BibTex RIS Kaynak Göster

Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes

Yıl 2012, Cilt: 40 Sayı: 4, 419 - 426, 01.09.2012

Öz

The FT-IR, FT-Raman and far-IR spectra of two dimensional coordination polymer compounds, M 6AU 2Ni CN 4 where M = Mn, Co, Ni and Cd; 6AU = 6-aminouracil = 4-amino-2,6-dihydroxypyrimidine were reported for the first time. 6-aminouracil molecules are found to involve coordination through one of the pyrimidine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni CN 42- ions bridged by M 6AU 22+ cations. Vibrational bands originated from both 6AU and Ni CN 4 group were assigned.

Kaynakça

  • E. Miszczak-Zaborska, K. Woźniak, The activity of thymidine phosphorylase obtained from human uterine leiomyomas and studied in the presence of pyrimidine derivatives, Z. Naturforsch. C., 52 (1997) 670.
  • L. Langen, G. Etzold, D. Barwolff, B. Preussel, Inhibition of thymine phophorylose by 6-aminothymine and derivates of 6-aminouracil, Biochem. Pharm., 16 (1967) 1833.
  • Z. Seferoğlu, N. Ertan, Synthesis, characterization and spectroscopic properties of some new phenylazo-6- aminouracil, Cent. Eur. J. Chem., 6 (2008) 81.
  • D. J. Brown, in: A. R. Katrizky, C. W. Rees, (Eds), Comprehensive Heterocyclic Chemistry, Pergamon, Oxford, New York, (1984) 55.
  • A. A. Mustafa, A. A. Alhaider, A. A. Hijazi, Study on the renal and cardiovascular activities of aminouracil derivatives, Pharm. Res., 6 (1989) 394.
  • V.M. Nesterov, L.A. Kucherya, L.A. Tretyakova, L.I. Markitantova, Methods of drugs synthesis and the technology of drag production: Improved synthesis of 6-aminouracil, Phar. Chem. J., 15 (1981) 591.
  • C.D. Mol, A.S. Arvai, G. Slupphaug, B. Kavli, I. Alseth, H. E. Krokan, J. Tainer, Crystal Structure and Mutational Analysis of Human Uracil-DNA Glycosylase: Structural Basisi for Specificity and Catalysis, Cell, 80 (1995) 869.
  • D. Dobritzsch, G. Schneider, K. Schnackerz, Y. Lindqvist, Crystal structure of dihydropyrimidine dehydrogenose, a major determinant of the pharmacokinetics of the anti-cancer drug 5-fluorouracil, The EMBO J., 20 (2001) 650.
  • T. Iwamoto, in: J.L. Atwood, J.E.D. Davies, D.D. Mac Nicol, (Eds.), Inclusion Compounds, vol. 5, Springer, Berlin, (Chapter 6), 177.
  • T. Iwamoto, Past, present and future of the clathrate inclusion compounds built of cyanometallate hosts, J. Incl. Phenom., 24 (1996) 61.
  • S. Aruna, G. Shanmugam, Vibrational assignments of six-membered heterocyclic compounds: normal vibrations of 6-amino uracil and 6-amino 2-thio uracil, Spectrochim, Acta A, 41 (1985) 531.
  • S. Akyüz, J.E.D. Davies, Solid-state vibrational spectroscopy: Part 11. An infrared and Raman vibrational spectroscopic study of metal(II) halide aniline complexes, J. Mol. Struct., 435 (1982) 157.
  • K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, fourth ed., John Wiley & Sons Inc., New York, (1986) 279.
  • B. Ishimoto, K. Tonan, S.I. Ikawa, Intramolecular hydrogen bonding of the C-terminal NH2 groups of small peptide amides in solution, Spectrochim, Acta A, 55 (1999) 2321.
  • M.S. Masoud, S.A.A. El-Enein, M.E. Ayad, A.S. Goher, Spectral and magnetic proporties of phenylazo-6- aminouracil complexes, Spectrochim, Acta A, 60 (2004) 77.
  • C. Bayrak, S. Bayarı, Vibrational and DFT studies of Creatinine and Its Metal Complexes, Hacettepe J. Biol.& Chem., 38 (2010) 107.
  • S. Akyüz, L. Andreeva, B. Minceva-Sukarova, G. Başar, Vibrational spectroscopic study of two dimensional polymer compounds of pyrazinamide, J. Mol. Struct., 399 (2007) 834.
  • S. Akyüz, T. Akyüz, Raman spectroscopic study of two dimensional polymer compounds of 2-aminopyrimidine, J. Mol. Struct., 277 (2005) 744.
  • S. Akyüz, T. Akyüz, Y. Akkaya, E. Akalin, Infrared and Raman spectroscopic study of 4-aminopyrimidine tetracyanonickelate complexes, J. Mol. Struct., 403 (2007) 834.
  • S. Akyüz, T. Akyüz, Vibrational specroscopic study of 4-aminopyrimidine complexes, J. Mol. Struct., 37 (2009) 924.
  • L.B. Andreeva, B. Minceva-Sukarova, Vibrational spectra of partially debenzenated analogues in some en-Td-Type clathrates, J. Mol. Struct., 431 (1997) 408.
  • B. Minceva-Sukarova, L. Andreeva, S. Akyüz, C. A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, (2002) 66.
  • S. Akyüz, A.B. Dempster, R.L.Morehouse, Host-guest interactions and stability of Hofmann-type benzene and aniline clathrates studied by IR spectroscopy, Spectrochim. Acta, 30A (1974) 1989.

