Potential controlled electrochemical coating and characterization of nanocrystalline Sn-Zn based thin films

Yıl 2024, Cilt: 14 Sayı: 2, 526 - 537, 15.06.2024

Begüm Ünveroğlu Abdioğlu

https://doi.org/10.17714/gumusfenbil.1269155

Öz

Sn-Zn thin films are commonly used in many areas of the industry, and the facile production of these layers is vital. This study aims to produce Sn-Zn layers via potentially controlled electrochemically deposited coatings. The potentially controlled mode was used to eliminate the extensive hydrogen evolution reaction during the electrochemical processes. The electrochemical reduction and oxidation reactions were first investigated with cyclic voltammetry to determine the applied potential sets. Later, cathodic pulse potential electrodeposition of the layers was performed. The characterization of the coated Sn-Zn thin films was performed with an X-ray diffraction device (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), four-point probe, potentiodynamic polarization measurements, and electrochemical impedance spectrometry. As the cathodic pulse potential value increased, the ratio of Zn in the Sn-Zn alloy increased, and the microstructure of the layers was also affected. Electrochemical studies showed that the corrosion resistance of the Sn-Zn thin films increased with the increasing Zn amount in the coating.

Anahtar Kelimeler

Corrosion resistance, Electrochemical coating, Pulse potential, Sn-Zn alloy

Proje Numarası

Destekleyen herhangi bir kurum bulunmamaktadır.

Nanokristal Sn-Zn bazlı ince filmlerinin gerilim kontrollü elektrokimyasal kaplanması ve karakterizasyonu

Öz

Sn-Zn ince filmler endüstrinin birçok alanında yaygın olarak kullanılmaktadır ve bu katmanların kolay üretimi önem taşımaktadır. Bu çalışma, potansiyel olarak kontrollü elektrokimyasal olarak biriktirilmiş kaplamalar yoluyla Sn-Zn katmanları üretmeyi amaçlamaktadır. Potansiyel olarak kontrol edilen mod, elektrokimyasal işlemler sırasında şiddetli hidrojen oluşumu reaksiyonunu ortadan kaldırmak için kullanılmıştır. İlk olarak, elektrokimyasal indirgeme ve oksidasyon reaksiyonları, uygulanan potansiyel setlerini belirlemek için döngüsel voltametri ile araştırılmıştır. Daha sonra katmanların katodik darbe potansiyelli elektrokaplaması gerçekleştirilmiştir. Kaplanmış Sn-Zn ince filmlerin karakterizasyonu X-ışını kırınım cihazı (XRD), taramalı elektron mikroskobu (SEM), enerji dağılımlı spektroskopi (EDS), dört noktalı prob, potansiyodinamik polarizasyon ölçümleri ve elektrokimyasal empedans spektrometrisi ile gerçekleştirilmiştir. Katodik darbe potansiyeli değeri arttıkça Sn-Zn alaşımındaki Zn oranı artmış ve katmanların mikro yapısı da etkilenmiştir. Elektrokimyasal çalışmalar, Sn-Zn ince filmlerinin korozyon direncinin, kaplamadaki Zn miktarının artmasıyla arttığını göstermiştir.

Anahtar Kelimeler

Korozyon direnci, Elektrokimyasal kaplama, Darbeli potansiyel, Sn-Zn alaşımı

Destekleyen Kurum

Destekleyen herhangi bir kurum bulunmamaktadır.

Proje Numarası

Destekleyen herhangi bir kurum bulunmamaktadır.

Teşekkür

Gümüşhane Üniversitesi Fen Bilimleri Dergisi kuruluna ve katkıda bulunan hakemlere teşekkürlerimi sunarım.

Kaynakça

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