Porcelain Glaze Development. MSc Thesis, Alfred University, NY.
• Muller, K. ve Zamek, J., 2011. The Potter’s Complete Studio Handbook: The Essential Start to Finish Guide for Ceramic Artists. Quarry Books. Beverly Massachusetts. 320p.
• Parmelee, C.W., 1987. Ceramic Glazes. Cahners Books Division of Cahners Publishing Company. New York. 612p.
• Singer, F. ve Singer, S.S., 1979. Industrial Ceramics. Chapman and Hall. London. 1457p.
• Singh, M., 2002. Treating waste phosphogypsum for cement and plaster manufacture. Journal of Cement and Concrete Resolution. 32 (7), 1033-1038.
• Sirazhiddinov, N.A., Irkakhodzhaeva, A.P. ve Azizkhodzhaeva M.M., 1994. Use of phosphogypsum and floatation wastes from copper concentration for fabrication of glass and glass ceramics. Glass and Ceramics. 51, 102-104.
• Smadi, M.M., Haddad, R.H. ve Akour, A.M., 1999. Potential use of phosphogypsum in concrete. Cement and Concrete Research. 9, 1419-1425.
• TS EN ISO 10545-3, 2018. Ceramic Tiles-Part 3: Determination of water absorption, apparent relative density and bulk density, 1-8.
• TS EN ISO 10545-5, 2000. Ceramic Tiles-Part 5: Determination of impact resistance by measuring the coefficient of restitution. 1-11.
• TS EN ISO 10545-9, 2000. Ceramic Tiles-Part 11: Determination of resistance to thermal shock.1-7.
• TS EN ISO 10545-13, 2017. Ceramic Tiles-Part 13: Determination of chemical resistance. 1-20.
• Uhlmann, D.R. ve Keidl, N.J., 1983. Glass Science and Technology Vol:1. New York. 301 p.
• URL-1,https:// www.fipr.statefl.us/publication/phosphogypsum-proceedings-of-the-international-symposium-on- phosphogypsum.2007
• URL-2,https://www.kalkinma.gov.tr/docobjects/download/3570/oik690.pdf
• URL-3,https://gardco.com/pages/viscosity/vi/din_cups.cfm.
• URL-4,https://www.hunterlab.com/appnotes/an0896a.pdf.
• URL-5,https://www.spectrumglazes.com/viscpg.html (accessed 08.06.2018)
• Wang, A.J., Yuan, Z.L., Zhang, J., Liu, L.T., Li, J.M. ve Liu, Z., 2013. Effect of raw material ratios on the compressive strength of magnesium potasium phosphate chemically bonded ceramic. Materials Science and Engineering C: Materials for Biological Applications. 38 (8), 5058-5063.
• Yalçın, N. ve Sevinç, V., 2000. Utilization of bauxite waste in ceramic glazes. Ceramics International. 26, 485-493.
• Zhou, J., Gao, H., Shu, Z. Wang, Y.X. ve Yan, C., 2012. Utilization of waste phosphogypsum to prepare non-fired bricks by a novel hydration-recrystallization process. Journal of Construction and Building Materials. 34, 114-119.
• Zhou, J., Sheng, Z., Li T., Shu, Z., Chen, Y. ve Wang C., 2016. Preparation of hardened tiles from waste phosphogypsum by new intermittent pressing hydration. Ceramics International. 42, 7237-7245.