Boya Uzaklaştırma İçin İmmobilize Metal Şelat AŞnite KromatograŞ Matriksi Olarak Fe3+

Yıl 2011, Cilt: 39 Sayı: 2, 145 - 155, 01.04.2011

Tülden Kalburcu M. Nalan Tüzmen

Öz

Bu çalışmada, Fe3+ şelatlanmış Cibacron Blue F3GA immobilize poli akrilamid-allil glisidil eter [p AAm-AGE CB-Fe3+] kriyojelin boya Congo Red, Reactive Green uzaklaştırma için potansiyel kullanımı araştırılmıştır. Kriyojel, radikalik polimerizasyon ile sentezlenmiştir. Cibacron Blue, kriyojel üzerine kovalent olarak bağlanmış ve Fe3+ iyonları ile şelatlanmıştır. Maksimum adsorpsiyon kapasiteleri, Congo Red için 14.50 mg/g kriyojel; Reaktive Green için 18.78 mg/g kriyojel olarak belirlenmiştir. Ayrıca, hem Congo Red hem de Reactive Green için Freundlich izoterminin uygun olduğu belirlenmiştir. Bu çalışma, p AAm-AGE -CB-Fe3+ kriyojelik materyalin yüksek derişimdeki farklı boyalar için adsorban olarak etkin bir şekilde kullanılabileceğini göstermiştir

Anahtar Kelimeler

Boya uzaklaştırma, Congo Red, Reactive Green, kriyojel, İMAK

Fe3+ Immobilized Cryogel as an Immobilized Metal Affinity Chromatography IMAC Support for Dye removal

Öz

In this study, the potential use of Fe3+ chelated Cibacron Blue F3GA immobilized poly acrylamide-allyl glycidyl ether [p AAm-AGE -CB-Fe3+ ] cryogel to remove dyes from aqueous solutions was evaluated. Cryogel was prepared by radical polymerization. Cibacron Blue F3GA was covalently immobilized on p AAm-AGE cryogel and then chelated with Fe3+ ions. Maximum adsorption capacities were determined as 14.50 mg/g cryogel for Congo Red and 18.78 mg/g cryogel for Reactive Green. It was also determined that Freundlich isotherm was convenient for both dyes. More than 90% of the adsorbed dyes were desorbed in all cases. This study indicates that p AAm-AGE -CB-Fe3+ cryogelic material can be efficiently used as adsorbent for different dyes at high concentrations.

