BibTex RIS Kaynak Göster

Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II

Yıl 2007, Cilt: 35 Sayı: 2, 123 - 128, 01.04.2007

Dursun Ali Kose Hasan Icbudak Hacali Necefoglu

Öz

Nicotinamide-acetylsalicylato complexes of Co II , Ni II , Cu II , and Zn II were synthesised and their structural properties were investigated by employing elemental analysis, magnetic susceptibilitiy, solid state UV-vis, direct injectionprobe mass, FTIR and thermoanalytic TG-DTG methods. It was found that ratio of metal:ligand:ligand is 1:2:2 and thedecomposition of each complex starts with dehydration and follows by decomposition of the nicotinamide and acetylsalicylato, respectively. The thermal dehydration of the complexes takes place in steps from one to two. The decomposition mechanism and thermal stability of the investigated complexes are interpreted in terms of their structures. Thefinal decomposition products are found to be the respective metal oxides

Anahtar Kelimeler

Nicotinamide N N-diethylnicotinamide acetylsalicylato Thermal decomposition metal complexes

Kaynakça

  • K. Florey, Aspirin in Analytical Profiles of Drug Sub- stances, Academic Press. Inc., 1979.
  • M Geraghty, V. Sheridan, M. McCann, M. Devereux and V. McKee, Polyhedron, 18 (1999) 2931. 3. Z. Zheng-Zhi and M. Yong-Xiang, Rev. Roum. Chim., 38, 5 (1993) 561.
  • S.R. Drake, S.D. Sanderson, M.B. Hurthouse and K.M. Abdul Malik, Inorg. Chem., 32 (1993) 1041.
  • N.J. Brownless and DA. Edwards and M.F. Mahon, Inorg. Chim. Acta, 287 (1999) 89.
  • U. Brühlmann and E. Hayon, J. Am. Chem. Soc., 96 (1974) 6169.
  • M. Kato and Y. Muto, Coord. Chem. Rev., 92 (1988) 45.
  • R. Nagar, J. Inorg. Biochem., 40 (1990) 349.
  • J. Eugen, K. Marian, M. Milan, M. Jerzy, J. Coord. Chem., 40 (1996) 167.
  • Y. Miwa, T. Mizuno, K. Tsuchiya, T. Taga and Y. Iwata, Acta Crystallogr., 55B (1999) 75.
  • B. Vogalsanger, R.D. Brown, P.D. Godfrey and A.P. Pierlot, J. Mol. Spectrosc., 145 (1991) 1.
  • P. Purcell, J. Phys. Chem., 68 (1964) 2666.
  • P. Purcell and A.J. Siger, J. Phys. Chem., 69 (1965) 4097.
  • E. Casassas, A. Izquierdo-Ridorsa and R. Tauler, J. Chem. Soc., Dalton Trans., (1990) 2341.
  • I. Leban, B. Kozlevcar, J. Sieler and P. Segedin, Acta Cryst., C53 (1997) 1420.
  • C Motz, H.P. Roth and M. Kirchgessner, Trace Elem. Electroly., 12, 1 (1995) 1.
  • N. Petrovcic, B. Kozlevcar, L. Golic, I. Leban and P. Segedin, Acta Cryst., C55 (1999) 176.
  • M. Devereux, M. Curran. M. McCann, R.M.T. Casey and V. McKee, Polyhedron, 15, 12 (1996) 2029.
  • T. Hökelek and H. Necefoglu, Acta Cryst., C53 (1997) 187.
  • D.A. Kose, MSc. Thesis (2001) Kars.
  • H. Icbudak, Z. Heren, D.A. Kose and H. Necefoglu, J. Therm. Anal.Cal., 76 (2004) 837.
  • Ö.F. Öztürk, M. Şekerci and E. Özdemir, Russ. J. Coord. Chem., 31 (2005) 687.
  • H. Icbudak, H. Olmez, O.Z. Yesilel, F. Arslan, P. Nau- mov, G. Jovanovski, A.R. Ibrahim, A. Usman, H.K. Fun, S. Chantrapromma and S.W. Ng, J. Mol. Struct., 657 (2003) 255.
  • K. Nakamoto, Infrared and Raman Spectra of Inor- ganic and Coordination Compounds, Wiley and Sons, New York, 1978, 197.
  • J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64 (2001) 843.
  • M.I. Pope and M.D. Judd. Differential Thermal Analy- sis, Heyden & Son, London, 1980.
  • J.D. Lee, Concice Inorganic Chemistry, Blackweel Science, 5thEdition, London, 2002.
  • H. İçbudak, T.K. Yazicilar and V.T. Yilmaz, Ther- mochim. Acta, 335 (1999) 93.
  • D.A. Köse, A. Kaya, H. Necefoğlu, Russ. J. Coord. Chem., 33(6) (2007) 422.
  • D.A. Köse, E.F. Öztürkkan, H. Necefoğlu, İ. Uzun, Assian J. Chem., 19(6) (2007) 4880.
  • H. içbudak, V.T. Yilmaz and H. Olmez, J. Therm. Anal., 53 (1998) 843.
  • D.A. Köse, B. Zümreoglu-Karan, O. Şahin and O. Büyükgüngör, J. Mol. Struct., 789(1-3) (2006) 147.
  • P. Kokkonen, L.H.J. Lajunen, A. Jaakola and H. Ruot- salainen, Thermochim. Acta, 79 (1984) 289.
  • G.A.M. Hussein, H.M. Ismail and S.A.S. Mansour, J. Anal. Appl. Pyrolysis, 36 (1996) 17.
  • K. Györyova, V. Balek, M. Melnik and F.A. Nour El- Dien, J. Therm. Anal., 53 (1998) 577.
  • E. Regulska, M. Samsonowicz, R. Swisłocka, W. Lewandowski, J. Mol. Struct., 744–747 (2005) 353.