6-Aminouracil Tetracyanonickelate Komplekslerinin Titreşim Spektroskopisi ile İncelenmesi

Yıl 2012, Cilt: 40 Sayı: 4, 419 - 426, 01.09.2012

Öz

İ ki boyutlu kordinasyon polimer kompleksleri M 6AU 2Ni CN 4 burada M = Mn, Co, Ni ve Cd; 6AU = 6-aminouracil = 4-amino-2,6-dihydroxypyrimidine ilk kez elde edilmiş ve FT-IR, FT-Raman ve far-IR ile incelenmiştir. 6-aminouracil molekülleri pirimidin halkasının azot atomlarının biri ile kordinasyon yaptığı bulunmuştur. Ni CN 2- iyonları ile M 6AU 2+ katyonlarının kordinasyonu sonucu, Hofmann tipi iki boyutlu kordinasyon polimer bileşikleri oluşturduğu spektral özellikler ile desteklenmiştir. 6AU ve Ni CN 4 grubunun her ikisinden kaynaklanan titreşim bandları tanımlanmıştır

Kaynakça

  • E. Miszczak-Zaborska, K. Woźniak, The activity of thymidine phosphorylase obtained from human uterine leiomyomas and studied in the presence of pyrimidine derivatives, Z. Naturforsch. C., 52 (1997) 670.
  • L. Langen, G. Etzold, D. Barwolff, B. Preussel, Inhibition of thymine phophorylose by 6-aminothymine and derivates of 6-aminouracil, Biochem. Pharm., 16 (1967) 1833.
  • Z. Seferoğlu, N. Ertan, Synthesis, characterization and spectroscopic properties of some new phenylazo-6- aminouracil, Cent. Eur. J. Chem., 6 (2008) 81.
  • D. J. Brown, in: A. R. Katrizky, C. W. Rees, (Eds), Comprehensive Heterocyclic Chemistry, Pergamon, Oxford, New York, (1984) 55.
  • A. A. Mustafa, A. A. Alhaider, A. A. Hijazi, Study on the renal and cardiovascular activities of aminouracil derivatives, Pharm. Res., 6 (1989) 394.
  • V.M. Nesterov, L.A. Kucherya, L.A. Tretyakova, L.I. Markitantova, Methods of drugs synthesis and the technology of drag production: Improved synthesis of 6-aminouracil, Phar. Chem. J., 15 (1981) 591.
  • C.D. Mol, A.S. Arvai, G. Slupphaug, B. Kavli, I. Alseth, H. E. Krokan, J. Tainer, Crystal Structure and Mutational Analysis of Human Uracil-DNA Glycosylase: Structural Basisi for Specificity and Catalysis, Cell, 80 (1995) 869.
  • D. Dobritzsch, G. Schneider, K. Schnackerz, Y. Lindqvist, Crystal structure of dihydropyrimidine dehydrogenose, a major determinant of the pharmacokinetics of the anti-cancer drug 5-fluorouracil, The EMBO J., 20 (2001) 650.
  • T. Iwamoto, in: J.L. Atwood, J.E.D. Davies, D.D. Mac Nicol, (Eds.), Inclusion Compounds, vol. 5, Springer, Berlin, (Chapter 6), 177.
  • T. Iwamoto, Past, present and future of the clathrate inclusion compounds built of cyanometallate hosts, J. Incl. Phenom., 24 (1996) 61.
  • S. Aruna, G. Shanmugam, Vibrational assignments of six-membered heterocyclic compounds: normal vibrations of 6-amino uracil and 6-amino 2-thio uracil, Spectrochim, Acta A, 41 (1985) 531.
  • S. Akyüz, J.E.D. Davies, Solid-state vibrational spectroscopy: Part 11. An infrared and Raman vibrational spectroscopic study of metal(II) halide aniline complexes, J. Mol. Struct., 435 (1982) 157.
  • K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, fourth ed., John Wiley & Sons Inc., New York, (1986) 279.
