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IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS

Yıl 2021, Cilt: 5 Sayı: 2, 164 - 170, 31.08.2021
https://doi.org/10.46519/ij3dptdi.949271

Öz

In order to enhance magnetic and thermal properties of polymeric structures in 3D (three-dimensional) form, stereolithography technique is an alternative way to in-situ synthesize magnetic nanoparticles such as iron, cobalt and nickel in photocurable resin during laser photopolymerization for magnetic micromachines. By using different types of magnetic nanoparticles in the resin, the formed structure exhibits different mechanical, thermal and magnetic behaviors.

In this study, magnetic nanoparticles were synthesized by laser irradiation to investigate the effects of the magnetic nanoparticles in 3D structure. Under constant metal salt amount and forming layer thickness, morphological, characterization, mechanical, thermal and magnetic properties were conducted by scanning electron microscope (SEM), transmission electron microscope (TEM), tensile test, thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM), respectively. As a result, it observed that the magnetic properties of iron-based polymeric structures show higher saturation magnetization (0.0145 emu/gr) while thermal stability remains low for other magnetic embedded polymer samples. In the presence of magnetic nanoparticles, its mechanical strength decreased from 14 MPa to 5 MPa for all experiments against pure 3D resin, as well as it leads to more fragile structures. Finally, for each sample, singular magnetic nanoparticles were formed in the polymer matrix and verified that nanoparticles are completely reduced. 

Kaynakça

  • 1. Bártolo, P.J., “Stereolithography: materials, processes and applications”, Springer, New York, 2011.
  • 2. Lantean, S., Barrera, G., Pirri, C.F., Tiberto, P., Sangermano, M., Roppolo, I., Rizza, G., “3D Printing of Magnetoresponsive Polymeric Materials with Tunable Mechanical and Magnetic Properties by Digital Light Processing”, Advanced Materials Technologies, Volume 4, Issue 11, Article Number 1900505, 2019.
  • 3. Martin, J.J., Fiore, B.E., Erb, R.M., “Designing bioinspired composite reinforcement architectures via 3D magnetic printing”, Nature Communications, Volume 6, Article Number 8641, 2015.
  • 4. Gurr, M., Hofmann, D., Ehm, M., Thomann, Y., Kübler, R., Mülhaupt, R., “Acrylic nanocomposite resins for use in stereolithography and structural light modulation based rapid prototyping and rapid manufacturing technologies”, Advanced Functional Materials, Volume 18, Issue 16, Pages 2390–2397, 2008.
  • 5. Weng, Z., Zhou, Y., Lin, W., Senthil, T., Wu, L., “Structure–property relationship of nano enhanced stereolithography resin for desktop SLA 3D printer”, Composites Part A: Applied Science and Manufacturing, Volume 88, Pages 234-242, 2016.
  • 6. Leigh, S.J., Purssell, C.P., Bowen, J., Hutchins, D.A., Covington, J.A., Billson, D.R., “A miniature flow sensor fabricated by micro-stereolithography employing a magnetite/acrylic nanocomposite resin”, Sensors Actuators A: Physical, Volume 168, Issue 1, Pages 66–71, 2011.
  • 7. Yasui, M., Ikuta, K., “Modeling and measurement of curing properties of photocurable polymer containing magnetic particles and microcapsules”, Microsystems & Nanoengineering, Volume 3, Article Number 17035, 2017.
  • 8. Sandoval, J.H., Wicker, R.B., “Functionalizing stereolithography resins: effects of dispersed multi-walled carbon nanotubes on physical properties”, Rapid Prototyping Journal, Volume 12, Issue 5, Pages 292-303, 2006.
  • 9. Fantino, E., Chiappone, A., Roppolo, I., Manfredi, D., Bongiovanni, R., Pirri, C.F., Calignano, F., “3D printing of conductive complex structures with in situ generation of silver nanoparticles”, Advanced Materials, Volume 28, Issue 19, Pages 3712-3717, 2016.
  • 10. Sandoval, J.H., Soto, K.F., Murr, L.E., Wicker, R.B., “Nanotailoring photocrosslinkable epoxy resins with multi-walled carbon nanotubes for stereolithography layered manufacturing”, Journal of Materials Science, Volume 42, Issue 1, Pages 156-165, 2007.
  • 11. Aktitiz, İ., Aydın, K, Topçu, A., “Characterization of TiO2 Nanoparticle–Reinforced Polymer Nanocomposite Materials Printed by Stereolithography Method”, Journal of Materials Engineering and Performance, Just Accepted, 2021.
  • 12. Taormina, G., Sciancalepore, C., Bondioli, F., Messori, M., “Special Resins for Stereolithography: In Situ Generation of Silver Nanoparticles”, Polymers, Volume 10, Issue 2, Article Number 212, 2018.

IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS

Yıl 2021, Cilt: 5 Sayı: 2, 164 - 170, 31.08.2021
https://doi.org/10.46519/ij3dptdi.949271

Öz

In order to enhance magnetic and thermal properties of polymeric structures in 3D (three-dimensional) form, stereolithography technique is an alternative way to in-situ synthesize magnetic nanoparticles such as iron, cobalt and nickel in photocurable resin during laser photopolymerization for magnetic micromachines. By using different types of magnetic nanoparticles in the resin, the formed structure exhibits different mechanical, thermal and magnetic behaviors.

In this study, magnetic nanoparticles were synthesized by laser irradiation to investigate the effects of the magnetic nanoparticles in 3D structure. Under constant metal salt amount and forming layer thickness, morphological, characterization, mechanical, thermal and magnetic properties were conducted by scanning electron microscope (SEM), transmission electron microscope (TEM), tensile test, thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM), respectively. As a result, it observed that the magnetic properties of iron-based polymeric structures show higher saturation magnetization (0.0145 emu/gr) while thermal stability remains low for other magnetic embedded polymer samples. In the presence of magnetic nanoparticles, its mechanical strength decreased from 14 MPa to 5 MPa for all experiments against pure 3D resin, as well as it leads to more fragile structures. Finally, for each sample, singular magnetic nanoparticles were formed in the polymer matrix and verified that nanoparticles are completely reduced. 

