Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications

Ahmet Tumbul

doi:10.46460/ijiea.1689650

EN TR

Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications

Abstract

Presented report, Cu2CoSnS4 (CCTS) semiconductor was growth on glass substrate by using chemical routes. The physical properties of sample were qualified by using XRD Raman spectrometer, SEM with EDS, UV-Vis spectrometer and AFM. The XRD measurement confirmed that the CCTS has stannite crystal structure with a preferential orientation throughout the (112) direction. The Raman measurement verified the presence of characteristic peak which occurred at 320 cm-1 correspond A1 vibrational mode. The EDS spectrum with mapping revealed the existence of the elements ( S, Sn, Co, Cu) in compound and these elements homogeneously distrubuted on the surfaces of the sample. The combination of AFM and SEM characterization highlighted the structural integrity of the CCTS thin film. Optical absorbance analyses showed the band gap value of sample (~1.33 eV) was suitable for solar cell applications. Besides, ıt could be said that fabricated device n-ITO/p-CCTS/Ag was convenient to use in renewable energy applications. These findings open up the possibility to explore new generation materials which have abundant elements in earth crust without any dangerous and rare/costly elements such as selenium, gallium, and indium.

Keywords

Cu2CoSnS4 semiconductor , Solution process , Thin film absorber , Sulfur-rich stoichiometry

Yenilenebilir Enerji Uygulamaları için Cu2CoSnS4 (CCTS) Soğurucu Malzeme Sentezi ve Karakterizasyonu

Öz

Bu çalışmada kimyasal kaplama tekniği kullanılarak Cu2CoSnS4 (CCTS) yarıiletken ince film sentezlenmiştir. Üretilen örneğin fiziksel özellikleri XRD, Raman Spektrometresi, SEM, EDS, AFM ve UV-Vis Spektrometresi kullanılarak incelenmiştir. X-ışını ölçümleri CCTS yarıiletkenin (112) tercihli yönelimli stanit kristal yapısında olduğunu göstermiştir. Ayrıca raman ölçümünden de 320 cm-1 konumundaki pikin CCTS yarıiletken malzemesinin A1 titreşim moduna ait olduğu doğrulanmıştır. Enerji Dağılımlı X-ışını vet haritalama teknikleri malzemenin yapısında bulunan Cu, Co, Sn, S elementlerinin ince film yüzeyine homojen bir şekilde dağıldıgını ortaya koymuştur. AFM ve SEM karakterizasyonu CCTS ince filmin yapısal bütünlügünün vurgulamıştır. Optik soğurma analizi ile CCTS ince filmin yasak enerji band değerinin yaklaşık 1.33 eV oldugunu ve bu değerin güneş hücresi uygulamaları için ideal olduğu gösterilmiştir. Bunun yanında üretilen n-ITO/p-CCTs/Ag cihazının yenilenebilir enerji uygulamaları için kullanılmaya elverişli oldugu söylenebilir. Bu bulgular; selenyum, galyum ve indiyum gibi tehlikeli, doğada az bulunan ve maliyetli elementler içermeyen, yeni nesil malzemelerin araştırılmasına olanak sağlamaktadır.

Anahtar Kelimeler

Cu2CoSnS4 yarıiletkeni , Çözelti yöntemi , İnce film soğurucu , Sülfür-zengin kimyasal içerik.

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Malzeme Karekterizasyonu

Bölüm

Araştırma Makalesi

Yazarlar

Ahmet Tumbul ^*
0000-0003-3790-9667
Türkiye

Yayımlanma Tarihi

29 Aralık 2025

Gönderilme Tarihi

2 Mayıs 2025

Kabul Tarihi

28 Temmuz 2025

Yayımlandığı Sayı

Yıl 2025 Cilt: 9 Sayı: 2

DOI

https://doi.org/10.46460/ijiea.1689650

IZ

https://izlik.org/JA94AT86BK

APA

Tumbul, A. (2025). Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications. International Journal of Innovative Engineering Applications, 9(2), 149-154. https://doi.org/10.46460/ijiea.1689650

AMA

1.Tumbul A. Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications. ijiea, IJIEA. 2025;9(2):149-154. doi:10.46460/ijiea.1689650

Chicago

Tumbul, Ahmet. 2025. “Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications”. International Journal of Innovative Engineering Applications 9 (2): 149-54. https://doi.org/10.46460/ijiea.1689650.

EndNote

Tumbul A (01 Aralık 2025) Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications. International Journal of Innovative Engineering Applications 9 2 149–154.

IEEE

[1]A. Tumbul, “Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications”, ijiea, IJIEA, c. 9, sy 2, ss. 149–154, Ara. 2025, doi: 10.46460/ijiea.1689650.

ISNAD

Tumbul, Ahmet. “Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications”. International Journal of Innovative Engineering Applications 9/2 (01 Aralık 2025): 149-154. https://doi.org/10.46460/ijiea.1689650.

JAMA

1.Tumbul A. Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications. ijiea, IJIEA. 2025;9:149–154.

MLA

Tumbul, Ahmet. “Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications”. International Journal of Innovative Engineering Applications, c. 9, sy 2, Aralık 2025, ss. 149-54, doi:10.46460/ijiea.1689650.

Vancouver

1.Ahmet Tumbul. Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications. ijiea, IJIEA. 01 Aralık 2025;9(2):149-54. doi:10.46460/ijiea.1689650

Synthesis and Characterization of Cu2CoSnS4 (CCTS) Absorber Material for Renewable Energy Applications

Abstract

Keywords

Yenilenebilir Enerji Uygulamaları için Cu2CoSnS4 (CCTS) Soğurucu Malzeme Sentezi ve Karakterizasyonu

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster