A New Adsorptive Square-Wave Stripping Voltammetric Method for the Trace Analysis of Germanium

Yıl 2008, Cilt: 36 Sayı: 3, 215 - 221, 01.08.2008

Faruk Gökmeşe Ebru Gökmeşe Ali Osman Solak

Öz

The adsorptive stripping voltammetric determination of trace amounts of germanium IV based on the adsorptiveaccumulation of the germanium IV -N- 2-hydroxyphenyl -3-hydroxysalicylaldimine complex on the hanging mercurydrop electrode is reported. The cathodic current of the adsorbed complex was measured by square wave adsorptivestripping voltammetry. The peak potential is at -0.44 V vs. Ag|AgCl|KCl sat . The effects of various parameters suchas ligand and supporting electrolyte H3PO4 concentrations, accumulation potential and deposition time wereinvestigated. After all optimization processes, the reduction peak was exploited for analytical purposes. The detectionlimit is 4.7×10-9M and coefficient of variation is 7.5%. The possible interferences in soil and biological samples bysome ions were evaluated in detail

Anahtar Kelimeler

Trace analysis of germanium, square wave stripping voltammetry, N- 2-hydroxyphenyl -3-hydroxysalicylaldimine complex

Kaynakça

• 1. Schleich, C.; Henze, G. Fresenius’ J. Anal Chem., 1990, 338, 145.
• 2. Alam, A.M.S.; Vittori, O.; Porthult, M. Anal. Chim. Acta, 1978, 102, 113.
• 3. McCrory-Joy, C.; Rosamilla, J.M. Anal Chim. Ada, 1982, 142, 231.
• 4. Hasebe, K.; Hikima, S.; Kakizaki, T.; Iwashimizu, T.; Aoki, K. Analyst, 1990, 115, 413.
• 5. Karpinski, Z. J.; Polosak, A.; Kublik, Z. Anal. Chim. Acta, 1980, 120, 55.
• 6. Aguilar, J. C.; de Gyves, J. Anal. Chim. Acta., 1995, 306, 243.
• 7. Sun, C.; Gao, Q.; Liu, L. Talanta, 1995, 42, 881.
• 8. Shi, J.; Jiao, K. Anal. Chim. Acta, 1995, 309, 103.
• 9. Mark, H.B. Analyst, 1990, 115, 667.
• 10. Tur'yan, Ya.I. J. Eledroanal. Chem., 1992, 388, 1.
• 11. Muňiz Alvarez, J.L.; García Calzón, J. A.; López Fonseca, J.M. Talanta, 2001, 53, 721.
• 12. Banica, F.G.; Moreira, J.C.; Fogg, A.G. Analyst, 1994, 119, 309.
• 13. Ion, A.; Banica, F.G.; Luca, C. Electroanalysis, 1997, 9, 945.
• 14. García Calzón, J. A.; Miranda Ordieres, A.J.; Muňiz Álvarez, J.L.; López Fonseca, J.M. J. Electroanal Chem., 1997, 427, 29.
• 15. Gökmeşe, F.; Gökmeşe, E.; Çekirdek, P.; Solak, A.O. B. Electrochem., 2005, 21 [5], 193.
• 16. Fernandez-G, J.M.; del Rio-Portilla, F.; QuirozGarcia, B.; Toscano, R.A.; Salcedo, R. J. Mol Struc. 2001, 561, 197.
• 17. Nazarenko, V.A. Analytical Chemistry of Germanium, J. Wiley, New York, 1974.