Yıl 2007, Cilt: 35 Sayı: 2, 123 - 128, 01.04.2007

Dursun Ali Kose Hasan Icbudak Hacali Necefoglu

Öz

Kaynakça

  • K. Florey, Aspirin in Analytical Profiles of Drug Sub- stances, Academic Press. Inc., 1979.
  • M Geraghty, V. Sheridan, M. McCann, M. Devereux and V. McKee, Polyhedron, 18 (1999) 2931. 3. Z. Zheng-Zhi and M. Yong-Xiang, Rev. Roum. Chim., 38, 5 (1993) 561.
  • S.R. Drake, S.D. Sanderson, M.B. Hurthouse and K.M. Abdul Malik, Inorg. Chem., 32 (1993) 1041.
  • N.J. Brownless and DA. Edwards and M.F. Mahon, Inorg. Chim. Acta, 287 (1999) 89.
  • U. Brühlmann and E. Hayon, J. Am. Chem. Soc., 96 (1974) 6169.
  • M. Kato and Y. Muto, Coord. Chem. Rev., 92 (1988) 45.
  • R. Nagar, J. Inorg. Biochem., 40 (1990) 349.
  • J. Eugen, K. Marian, M. Milan, M. Jerzy, J. Coord. Chem., 40 (1996) 167.
  • Y. Miwa, T. Mizuno, K. Tsuchiya, T. Taga and Y. Iwata, Acta Crystallogr., 55B (1999) 75.
  • B. Vogalsanger, R.D. Brown, P.D. Godfrey and A.P. Pierlot, J. Mol. Spectrosc., 145 (1991) 1.
  • P. Purcell, J. Phys. Chem., 68 (1964) 2666.
  • P. Purcell and A.J. Siger, J. Phys. Chem., 69 (1965) 4097.
  • E. Casassas, A. Izquierdo-Ridorsa and R. Tauler, J. Chem. Soc., Dalton Trans., (1990) 2341.
  • I. Leban, B. Kozlevcar, J. Sieler and P. Segedin, Acta Cryst., C53 (1997) 1420.
  • C Motz, H.P. Roth and M. Kirchgessner, Trace Elem. Electroly., 12, 1 (1995) 1.
  • N. Petrovcic, B. Kozlevcar, L. Golic, I. Leban and P. Segedin, Acta Cryst., C55 (1999) 176.
  • M. Devereux, M. Curran. M. McCann, R.M.T. Casey and V. McKee, Polyhedron, 15, 12 (1996) 2029.
  • T. Hökelek and H. Necefoglu, Acta Cryst., C53 (1997) 187.
  • D.A. Kose, MSc. Thesis (2001) Kars.
  • H. Icbudak, Z. Heren, D.A. Kose and H. Necefoglu, J. Therm. Anal.Cal., 76 (2004) 837.
  • Ö.F. Öztürk, M. Şekerci and E. Özdemir, Russ. J. Coord. Chem., 31 (2005) 687.
  • H. Icbudak, H. Olmez, O.Z. Yesilel, F. Arslan, P. Nau- mov, G. Jovanovski, A.R. Ibrahim, A. Usman, H.K. Fun, S. Chantrapromma and S.W. Ng, J. Mol. Struct., 657 (2003) 255.
  • K. Nakamoto, Infrared and Raman Spectra of Inor- ganic and Coordination Compounds, Wiley and Sons, New York, 1978, 197.
  • J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64 (2001) 843.
  • M.I. Pope and M.D. Judd. Differential Thermal Analy- sis, Heyden & Son, London, 1980.
  • J.D. Lee, Concice Inorganic Chemistry, Blackweel Science, 5thEdition, London, 2002.