Kaynakça

  • 1. Bártolo, P.J., “Stereolithography: materials, processes and applications”, Springer, New York, 2011.
  • 2. Lantean, S., Barrera, G., Pirri, C.F., Tiberto, P., Sangermano, M., Roppolo, I., Rizza, G., “3D Printing of Magnetoresponsive Polymeric Materials with Tunable Mechanical and Magnetic Properties by Digital Light Processing”, Advanced Materials Technologies, Volume 4, Issue 11, Article Number 1900505, 2019.
  • 3. Martin, J.J., Fiore, B.E., Erb, R.M., “Designing bioinspired composite reinforcement architectures via 3D magnetic printing”, Nature Communications, Volume 6, Article Number 8641, 2015.
  • 4. Gurr, M., Hofmann, D., Ehm, M., Thomann, Y., Kübler, R., Mülhaupt, R., “Acrylic nanocomposite resins for use in stereolithography and structural light modulation based rapid prototyping and rapid manufacturing technologies”, Advanced Functional Materials, Volume 18, Issue 16, Pages 2390–2397, 2008.
  • 5. Weng, Z., Zhou, Y., Lin, W., Senthil, T., Wu, L., “Structure–property relationship of nano enhanced stereolithography resin for desktop SLA 3D printer”, Composites Part A: Applied Science and Manufacturing, Volume 88, Pages 234-242, 2016.
  • 6. Leigh, S.J., Purssell, C.P., Bowen, J., Hutchins, D.A., Covington, J.A., Billson, D.R., “A miniature flow sensor fabricated by micro-stereolithography employing a magnetite/acrylic nanocomposite resin”, Sensors Actuators A: Physical, Volume 168, Issue 1, Pages 66–71, 2011.
  • 7. Yasui, M., Ikuta, K., “Modeling and measurement of curing properties of photocurable polymer containing magnetic particles and microcapsules”, Microsystems & Nanoengineering, Volume 3, Article Number 17035, 2017.
  • 8. Sandoval, J.H., Wicker, R.B., “Functionalizing stereolithography resins: effects of dispersed multi-walled carbon nanotubes on physical properties”, Rapid Prototyping Journal, Volume 12, Issue 5, Pages 292-303, 2006.
  • 9. Fantino, E., Chiappone, A., Roppolo, I., Manfredi, D., Bongiovanni, R., Pirri, C.F., Calignano, F., “3D printing of conductive complex structures with in situ generation of silver nanoparticles”, Advanced Materials, Volume 28, Issue 19, Pages 3712-3717, 2016.
  • 10. Sandoval, J.H., Soto, K.F., Murr, L.E., Wicker, R.B., “Nanotailoring photocrosslinkable epoxy resins with multi-walled carbon nanotubes for stereolithography layered manufacturing”, Journal of Materials Science, Volume 42, Issue 1, Pages 156-165, 2007.
  • 11. Aktitiz, İ., Aydın, K, Topçu, A., “Characterization of TiO2 Nanoparticle–Reinforced Polymer Nanocomposite Materials Printed by Stereolithography Method”, Journal of Materials Engineering and Performance, Just Accepted, 2021.
  • 12. Taormina, G., Sciancalepore, C., Bondioli, F., Messori, M., “Special Resins for Stereolithography: In Situ Generation of Silver Nanoparticles”, Polymers, Volume 10, Issue 2, Article Number 212, 2018.
Toplam 12 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Biyomateryaller
Bölüm Araştırma Makalesi
Yazarlar

Mehmet Fahri Saraç 0000-0002-0760-5569

Yayımlanma Tarihi 31 Ağustos 2021
Gönderilme Tarihi 7 Haziran 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 5 Sayı: 2

Kaynak Göster

APA Saraç, M. F. (2021). IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS. International Journal of 3D Printing Technologies and Digital Industry, 5(2), 164-170. https://doi.org/10.46519/ij3dptdi.949271
AMA Saraç MF. IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS. IJ3DPTDI. Ağustos 2021;5(2):164-170. doi:10.46519/ij3dptdi.949271
Chicago Saraç, Mehmet Fahri. “IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS”. International Journal of 3D Printing Technologies and Digital Industry 5, sy. 2 (Ağustos 2021): 164-70. https://doi.org/10.46519/ij3dptdi.949271.
EndNote Saraç MF (01 Ağustos 2021) IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS. International Journal of 3D Printing Technologies and Digital Industry 5 2 164–170.
IEEE M. F. Saraç, “IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS”, IJ3DPTDI, c. 5, sy. 2, ss. 164–170, 2021, doi: 10.46519/ij3dptdi.949271.
ISNAD Saraç, Mehmet Fahri. “IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS”. International Journal of 3D Printing Technologies and Digital Industry 5/2 (Ağustos 2021), 164-170. https://doi.org/10.46519/ij3dptdi.949271.
JAMA Saraç MF. IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS. IJ3DPTDI. 2021;5:164–170.
MLA Saraç, Mehmet Fahri. “IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS”. International Journal of 3D Printing Technologies and Digital Industry, c. 5, sy. 2, 2021, ss. 164-70, doi:10.46519/ij3dptdi.949271.
Vancouver Saraç MF. IN-SITU SYNTHESIS OF 3D-PRINTED MAGNETIC NANOPARTICLES EMBEDDED PHOTOPOLYMERS. IJ3DPTDI. 2021;5(2):164-70.

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