  • B. Ishimoto, K. Tonan, S.I. Ikawa, Intramolecular hydrogen bonding of the C-terminal NH2 groups of small peptide amides in solution, Spectrochim, Acta A, 55 (1999) 2321.
  • M.S. Masoud, S.A.A. El-Enein, M.E. Ayad, A.S. Goher, Spectral and magnetic proporties of phenylazo-6- aminouracil complexes, Spectrochim, Acta A, 60 (2004) 77.
  • C. Bayrak, S. Bayarı, Vibrational and DFT studies of Creatinine and Its Metal Complexes, Hacettepe J. Biol.& Chem., 38 (2010) 107.
  • S. Akyüz, L. Andreeva, B. Minceva-Sukarova, G. Başar, Vibrational spectroscopic study of two dimensional polymer compounds of pyrazinamide, J. Mol. Struct., 399 (2007) 834.
  • S. Akyüz, T. Akyüz, Raman spectroscopic study of two dimensional polymer compounds of 2-aminopyrimidine, J. Mol. Struct., 277 (2005) 744.
  • S. Akyüz, T. Akyüz, Y. Akkaya, E. Akalin, Infrared and Raman spectroscopic study of 4-aminopyrimidine tetracyanonickelate complexes, J. Mol. Struct., 403 (2007) 834.
  • S. Akyüz, T. Akyüz, Vibrational specroscopic study of 4-aminopyrimidine complexes, J. Mol. Struct., 37 (2009) 924.
  • L.B. Andreeva, B. Minceva-Sukarova, Vibrational spectra of partially debenzenated analogues in some en-Td-Type clathrates, J. Mol. Struct., 431 (1997) 408.
  • B. Minceva-Sukarova, L. Andreeva, S. Akyüz, C. A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, (2002) 66.
  • S. Akyüz, A.B. Dempster, R.L.Morehouse, Host-guest interactions and stability of Hofmann-type benzene and aniline clathrates studied by IR spectroscopy, Spectrochim. Acta, 30A (1974) 1989.
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Research Article
Yazarlar

Celal Bayrak Bu kişi benim

Yayımlanma Tarihi 1 Eylül 2012
Yayımlandığı Sayı Yıl 2012 Cilt: 40 Sayı: 4

Kaynak Göster

APA Bayrak, C. (2012). Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes. Hacettepe Journal of Biology and Chemistry, 40(4), 419-426.
AMA Bayrak C. Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes. HJBC. Eylül 2012;40(4):419-426.
Chicago Bayrak, Celal. “Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes”. Hacettepe Journal of Biology and Chemistry 40, sy. 4 (Eylül 2012): 419-26.
EndNote Bayrak C (01 Eylül 2012) Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes. Hacettepe Journal of Biology and Chemistry 40 4 419–426.
IEEE C. Bayrak, “Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes”, HJBC, c. 40, sy. 4, ss. 419–426, 2012.
ISNAD Bayrak, Celal. “Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes”. Hacettepe Journal of Biology and Chemistry 40/4 (Eylül 2012), 419-426.
JAMA Bayrak C. Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes. HJBC. 2012;40:419–426.
MLA Bayrak, Celal. “Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes”. Hacettepe Journal of Biology and Chemistry, c. 40, sy. 4, 2012, ss. 419-26.
Vancouver Bayrak C. Vibrational Spectroscopic Study of 6-Aminouracil Tetracyanonickelate Complexes. HJBC. 2012;40(4):419-26.

HACETTEPE JOURNAL OF BIOLOGY AND CHEMİSTRY

Copyright © Hacettepe University Faculty of Science

http://www.hjbc.hacettepe.edu.tr/

https://dergipark.org.tr/tr/pub/hjbc