Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen
Yıl 2024,
Cilt: 9 Sayı: 4, 559 - 579, 25.12.2024
Kemalcan Sevük
,
Berre Kümük
,
Mustafa İlbaş
Öz
This study experimentally investigates the purification of synthesis gas using the pressure swing adsorption (PSA) method to isolate H₂. The effects of different pressures and flow rates on adsorption durations has been examined. The lowest adsorption capacity has been observed at 5 bar, while the highest has been recorded at 15 bar. It has been observed that the column adsorption capacity increases with increasing pressure. The results indicate an increase in column retention capacity with pressure. The optimum adsorption duration has been found to be 3 minutes at 5 bar and 9 minutes at 15 bar. Additionally, significant effects of p/f ratio and pressurization direction on H₂ purity has been observed. These findings are consistent with the study’s objective which is to provide insights on optimization of PSA parameters and enhancing hydrogen purity. The results support a broader understanding of PSA technology and potential applications of hydrogen purification in industrial areas and paves the way for further progress. Future research suggests that modeling studies could provide further insights and the use of different adsorbents may enhance H₂ purity.
Teşekkür
The authors would like to thank to Lentatek Space Aviation and Technology for the experimental setup.
Kaynakça
- [1] Lorenz TB, Jiang L, Fox VG. Recent Advances in Simulation and Optimal Design of Pressure
Swing Adsorption Systems. Separation & Purification Reviews. 2005;33(1):1-39.
- [2] Zhang R, Shen Y, Tang Z, Li W, Zhang D. A Review of Numerical Research on the Pressure
Swing Adsorption Process. Processes. 2022;10(5):812.
- [3] Voss C. Applications of Pressure Swing Adsorption Technology. Adsorption. 2005;11:527-9.
- [4] Riboldi L, Bolland O. Overview on Pressure Swing Adsorption (PSA) as CO2 Capture
Technology: State-of-the-Art, Limits and Potentials. Energy Procedia. 2017;114:2390-400.
- [5] Zhu X, Li S, Shi Y, Cai N. Recent advances in elevated-temperature pressure swing adsorption
for carbon capture and hydrogen production. Progress in Energy and Combustion Science.
2019;75:100784.
- [6] Shabbani HJ, Othman MR, Al-Janabi SK, Barron AR, Helwani Z. H2 purification employing
pressure swing adsorption process: Parametric and bibliometric review. Renew Sustain Energy
Rev. 2024;50:674-99.
- [7] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a
PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical
Engineering. 2017;5(12):10.
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of synthesis gas. Adsorption. 2008;14(5-6):583-90.
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process for CO2 recovery. Korean J Chem Eng. 2003;20(4):617-23.
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on pressure swing adsorption performance. Ind Eng Chem Res. 2021;60(37):13684-91.
- [11] Beeyani A, Singh K, Vyas R, Kumar S, Kumar S. Parametric studies and simulation of PSA
process for oxygen production from air. Pol J Chem Technol. 2010;12(1):18-28.
- [12] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and Kinetic Behaviour of CO2 Adsorption
onto Zeolites, Carbon Molecular Sieve and Activated Carbons. Energy Procedia. 2017;114:2450
9.
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Metallurgical Transactions A. 1974;5(7):1757-65.
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Cracking: Theory and Practice. Houston: NACE International; 1990. p. 55-77.
- [15] Xiao J, Peng Y, Benard P, Chahine R. Thermal effects on breakthrough curves of pressure
swing adsorption for hydrogen purification. International Journal of Hydrogen Energy.
2015;40(9):3706-13.
- [16] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and kinetic behaviour of CO2 adsorption
onto zeolites, carbon molecular sieve and activated carbons. Energy Procedia. 2017;114:2450-9.
- [17] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of
a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical
Engineering. 2017;5:1250-9.
- [18] Liu Y, Shen X, Ding W, Hou J. Adsorption of CO2 and CH4 on shale under high pressure:
An experimental study and thermodynamic modeling. Journal of Chemical & Engineering Data.
2021;66(1):185-94.
- [19] Khosravi Z, Rajabzadeh A, Bahrami S. Adsorption behavior of carbon dioxide on chemically
modified activated carbons: A study on equilibrium, kinetic, and thermodynamic properties.
Adsorption Science & Technology. 2019;37(1-2):181-97.
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Competitive adsorption of a binary mixture of gases on activated carbon: Effects of surface
chemistry. Microporous and Mesoporous Materials. 2018;263:169-79.
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Adsorption. 2000;6(4):283-300.
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Yıl 2024,
Cilt: 9 Sayı: 4, 559 - 579, 25.12.2024
Kemalcan Sevük
,
Berre Kümük
,
Mustafa İlbaş
Kaynakça
- [1] Lorenz TB, Jiang L, Fox VG. Recent Advances in Simulation and Optimal Design of Pressure
Swing Adsorption Systems. Separation & Purification Reviews. 2005;33(1):1-39.
- [2] Zhang R, Shen Y, Tang Z, Li W, Zhang D. A Review of Numerical Research on the Pressure
Swing Adsorption Process. Processes. 2022;10(5):812.
- [3] Voss C. Applications of Pressure Swing Adsorption Technology. Adsorption. 2005;11:527-9.
- [4] Riboldi L, Bolland O. Overview on Pressure Swing Adsorption (PSA) as CO2 Capture
Technology: State-of-the-Art, Limits and Potentials. Energy Procedia. 2017;114:2390-400.
- [5] Zhu X, Li S, Shi Y, Cai N. Recent advances in elevated-temperature pressure swing adsorption
for carbon capture and hydrogen production. Progress in Energy and Combustion Science.
2019;75:100784.
- [6] Shabbani HJ, Othman MR, Al-Janabi SK, Barron AR, Helwani Z. H2 purification employing
pressure swing adsorption process: Parametric and bibliometric review. Renew Sustain Energy
Rev. 2024;50:674-99.
- [7] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a
PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical
Engineering. 2017;5(12):10.
- [8] Yang SI, Choi DY, Jang SC, et al. Hydrogen separation by multi-bed pressure swing adsorption
of synthesis gas. Adsorption. 2008;14(5-6):583-90.
- [9] Choi WK, Kwon TI, Yeo YK, et al. Optimal operation of the pressure swing adsorption (PSA)
process for CO2 recovery. Korean J Chem Eng. 2003;20(4):617-23.
- [10] De Witte N, Denayer JFM, Van Assche TRC. Effect of adsorption duration and purge flowrate
on pressure swing adsorption performance. Ind Eng Chem Res. 2021;60(37):13684-91.
- [11] Beeyani A, Singh K, Vyas R, Kumar S, Kumar S. Parametric studies and simulation of PSA
process for oxygen production from air. Pol J Chem Technol. 2010;12(1):18-28.
- [12] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and Kinetic Behaviour of CO2 Adsorption
onto Zeolites, Carbon Molecular Sieve and Activated Carbons. Energy Procedia. 2017;114:2450
9.
- [13] Fletcher FB, Leitch HR. Hydrogen Embrittlement of Austenitic Stainless Steels.
Metallurgical Transactions A. 1974;5(7):1757-65.
- [14] Gangloff RP. Hydrogen-Assisted Cracking. In: Sedriks AJ, editor. Stress Corrosion
Cracking: Theory and Practice. Houston: NACE International; 1990. p. 55-77.
- [15] Xiao J, Peng Y, Benard P, Chahine R. Thermal effects on breakthrough curves of pressure
swing adsorption for hydrogen purification. International Journal of Hydrogen Energy.
2015;40(9):3706-13.
- [16] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and kinetic behaviour of CO2 adsorption
onto zeolites, carbon molecular sieve and activated carbons. Energy Procedia. 2017;114:2450-9.
- [17] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of
a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical
Engineering. 2017;5:1250-9.
- [18] Liu Y, Shen X, Ding W, Hou J. Adsorption of CO2 and CH4 on shale under high pressure:
An experimental study and thermodynamic modeling. Journal of Chemical & Engineering Data.
2021;66(1):185-94.
- [19] Khosravi Z, Rajabzadeh A, Bahrami S. Adsorption behavior of carbon dioxide on chemically
modified activated carbons: A study on equilibrium, kinetic, and thermodynamic properties.
Adsorption Science & Technology. 2019;37(1-2):181-97.
- [20] Lillo-Ródenas MA, Fletcher AJ, Thomas KM, Cazorla-Amorós D, Linares-Solano A.
Competitive adsorption of a binary mixture of gases on activated carbon: Effects of surface
chemistry. Microporous and Mesoporous Materials. 2018;263:169-79.
- [21] Sircar S, Golden TC. Pressure swing adsorption technology for hydrogen production.
Adsorption. 2000;6(4):283-300.
- [22] Yang RT. Gas separation by adsorption processes. Butterworth-Heinemann; 1987.