  • H. İçbudak, T.K. Yazicilar and V.T. Yilmaz, Ther- mochim. Acta, 335 (1999) 93.
  • D.A. Köse, A. Kaya, H. Necefoğlu, Russ. J. Coord. Chem., 33(6) (2007) 422.
  • D.A. Köse, E.F. Öztürkkan, H. Necefoğlu, İ. Uzun, Assian J. Chem., 19(6) (2007) 4880.
  • H. içbudak, V.T. Yilmaz and H. Olmez, J. Therm. Anal., 53 (1998) 843.
  • D.A. Köse, B. Zümreoglu-Karan, O. Şahin and O. Büyükgüngör, J. Mol. Struct., 789(1-3) (2006) 147.
  • P. Kokkonen, L.H.J. Lajunen, A. Jaakola and H. Ruot- salainen, Thermochim. Acta, 79 (1984) 289.
  • G.A.M. Hussein, H.M. Ismail and S.A.S. Mansour, J. Anal. Appl. Pyrolysis, 36 (1996) 17.
  • K. Györyova, V. Balek, M. Melnik and F.A. Nour El- Dien, J. Therm. Anal., 53 (1998) 577.
  • E. Regulska, M. Samsonowicz, R. Swisłocka, W. Lewandowski, J. Mol. Struct., 744–747 (2005) 353.
Toplam 35 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Research Article
Yazarlar

Dursun Ali Kose Bu kişi benim

Hasan Icbudak Bu kişi benim

Hacali Necefoglu Bu kişi benim

Yayımlanma Tarihi 1 Nisan 2007
Yayımlandığı Sayı Yıl 2007 Cilt: 35 Sayı: 2

Kaynak Göster

APA Kose, D. A., Icbudak, H., & Necefoglu, H. (2007). Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. Hacettepe Journal of Biology and Chemistry, 35(2), 123-128.
AMA Kose DA, Icbudak H, Necefoglu H. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC. Nisan 2007;35(2):123-128.
Chicago Kose, Dursun Ali, Hasan Icbudak, ve Hacali Necefoglu. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry 35, sy. 2 (Nisan 2007): 123-28.
EndNote Kose DA, Icbudak H, Necefoglu H (01 Nisan 2007) Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. Hacettepe Journal of Biology and Chemistry 35 2 123–128.
IEEE D. A. Kose, H. Icbudak, ve H. Necefoglu, “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”, HJBC, c. 35, sy. 2, ss. 123–128, 2007.
ISNAD Kose, Dursun Ali vd. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry 35/2 (Nisan 2007), 123-128.
JAMA Kose DA, Icbudak H, Necefoglu H. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC. 2007;35:123–128.
MLA Kose, Dursun Ali vd. “Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II”. Hacettepe Journal of Biology and Chemistry, c. 35, sy. 2, 2007, ss. 123-8.
Vancouver Kose DA, Icbudak H, Necefoglu H. Synthesis and Characterization of the Nicotinamide-Acetylsalicylato Complexes of Co II , Ni II , Cu II , and Zn II. HJBC. 2007;35(2):123-8.

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