Anahtar Kelimeler

Dye removal, Congo red, reactive green, cryogel, IMAC

Kaynakça

• 1. A. Bhatnagar, A.K. Jain, M.K. Mukul, Removal of congo red dye from water using carbon slurry waste, Environ Chem Lett., 2 (2005) 199.
• 2. S. Seshadri, P.L. Bishop, A.M. Agha, Anaerobic-aerobic treatment of selected azo dyes in wastewater, Waste Manage, 15 (2004) 127.
• 3. R.Y.L. Yeh, A. Thomas, Color difference measurements and color removal from dye wastewaters using different adsorbents, J. Chem. Technol. Biotechnol., 63 (1995) 55.
• 4. L.C. Morais, O.M. Freitas, E.P. Goncalves, L.T. Vaskancelos, C.G. Beca, Reactive dyes removal from wastewaters by adsorption on eucalyptus bark: variables that define the process, Water Res. 33 (1999) 978.
• 6. J. McCann, B.N. Ames, Detection of carcinogens as mutagens in the Salmonella/microsome test, Assay of 300 chemicals: discussion, Proc. Natl. Acad. Sci., 73 (1975) 950.
• 7. J. Oakes, P. Gratton, Kinetic investigations of the oxidation of arylazonaphthol dyes in hypochlorite solutions as a function of pH, J. Chem. Soc. Perkin Transactions, 10 (1998) 2201.
• 8. S.H. Lin, C.C. Lo, Treatment of textile wastewater by foam flotation, Environ. Technol., 17 (1996) 841.
• 9. S.M. McClung, A.T. Lemley, Electrochemical treatment and HPLC analysis of wastewater containing acid dyes, Text. Chem. Color., 26 (1994) 17.
• 10. H. Kanazawa, T. Onami, Degradation of azo dyes by sodium hypochlorite, Estimation of the rate equation for the degradation of Orange G and Benzopurpurine, Bull. Chem. Soc. Jpn., 68 (1997) 2483.
• 11. A. Bousher, X. Shen, R.G.J. Edyvean, Removal of colored organic matter by adsorption onto low-cost waste materials, Water Res., 31 (1997) 2084.
• 12. J. Sarasa, M.P. Roche, M.P. Ormad, E. Gimeno, A. Puig, J.L. Ovellerio, Treatment of a wastewater resulting from dyes manufacturing with ozone and chemical coagulation, Water Res., 32 (1998) 2721.
• 13. S. Papic, N. Koprivanac, B.A. Loncaric, Removal of reactive dyes from wastewater using Fe(III) coagulant, J. Soc. Dyers Color., 116 (2000) 352.
• 14. I. Poulios, I. Aetopoulou, Photocatalytic degradation of the textile dye Reactive Orange 16 in the presence of TiO2 suspensions, Environ. Technol., 20 (1999) 479.
• 15. S.D. Faust, O.M. Aly, Adsorption process for water treatment, Butterworths Publishers, Stoneham, 1987.
• 16. R.S. Blackburn, Natural polysaccharides and their interaction with dye molecules: applications in effluent treatment, Environ. Sci. Technol., 38 (2004) 4905.
• 17. V.K. Gupta, D. Mohan, S. Sharma, M. Sharma, Removal of basic dyes (Rhodamine-B and Methylene blue) from aqueous solutions using bagasse fly ash, Sep. Sci. Technol., 35 (2000) 2097.
• 18. V.K. Gupta, A. Mittal, L. Krishnan, J. Mittal, Adsorption treatment and recovery of the hazardous dye, Brilliant Blue FCF, over bottom ash and de-oiled soya, J. Colloid Interface Sci., 296 (2005) 16.
• 19. V.K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Removal and recovery of the hazardous azo dye Acid Orange 7 through adsorption over waste materials: bottom ash and de-oiled soya columns’, Ind. Eng. Chem. Res., 45 (2006) 1446.
• 20. V.K. Gupta, R. Jain, S. Varshney, Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents, J. Colloid Interface Sci., 312 (2007) 292.
• 21. V.K. Gupta, R. Jain, S. Varshney, Removal of Reactofix golden yellow 3 RFN from aqueous husk—an agricultural waste, J. Hazard. Mater., 142 (2007) 443.
• 22. A. Mittal, A. Malviya, D. Kaur, J. Mittal, L. Kurup, Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials, J. Hazard. Mater., 148 (2007) 229.
• 23. A. Mittal, V.K. Gupta, A. Malviya, J. Mittal, Process development for the batch and bulk removal and recovery of a hazardous, water-soluble azo dye Metanil Yellow by adsorption over waste materials (bottom ash and de-oiled soya), J. Hazard. Mater., 151 (2008) 821.
• 24. D. Mohan, K.P. Singh, G. Singh, K. Kumar, K. Removal of dyes from wastewater using fly ash, a low cost adsorbent, Ind. Eng. Chem. Res., 41 (2002) 3688.
• 25. S.V. Mohan, N.C. Rao, J. Karthikeyan, Adsorption removal of direct azo dye from aqueous phase onto coal based sorbents: a kinetic and mechanistic study, J. Hazard. Mater., 90 (2002) 189.
• 26. F.C. Wu, R.L. Tseng, R.S. Juang, Kinetics of color removal by adsorption from water using activated clay, Environ. Technol., 22 (2001) 721.
• 27. M.M. Nassar, The kinetics of basic dye removal using palm fruit bunch, Adsorpt. Sci. Technol., 15 (1997) 609.
• 28. G. McKay, Application of surface diffusion model to the adsorption of dyes on bagasse pith, Adsorption, 4 (1998) 361.
• 29. G. Annadurai, R.S. Juang, D.J. Lee, Use of cellulosebased wastes for adsorption of dyes from aqueous solutions, , J. Hazard. Mater., 92 (2002) 263.
• 30. K.R. Ramakrishna, T. Viraraghavan, Dye removal using low cost adsorbents, Water Sci. Technol., 36 (1997) 189.
• 31. Z. Aksu, Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modeling, Biochem. Eng. J., 7 (2001) 79.
• 32. V.K. Gupta, A. Mittal, R. Jain, M. Mathur, S. Sikarwar, Adsorption of Safranin T from wastewater using waste materials-activated carbon and activated rice husk’, J. Colloid Interface Sci., 303 (2006) 80.
• 33. R. Jain, S. Sikarwar, Photocatalytic and adsorption studies on the removal of dye Congo red from wastewater, Int. J. Environ. Pollut., 27 (2006) 158.
• 34. R. Jain, A. Mittal, M. Mathur, S. Sikarwar, Removal of the hazardous dye Rhodamine B from photocatalytic and adsorption treatments, J. Environ. Manage., 85 (2007) 956.
• 35. V. Kudela, Hydrogels, In: Encyclopedia of Polymer Science and Engineering, J. Wiley & Sons, New York, 7, 1987.
• 36. T. Tanaka, Gels, In: Nicolini C., Structure and Dynamics of Biopolymers, M. Nijhoff Publ., Dordrecht, 1987.
• 37. V.I. Lozinsky, F.M. Plieva, I.Y. Galaev, B. Mattiasson, The potential of polymeric cryogels in bioseparation, Bioseparation, 10 (2002) 163.
• 38. V.I. Lozinsky, I.Y. Galaev, F.M. Plieva, I.N. Savina, H. Jungvid, B. Mattiasson, Polymeric cryogels as promising materials of biotechnological interest, Trends in Biotechnol., 10 (2003) 445.
• 39. N. Demiryas, N. Tüzmen, I.Y. Galaev, E. Pişkin, A. Denizli, Poly(acrylamide-allyl glycidyl ether) Cryogel as a Novel Stationary Phase in Dye-Affinity Chromatography, J. Appl. Polym. Sci., 105 (2007) 1808.
• 40. G.S. Chaga, Twenty-five years of immobilized metal ion affinity chromatography, past, present and future, J. Biochem. Bioph. Methods, 49 (2001) 313.
• 41. F.H. Arnold, Metal-affinity separations, a new dimension in protein processing, Bio/Technol., 9 (1991) 150.
• 42. P. Arvidsson, F.M. Plieva, I.N. Savina, V.I. Lozinsky, S. Fexby, L. Bülow, I.Y. Galaev, B. Mattiasson, Chromatography of microbial cells using continuous supermacroporous affinity and ion-exchange columns, J. Chromatogr. A, 977 (2002) 27.
• 43. G.T. Hermanson, A.K. Mallia, P.K. Smith, Immobilized Cibacron Blue F3GA, in: Immobilized Affinity Ligand Techniques, Academic Pres Inc., California, USA, 1992.