Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio

Murat Kıranşan

doi:10.46460/ijiea.1840634

EN TR

Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio

Öz

In this study, the synthesis of TBA-Br/Mt organoclay at different cation exchange ratios was carried out using tetrabutyl ammonium bromide (TBA-Br) surfactant on Montmorillonite (Mt) clay. Due to the swelling properties of Mt layers with water, it’s possible to disperse or deaggregate clay aggregates into a single layer under appropriate preparation conditions. Silicate clay minerals consist of octahedral and tetrahedral layers. The most commonly used fillers in the synthesis of organoclays have a silicate layer structure. The cation exchange capacity (CEC) of montmorillonite clay is usually dependent on the Si/Al ratio. The structures of TBA-Br/Mt organoclays synthesized at different cation exchange capacities were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier-transform infrared spectroscopy (FT-IR), N2 adsorption/desorption (BET), Scanning electron microscope (SEM), and Transmission electron microscope (TEM). It was observed that the BET surface area decreased as the CEC ratio increased from 0.5 to 2.0 due to the increase in the amount of tetrabutyl ammonium bromide (TBA-Br) in the synthesized TBA-Br/Mt organoclay. As can be understood from the TEM images, it was observed that the Mt layers partially expanded as the CEC ratio increased from 0.5 to 2.0.

Anahtar Kelimeler

Cation exchange capacity (CEC), hydrophilic and hydrophobic group, montmorillonite (Mt), tetrabutyl ammonium bromide (TBA-Br), surfactant

Destekleyen Kurum

Gümüşhane University

Etik Beyan

The authors report no conflict of interest relevant to this article.

Teşekkür

The authors sincerely thank Gümüşhane University for its institutional support.

Farklı Katyon Değişim Oranlarında TBA-Br/Mt Organokillerinin Sentezi, Yapısal Karakterizasyonu ve Yüzey Modifikasyonu

Öz

Bu çalışmada, montmorillonit (Mt) kiline tetrabütil amonyum bromür (TBA-Br) yüzey aktif maddesi kullanılarak farklı katyon değişim oranlarında TBA-Br/Mt organokil sentezi gerçekleştirilmiştir. Mt katmanlarının su ile şişme özelliği sayesinde, uygun hazırlama koşullarında kil agregaları tek katmana kadar dağılabilir veya ayrıştırılabilir. Silikat kil mineralleri, oktahedral ve tetrahedral katmanlardan oluşur. Tetrahedral ve oktahedral katmanların temel yapı birimleri sırasıyla silisyum tetrahedral ve alüminyum oktahedral yapılardır. Organokil sentezinde en yaygın kullanılan dolgu maddeleri, silikat katman yapısına sahip olanlardır. Mt kilinin katyon değişim kapasitesi (CEC), genellikle Si/Al oranına bağlıdır. Si/Al oranı, değiştirilebilecek katyon miktarını etkiler. Bu nedenle, katyon miktarı anyonik yapının yoğunluğunun bir fonksiyonudur. Farklı katyon değişim kapasitelerinde sentezlenen TBA-Br/Mt organokillerinin yapıları; X-ışını kırınımı (XRD), X-ışını floresansı (XRF), Fourier dönüşümlü kızılötesi spektroskopisi (FT-IR), N2 adsorpsiyon/desorpsiyon izotermleri (BET), Taramalı elektron mikroskobu (SEM) ve Geçirimli elektron mikroskobu (TEM) ile karakterize edilmiştir. Sentezlenen TBA-Br/Mt organokillerinde CEC oranı 0.5’ten 2.0’a arttıkça kullanılan tetrabütil amonyum bromür (TBA-Br) miktarının artmasına bağlı olarak BET yüzey alanının azaldığı gözlemlenmiştir. TEM görüntülerinden anlaşıldığı üzere, CEC oranı 0.5’ten 2.0’a arttıkça Mt katmanlarının kısmen genişlediği görülmüştür. Anahtar Kelimeler: Hidrofilik ve hidrofobik grup, katyon değişim kapasitesi (CEC), montmorillonit (Mt), tetrabütil amonyum bromür (TBA-Br), yüzey aktif madde.

Anahtar Kelimeler

Hidrofilik ve hidrofobik grup, katyon değişim kapasitesi (CEC), montmorillonit (Mt), tetrabütil amonyum bromür (TBA-Br), yüzey aktif madde

Destekleyen Kurum

Gümüşhane Üniversitesi

Etik Beyan

Yazarlar, bu çalışmanın araştırma ve yayın etiğine uygun olduğunu beyan ederler.

Teşekkür

Yazarlar, kurumsal desteği için Gümüşhane Üniversitesi'ne içtenlikle teşekkür ederler.

Kaynakça

Galvan, D., Carneiro, F., Mazzucco, M., Bartoli, J. R., D’Avila, M. A., Morales, A. R., & Fernandes, E. G. (2012). Effect of Organoclay Mixture on the Rheological Properties of ABS‐Clay Nanocomposites. In Macromolecular Symposia, 319(1), 167-172). Weinheim: WILEY‐VCH Verlag.
Acik, E., Orbey, N., & Yilmazer, U. (2016). Rheological properties of poly (lactic acid) based nanocomposites: Effects of different organoclay modifiers and compatibilizers. Journal of Applied Polymer Science, 133(4), 42915.
Alves, J. L., Zanini, A. E., Souza, M. D., & Nascimento, M. L. F. (2016). Study of selection and purification of Brazilian bentonite clay by elutriation: a XRF, SEM and Rietveld analysis. Cerâmica, 62(361), 1-8.
Luo, W., Inoue, A., Hirajima, T., & Sasaki, K. (2016). Sequential modification of montmorillonite with dimethyl dioctadecyl ammonium chloride and benzyl octadecyl dimethyl ammonium chloride for removal of perchlorate. Microporous and Mesoporous Materials, 233, 117-124.
Zhou, D., Zhang, Z., Tang, J., Zhang, X., Wang, Q., and Liao, L. (2015). Influence of different exchangeable cations (Li+, Na+ and Ca2+) on the modification effects and properties of organomont-morillonites used in oil-based drilling fluids/muds. Rsc Advances, 5(110), 90281-90287.
Fan, J., Zhu, H., Li, R., & Chen, N. (2015). Montmorillonite modified by cationic and nonionic surfactants as high-performance fluid-loss-control additive in oil-based drilling fluids. Journal of Dispersion Science and Technology, 36(4), 569-576.
Gu, X. H., Li, S. W., Zheng, B., & Zhou, J. L. (2012). Preparation and research of anionic and cationic secondary modified organophilic montmorillonite. Advanced Materials Research, 396, 417-420.
Zhuang, G., Zhang, Z., Fu, M., Ye, X., & Liao, L. (2015). Comparative study on the use of cationic–nonionic-organo-montmorillonite in oil-based drilling fluids. Applied Clay Science, 116, 257-262.
Silva, I. A., Sousa, F. K. A., Menezes, R. R., Neves, G. A., Santana, L. N. L., & Ferreira, H. C. (2014). Modification of bentonites with nonionic surfactants for use in organic-based drilling fluids. Applied Clay Science, 95, 371-377.
Alves, J. L., e Rosa, P. D. T. V., & Morales, A. R. (2017). Evaluation of organic modification of montmorillonite with ionic and nonionic surfactants. Applied Clay Science, 150, 23-33.

He, H., Frost, R. L., Bostrom, T., Yuan, P., Duong, L., Yang, D., & Kloprogge, J. T. (2006). Changes in the morphology of organoclays with HDTMA+ surfactant loading. Applied Clay Science, 31(3-4), 262-271.
Chen, C., Liu, H.B., Chen, T.H., Chen, D., &Frost, R.L. (2015). An insight into the removal of Pb(II), Cu(II), Co(II), Cd(II), Zn(II), Ag(I), Hg(I), Cr(VI) by Na(I)-montmorillonite and Ca(II)-montmorillonite. Applied Clay Science, 118, 239–247.
Lu, L.F., Gao, M.L., Gu, Z., Yang, S.F., & Liu, Y.N. (2014). A comparative study and evaluation of sulfamethoxazole adsorption onto organo-montmorillonites. J. Environ. Sci., 26, 2535–2545.
Hassani, A., Kıranşan, M., Soltani, R. D. C., Khataee, A., & Karaca, S. (2015). Optimization of the adsorption of a textile dye onto nanoclay using a central composite design. Turkish Journal of Chemistry, 39(4), 734-749.
Yang, W. & Zaoui, A. (2013). Behind adhesion of uranyl onto montmorillonite surface: a molecular dynamics study. J. Hazard. Mater. 261, 224–234.
Yang, W., Xia, X.H., Liu, X.Y., & Zhang, S.Q. (2023). Interlayer structure and dynamic properties of CTMAB-montmorillonite: experiment and molecular dynamics. RSC Adv. 13(19), 13324–13336.
Araujo, E., Barbosa, R., Morais, C., Soledade, L., Souza, A., & Vieira, M. (2007). Effects of organoclays on the thermal processing of pe/clay nanocomposites. Journal of thermal analysis and calorimetry, 90(3), 841–848.
Luo, W., Inoue, A., Hirajima, T., and Sasaki, K. (2016). Sequential modification of montmorillonite with dimethyl dioctadecyl ammonium chloride and benzyl octadecyl dimethyl ammonium chloride for removal of perchlorate. Microporous and Mesoporous Materials, 233, 117–124.
Liao, L., Lv, G., Cai, D., & Wu, L. (2016). The sequential intercalation of three types of surfactants into sodium montmorillonite. Applied Clay Science, 119, 82–86.
Fu, M., Zhang, Z., Wu, L., Zhuang, G., Zhang, S., Yuan, J., & Liao, L. (2016). Investigation on the co-modification process of montmorillonite by anionic and cationic surfactants. Applied Clay Science, 132, 694-701.
Gherdaoui, C.E., Aldoori, H., Alaoui, C., Oumeddour, H., Taibi, Z., Zeggai, N., Lerari, D., et al. (2023). Exploring organo-bentonite adsorption properties for biphenyl removed from organic-aqueous media: kinetic study and industrial perspective. Brazi. J. Develop. 9, 29886–29910.
Chu, Y., Khan, M. A., Zhu, S., Xia, M., Lei, W., Wang, F., & Xu, Y. (2019). Microstructural modification of organo‐montmorillonite with Gemini surfactant containing four ammonium cations: molecular dynamics (MD) simulations and adsorption capacity for copper ions. Journal of Chemical Technology & Biotechnology, 94(11), 3585–3594.
Thapa, K.B., Katti, K.S., & Katti, D. R. (2020). Compression of Na–montmorillonite swelling clay interlayer is influenced by fluid polarity: a steered molecular dynamics study. Langmuir, 36(40), 11742–11753.
Liu, S., Chen, M., Cao, X., Li, G., Zhang, D., Li, M., ... and Yan, B. (2020). Chromium (VI) removal from water using cetylpyridinium chloride (CPC)-modified montmorillonite. Separation and Purification Technology, 241, 116732.
Chu, Y., Khan, M.A., Xia, M., Lei, W., Wang, F., Zhu, S., & Yan, X. (2020). Synthesis and micro-mechanistic studies of histidine modified montmorillonite for lead (II) and copper (II) adsorption from wastewater. Chemical Engineering Research and Design, 157, 142–152.
Chu, Y., Khan, M.A., Wang, F., Xia, M., Lei, W., & Zhu, S. (2019). Kinetics and equilibrium isotherms of adsorption of Pb (II) and Cu (II) onto raw and arginine-modified montmorillonite. Advanced Powder Technology, 30(5), 1067–1078.
Abou-El-Sherbini, K.S. & Hassanien, M.M. (2010). Study of organically-modified montmorillonite clay for the removal of copper (II). Journal of hazardous materials, 184(1-3), 654–661.
Fan, H., Zhou, L., Jiang, X., Huang, Q., & Lang, W. (2014). Adsorption of Cu2+ and methylene blue on dodecyl sulfobetaine surfactant-modified montmorillonite. Applied Clay Science, 95, 150–158.
Wei, J., Aly Aboud, M.F., Shakir, I., Tong, Z., & Xu, Y. (2019). Graphene oxide-supported organo-montmorillonite composites for the removal of Pb (II), Cd (II), and As (V) contaminants from water. ACS Applied Nano Materials, 3(1), 806–813.
Carvalho, M.N., da Motta, M., Benachour, M., Sales, D.C.S., & Abreu, C.A.M. (2012). Evaluation of BTEX and phenol removal from aqueous solution by multi-solute adsorption onto smectite organoclay. J. Hazard. Mater. 239–240, 95–101.
Hackbarth, F.V., Vilar, V.J.P., De Souza, G.B., de Souza, S.M.A.G.U., & de Souza, A.A.U. (2014). Benzene, toluene and o-xylene (BTX) removal from aqueous solutions through adsorptive processes. Adsorption, 20, 577–590.
Luo, W., Sasaki, K., & Hirajima, T. (2015). Effect of surfactant molecular structure on perchlorate removal by various organo-montmorillonites. Appl. Clay Sci. 114, 212–220.
Zhang, L.L., Zaoui, A., Sekkal, W., & Zheng, Y.Y. (2023). Interlayer adsorption of cationic dye on cationic surfactant-modified and unmodified montmorillonite. J. Hazard. Mater. 442, 130107.
Xu, L. & Zhu, L. (2009). Structures of OTMA- and DODMA-bentonite and their sorption characteristics towards organic compounds. J. Colloid Interface Sci. 331, 8–14.
Wu, W., Lan, Y., Zeng, Y., Lin, D., & Yang, K. (2020). Nonlinear sorption of phenols and anilines by organo-bentonites: nonlinear partition and space limitation for partitioning. Sci. Total Environ. 736, 139609
Zhu, R., Chen, W., Shapley, T.V., Molinari, M., Ge, F., & Parker, S.C. (2011). Sorptive characteristics of organomontmorillonite toward organic compounds: a combined LFERs and molecular dynamics simulation study. Environ. Sci. Technol. 45, 6504–6510.
Zhang, S.Q., Yang, W., Chen, R.P., Kang, X., and Ren, M.J. (2022). Modified geosynthetic clay liners bentonite for barriers of Cr (VI) in contaminated soil. Environmental Technology, 1-13.
Zhou, Q., Shen, W., Zhu, J.X., Zhu, R.L., He, H.P., Zhou, J.H., & Yuan, P. (2014). Structure and dynamic properties of water saturated CTMA-montmorillonite: molecular dynamics simulations. Applied Clay Science, 97-98, 62–71.
Machida, S., Guegan, R., & Sugahara, Y. (2019). Preparation and comparative stability of a kaolinite-tetrabutylphosphonium bromide intercalation compound for heat and solvent treatments. Langmuir, 35(42), 13553-13561.
Yang, J., Yu, K., & Liu, C. (2017). Chromium immobilization in soil using quaternary ammonium cations modified montmorillonite: Characterization and mechanism. J. Hazard. Mater. 321, 73–80.
Bhatt, J., Somani, R. S., Mody, H. M., & Bajaj, H. C. (2013). Rheological study of organoclays prepared from Indian bentonite: effect of dispersing methods. Applied Clay Science, 83, 106-114.
Dlamini, D. S., Li, J., & Mamba, B. B. (2019). Critical review of montmorillonite/polymer mixed-matrix filtration membranes: Possibilities and challenges. Applied Clay Science, 168, 21-30.
Nivedita, S. & Joseph, S. (2018). Effect of unmodified and modified montmorillonite on the properties of PCL based ultrafiltration membrane for water treatment applications. Journal of Water Process Engineering, 21, 61-68.
Jamil, A., Oh, P. C., & Shariff, A. M. (2018). Polyetherimide-montmorillonite mixed matrix hollow fibre membranes: Effect of inorganic/organic montmorillonite on CO2/CH4 separation. Separation and Purification Technology, 206, 256-267.
Gürses, A., Hassani, A., Kıranşan, M., Açışlı, Ö., & Karaca, S. (2014). Removal of methylene blue from aqueous solution using by untreated lignite as potential low-cost adsorbent: kinetic, thermodynamic and equilibrium approach. Journal of Water Process Engineering, 2, 10-21.
Sun, H., Zhang, J., Li, L., Xu, J., &Sun, D. (2013). Surface modification of natural Na-montmorillonite in alkane solvents using a quaternary ammonium surfactant. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 426, 26-32.
Xiao, F., Yan, B. Q., Zou, X. Y., Cao, X. Q., Dong, L., Lyu, X. J., & Zhang, Q. J. (2020). Study on ionic liquid modified montmorillonite and molecular dynamics simulation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 587, 124311.
Bala, P., Samantaraya, B. K., &Srivastava, S. K. (2000). Synthesis and characterization of Na-montmorillonite-alkylammonium intercalation compounds. Materials Research Bulletin, 35(10), 1717-1724.
Huskic, M., Brnardic, I., Zigon, M., & Ivankovic, M. (2008). Modification of montmorillonite by quaternary polyesters. Journal of non-crystalline solids, 354(28), 3326-3331.
Song, K. & Sandi, G. (2001). Characterization of montmorillonite surfaces after modification by organosilane. Clays and clay minerals, 49(2), 119-125.
Zhu, R.L., Chen, W.X., Shapley, T.V., Molinari, M., Ge, F., & Parker, S.C. (2011). Sorptive characteristics of organo-montmorillonite toward organic compounds: a combined LFERs and molecular dynamics simulation study. Environ. Sci. Technol. 45, 6504–6510.
Shen, T., Gao, M., Ding, F., Zeng, H., & Yu, M. (2018). Organo-vermiculites with biphenyl and dipyridyl gemini surfactants for adsorption of bisphenol A: Structure, mechanism and regeneration. Chemosphere, 207, 489–496.
Xiang, Y., Gao, M., Ding, F., & Shen, T. (2019). The efficient removal of dimethyl phthalate by three organo-vermiculites with imidazolium-based gemini surfactants in aqueous media. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 580, 123726.
Bergaya, F. & Lagaly, G. (2006). Chapter 1 General Introduction: Clays, Clay Minerals, and Clay Science. Developments in Clay Science, 1, 1–18.
Zhao, Q. & Burns, S.E. (2012). Molecular dynamics simulation of secondary sorption behavior of montmorillonite modified by single chain quaternary ammonium cations. Environ. Sci. Technol. 46, 3999–4007.
Zheng, Y., Lu, X., Lai, L., Yu, L., Zheng, H., & Dai, C. (2020). The micelle thermodynamics and mixed properties of sulfobetaine-type zwitterionic Gemini surfactant with nonionic and anionic surfactants. Journal of Molecular Liquids, 299, 112108.
Cheng, Y., Yang, Y., Niu, C., Feng, Z., Zhao, W., & Lu, S. (2019). Progress in synthesis and application of zwitterionic Gemini surfactants. Frontiers of Materials Science, 13(3), 242-257.
Yoshimura, T., Ichinokawa, T., Kaji, M., & Esumi, K. (2006). Synthesis and surface-active properties of sulfobetaine-type zwitterionic gemini surfactants. Colloids and Surfaces A: Physico-chemical and Engineering Aspects, 273(1-3), 208-212.
Zang, W., Gao, M., Shen, T., Ding, F., & Wang, J. (2017). Facile modification of homoionic -vermiculites by a gemini surfactant: Comparative adsorption exemplified by methyl orange. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 533, 99-108.
Ma, L., Chen, Q., Zhu, J., Xi, Y., He, H., Zhu, R., & Ayoko, G. A. (2016). Adsorption of phenol and Cu (II) onto cationic and zwitterionic surfactant modified montmorillonite in single and binary systems. Chemical Engineering Journal, 283, 880-888.
Luo, Z., Gao, M., Ye, Y., & Yang, S. (2015). Modification of reduced-charge montmorillonites by a series of Gemini surfactants: characterization and application in methyl orange removal. Applied Surface Science, 324, 807-816.
Gu, Z., Gao, M., Luo, Z., Xue, G., Lu, L., & Liu, Y. (2014). Gemini surfactant modified montmorillonite as highly efficient adsorbent for anionic dyes. Separation Science and Technology, 49(18), 2878-2889.
Bhatt, J., Somani, R. S., Mody, H. M., & Bajaj, H. C. (2013). Rheological study of organoclays prepared from Indian bentonite: effect of dispersing methods. Applied Clay Science, 83, 106–114.
Raghavendra, N., Murthy, N. H., Mahesh, V. K., Sridhar, R., & Krishna, M. (2015). Organo-modification of Indian bentonite clay and its influence on fire behavior of nanoclay/vinylester composites. Proceedings of The Institution of Mechanical Engineers Part N-Journal of Nanomaterials Nanoengineering and Nanosystems, 229(2), 55–65.
Akçay, M. (2006). Characterization and adsorption properties of tetrabutylammonium montmorillonite (TBAM) clay: thermodynamic and kinetic calculations. Journal of Colloid and Interface Science, 296(1), 16–21.
Abbas, A., Sallam, A. S., Usman, A. R., & Al-Wabel, M. I. (2017). Organoclay-based nano-particles from montmorillonite and natural clay deposits: Synthesis, characteristics, and application for MTBE removal. Applied Clay Science, 142, 21–29.
Lazaratou, C.V., Vayenas, D.V., & Papoulis, D. (2020). The role of clays, clay minerals and clay-based materials for nitrate removal from water systems: A review. Appl. Clay Sci. 185, 105377.
Patel, H.A., Somani, R.S., Bajaj, H.C., & Jasra, R.V. (2007). Preparation and characterization of phosphonium montmorillonite with enhanced thermal stability. Appl. Clay Sci. 35, 194–200.
Seyidoglu, T. & Yilmazer, U. (2015). Modification and characterization of bentonite with qua-ternary ammonium and phosphonium salts and its use in polypropylene nanocomposites. J. Thermoplast. Compos. Mater. 28, 86–110.
Ma, Y.H., Zhu, J.X., He, H.P., Yuan, P., Shen, W., & Liu, D. (2010). Infrared investigation of organo-montmorillonites prepared from different surfactants. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 76, 122–129.
Machida, S., Guegan, R., & Sugahara, Y. (2019). Preparation and comparative stability of a kaolinite-tetrabutylphosphonium bromide intercalation compound for heat and solvent treatments. Langmuir 35 (42), 13553–13561.
Madejova, J., Jankovic, L., Slany, M., & Hronsky, V. (2020). Conformation heterogeneity of alkylammonium surfactants self-assembled on montmorillonite: Effect of head-group structure and temperature. Appl. Surf. Sci. 503, 144125.
Zhuang, G., Zhang, Z., Peng, S., Gao, J., Pereira, F.A., Jaber, M. (2019). The interaction between surfactants and montmorillonite and its influence on the properties of organo-montmorillonite in oil-based driffing fluids. Clay Clay Miner. 67, 190–208.
Duman, O., Tunç, S., & Çetinkaya, A. (2012). Electrokinetic and rheological properties of kaolinite in poly (diallyl dimethylammonium chloride), poly (sodium 4-styrene sulfonate) and poly (vinyl alcohol) solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 394, 23–32.
Wang, C., Jiang, X., Zhou, L., Xia, G., Chen, Z., Duan, M., & Jiang, X. (2013). The preparation of organo-bentonite by a new gemini and its monomer surfactants and the application in MO removal: A comparative study. Chemical engineering journal, 219, 469-477.
Yang, S., Gao, M., Luo, Z., & Yang, Q. (2015). The characterization of organo-montmorillonite modified with a novel aromatic-containing gemini surfactant and its comparative adsorption for 2-naphthol and phenol. Chemical Engineering Journal, 268, 125-134.
Zhang, Y., Zhao, Y., Zhu, Y., Wu, H., Wang, H., & Lu, W. (2012). Adsorption of mixed cat-ionic-nonionic surfactant and its effect on bentonite structure. Journal of Environmental Sciences, 24(8), 1525-1532.
Yoshimura, T., Ichinokawa, T., Kaji, M., & Esumi, K. (2006). Synthesis and surface-active properties of sulfobetaine-type zwitterionic gemini surfactants. Colloids and Surfaces A: Physico-chemical and Engineering Aspects, 273(1-3), 208-212.
Ouellet-Plamondon, C. M., Stasiak, J., & Al-Tabbaa, A. (2014). The effect of cationic, non-ionic and amphiphilic surfactants on the intercalation of bentonite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 444, 330-337.
Yang, S., Huang, Z., Li, C., Li, W., Yang, L., & Wu, P. (2020). Individual and simultaneous adsorption of tetracycline and cadmium by dodecyl dimethyl betaine modified vermiculite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 602, 125171.
Zhou, Y., Fusheng, L. & Shitao, Y. (2015). Preparation and photo-catalytic activities of FeOOH/ZnO/MMT composite. Applied Surface Science, 355, 861–867.
Wang, X., Du, Y., Yang, J., Tang, Y., & Luo, J. (2008). Preparation, characterization, and antimicrobial activity of quaternized chitosan/organic montmorillonite nanocomposites. Journal of biomedical materials research part A, 84(2), 384-390.
Liu, Y., Luan, J., Zhang, C., Ke, X., & Zhang, H. (2019). The adsorption behavior of multiple contaminants like heavy metal ions and p-nitrophenol on organic-modified montmorillonite. Environmental Science and Pollution Research, 26, 10387-10397.
Ma, L., Chen, Q., Zhu, J., Xi, Y., He, H., Zhu, R., & Ayoko, G. A. (2016). Adsorption of phenol and Cu (II) onto cationic and zwitterionic surfactant modified montmorillonite in single and binary systems. Chemical Engineering Journal, 283, 880-888.
Zhang, L., Zhang, B., Wu, T., Sun, D., & Li, Y. (2015). Adsorption behavior and mechanism of chlorophenols onto organoclays in aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 484, 118-129.
Bergaya, F., Jaber, M., & Lambert, J. F. (2011). Organophilic clay minerals. Rubber‐Clay Nanocomposites: Science, Technology, and Applications, 45-86.
Karaca, C., Karaca, M., Kıranşan, M., Karaca, S., Açışlı, O. & Gürses, A. (2023). Comparison of the removal efficiencies of Basic Red 46 from aqueous solutions using Aşkale lignite with and without ultrasound-assisted processes. Desalination and Water Treatment, 315, 111-121.
Zhuang, G., Zhang, Z., Sun, J., & Liao, L. (2016). The structure and rheology of organo-montmorillonite in oil-based system aged under different temperatures. Applied Clay Science, 124, 21-30.
Zhuang, G., Zhang, Z., Fu, M., Ye, X., & Liao, L. (2015). Comparative study on the use of cationic–nonionic-organo-montmorillonite in oil-based drilling fluids. Applied Clay Science, 116, 257-262.
Yang, J., Yu, K., & Liu, C. (2017). Chromium immobilization in soil using quaternary ammonium cations modified montmorillonite: characterization and mechanism. J. Hazard. Mater. 321, 73–80. https://doi.org/10.1016/j.jhazmat.2016.09.003.
Calderon, J. U., Lennox, B., & Kamal, M. R. (2008). Thermally stable phosphonium montmorillonite organoclays. Applied Clay Science, 40(1-4), 90-98.
Chen, D., Zhu, J., Yuan, P., Yang, S., Chen, T., & He, H. (2008). Preparation and characterization of anion-cation surfactants modified montmorillonite. Journal of Thermal Analysis and Calorimetry, 94(3), 841-848.
Zhang, Z., Zhang, J., Liao, L., & Xia, Z. (2013). Synergistic effect of cationic and anionic surfactants for the modification of Ca-montmorillonite. Materials Research Bulletin, 48(5), 1811-1816.
Zhang, Z., Liao, L., & Xia, Z. (2010). Ultrasound-assisted preparation and characterization of anionic surfactant modified montmorillonites. Applied Clay Science, 50(4), 576-581.
Sun, Z., Park, Y., Zheng, S., Ayoko, G. A., & Frost, R. L. (2013). XRD, TEM, and thermal analysis of Arizona Ca-montmorillonites modified with didodecyldimethylammonium bromide. Journal of Colloid and Interface Science, 408, 75-81.
Lee, Y. C., Kuo, C. L., Wen, S. B., & Lin, C. P. (2007). Changes of organo-montmorillonite by ball-milling in water and kerosene. Applied Clay Science, 36(4), 265-270.
Vazquez, A., Lopez, M., Kortaberria, G., Martín, L., & Mondragon, I. (2008). Modification of montmorillonite with cationic surfactants. Thermal and chemical analysis including CEC determination. Applied Clay Science, 41(1-2), 24-36.
Mittal, V. (2012). Modification of montmorillonites with thermally stable phosphonium cations and comparison with alkylammonium montmorillonites. Applied Clay Science, 56, 103-109.
Dultz, S., An, J. H., & Riebe, B. (2012). Organic cation exchanged montmorillonite and vermiculite as adsorbents for Cr (VI): Effect of layer charge on adsorption properties. Applied Clay Science, 67, 125-133.
Silva, M. M., Oliveira, M. M., Avelino, M. C., Fonseca, M. G., Almeida, R. K., & Silva Filho, E. C. (2012). Adsorption of an industrial anionic dye by modified-KSF-montmorillonite: Evaluation of the kinetic, thermodynamic and equilibrium data. Chemical Engineering Journal, 203, 259-268.
Cottet, L., Almeida, C. A. P., Naidek, N., Viante, M. F., Lopes, M. C., & Debacher, N. A. (2014). Adsorption characteristics of montmorillonite clay modified with iron oxide with respect to methylene blue in aqueous media. Applied Clay Science, 95, 25-31.

Ayrıntılar

Birincil Dil

İngilizce

Konular

Kimya Mühendisliği (Diğer), Malzeme Mühendisliği (Diğer)

Bölüm

Araştırma Makalesi

Yazarlar

Murat Kıranşan ^*
0000-0002-8520-6563
Türkiye

Yayımlanma Tarihi

30 Haziran 2026

Gönderilme Tarihi

11 Aralık 2025

Kabul Tarihi

4 Haziran 2026

Yayımlandığı Sayı

Yıl 2026 Cilt: 10 Sayı: 1

DOI

https://doi.org/10.46460/ijiea.1840634

IZ

https://izlik.org/JA37PF84ZC

APA

Kıranşan, M. (2026). Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio. International Journal of Innovative Engineering Applications, 10(1), 39-54. https://doi.org/10.46460/ijiea.1840634

AMA

1.Kıranşan M. Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio. ijiea, IJIEA. 2026;10(1):39-54. doi:10.46460/ijiea.1840634

Chicago

Kıranşan, Murat. 2026. “Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio”. International Journal of Innovative Engineering Applications 10 (1): 39-54. https://doi.org/10.46460/ijiea.1840634.

EndNote

Kıranşan M (01 Haziran 2026) Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio. International Journal of Innovative Engineering Applications 10 1 39–54.

IEEE

[1]M. Kıranşan, “Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio”, ijiea, IJIEA, c. 10, sy 1, ss. 39–54, Haz. 2026, doi: 10.46460/ijiea.1840634.

ISNAD

Kıranşan, Murat. “Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio”. International Journal of Innovative Engineering Applications 10/1 (01 Haziran 2026): 39-54. https://doi.org/10.46460/ijiea.1840634.

JAMA

1.Kıranşan M. Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio. ijiea, IJIEA. 2026;10:39–54.

MLA

Kıranşan, Murat. “Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio”. International Journal of Innovative Engineering Applications, c. 10, sy 1, Haziran 2026, ss. 39-54, doi:10.46460/ijiea.1840634.

Vancouver

1.Murat Kıranşan. Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio. ijiea, IJIEA. 01 Haziran 2026;10(1):39-54. doi:10.46460/ijiea.1840634

Synthesis, Structural Characterization and Surface Modification of TBA-Br/Mt Organoclays at Different Cation Exchange Ratio

Öz

Anahtar Kelimeler

Destekleyen Kurum

Etik Beyan

Teşekkür

Farklı Katyon Değişim Oranlarında TBA-Br/Mt Organokillerinin Sentezi, Yapısal Karakterizasyonu ve Yüzey Modifikasyonu

Öz

Anahtar Kelimeler

Destekleyen Kurum

Etik Beyan

Teşekkür

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster