Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi

Betul Çiçek Ozkan; Melek Güner

doi:10.46460/ijiea.946875

EN TR

Production of Nanocrystalline Cellulose by Ultrasonically Assisted Acid Hydrolysis

Öz

Cellulose nanocrystals (SN) were isolated from the shell of horse chestnut seed using sulfuric acid hydrolysis. The raw shells were broken into small pieces, treated alkali, bleached, and subjected to the sulphuric acid process. The effect of hydrolysis time on the structure, crystallinity, thermal properties, morphology, and topology of cellulose and SNs were investigated. The lignin and hemicellulose contents were almost entirely removed from the produced cellulose through the alkali and bleaching treatments demonstrated to Fourier transform infrared spectroscopy. The crystallinity of SNs was increased firstly with increasing reaction time and then along with the reaction times longer than 20 minutes decreases. The optimal isolation time for SN production was found to be 20 min at 45 °C in a 50 % sulfuric acid solution. The morphology of the cellulose and SN were investigated by Field Emission Scanning Electron Microscopy and revealed a changed needle-like surface structure of SN relative to cellulose. The surface roughness of cellulose with a Ra value of 585 nm is higher than the cellulose nanocrystalline with a Ra value of 111 nm, which were characterized using Atomic Force Microscopy. The thermal stability of SNs was decreased during increased extraction times compared with cellulose.

Anahtar Kelimeler

horse chestnut, cellulose nanocrystals, acid hydrolysis, crystallinity

Proje Numarası

TEKF.21.06

Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi

Öz

Selüloz nanokristalin (SN) atkestanesi tohumu kabuğundan asit hidrolizi ile ekstrakte edilmiştir. Ham kabuklar küçük parçalara bölünmüş, alkali işleme tabi tutulmuş, ağartılmış ve sülfirik asit ile muamele edilmiştir. Hidroliz reaksisyonunun süresinin elde edilen SN’lerin yapısına, kristalinitesine, termal, morfolojik ve topolojik özelliklerine etkisi araştırılmıştır. Fouriere kızıl ötesi spektrumları incelendiğinde ligninin ve hemiselülozun alkali ve ağartma işlemleri sırasında üretilen ürünlerin yapısından tamamen uzaklaştırıldığı görülmüştür. Üretilen SN’lerin kristalinite dereceleri artan reaksiyon sürei ile birlikte önce artmış ve 20 dakikadan sonra azalmaya başlamıştır. Atkestanesi kabuğundan SN üretiminde optimal isolasyon süresi 20 dakika (45 °C’de ve % 50’lik sülfirik asit çözeltisi içerisinde) olarak belirlenmiştir. Selüloz ve SN’nin morfolojik özellikler Taramalı Elektron Mikroskobu ilen incelenmiş ve selüloza göre SN’nin iğne benzeri değişmiş bir yapıya sahip olduğu gözlenmiştir. 585 nm’lik Ra değeri ile selülozun yüzey pürüzlülüğünün SN’ye göre (111 nm) dah yüzek olduğu Atomik Kuvvet mikrokobu ile karakterize edilmiştir. SN’lerin termal stabilitesi artan isolasyon süresi ile selüloza göre azalmıştır.

Anahtar Kelimeler

atkestanesi, selüloz nanokristal, asit hidrolizi, kristalinite

Destekleyen Kurum

FIRAT ÜNİVERSİTESİ

Proje Numarası

TEKF.21.06

Teşekkür

Bu çalışma Fırat Üniversitesi Bilimsel Araştırma Projeleri birimi (FÜBAP) tarafından Proje No: TEKF. 21.06 ile desteklenmiştir.

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Betul Çiçek Ozkan ^*
0000-0002-8852-6650
Türkiye

Melek Güner
0000-0001-9990-9051
Türkiye

Yayımlanma Tarihi

31 Aralık 2021

Gönderilme Tarihi

2 Haziran 2021

Kabul Tarihi

26 Temmuz 2021

Yayımlandığı Sayı

Yıl 2021 Cilt: 5 Sayı: 2

DOI

https://doi.org/10.46460/ijiea.946875

IZ

https://izlik.org/JA55TJ99PW

APA

Çiçek Ozkan, B., & Güner, M. (2021). Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi. International Journal of Innovative Engineering Applications, 5(2), 101-106. https://doi.org/10.46460/ijiea.946875

AMA

1.Çiçek Ozkan B, Güner M. Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi. ijiea, IJIEA. 2021;5(2):101-106. doi:10.46460/ijiea.946875

Chicago

Çiçek Ozkan, Betul, ve Melek Güner. 2021. “Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi”. International Journal of Innovative Engineering Applications 5 (2): 101-6. https://doi.org/10.46460/ijiea.946875.

EndNote

Çiçek Ozkan B, Güner M (01 Aralık 2021) Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi. International Journal of Innovative Engineering Applications 5 2 101–106.

IEEE

[1]B. Çiçek Ozkan ve M. Güner, “Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi”, ijiea, IJIEA, c. 5, sy 2, ss. 101–106, Ara. 2021, doi: 10.46460/ijiea.946875.

ISNAD

Çiçek Ozkan, Betul - Güner, Melek. “Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi”. International Journal of Innovative Engineering Applications 5/2 (01 Aralık 2021): 101-106. https://doi.org/10.46460/ijiea.946875.

JAMA

1.Çiçek Ozkan B, Güner M. Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi. ijiea, IJIEA. 2021;5:101–106.

MLA

Çiçek Ozkan, Betul, ve Melek Güner. “Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi”. International Journal of Innovative Engineering Applications, c. 5, sy 2, Aralık 2021, ss. 101-6, doi:10.46460/ijiea.946875.

Vancouver

1.Betul Çiçek Ozkan, Melek Güner. Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi. ijiea, IJIEA. 01 Aralık 2021;5(2):101-6. doi:10.46460/ijiea.946875

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Cellulose and chitosan biopolymer composites reinforced with graphene and their adsorption properties for basic blue 41

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Bartın Orman Fakültesi Dergisi

https://doi.org/10.24011/barofd.1358005

Production of Nanocrystalline Cellulose by Ultrasonically Assisted Acid Hydrolysis

Öz

Anahtar Kelimeler

Proje Numarası

Ultrasonik Destekli Asit Hidrolizi ile Nanokristalin Selüloz Üretimi

Öz

Anahtar Kelimeler

Destekleyen Kurum

Proje Numarası

Teşekkür

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster

Cited By

Cellulose and chitosan biopolymer composites reinforced with graphene and their adsorption properties for basic blue 41

Nanoselüloz: yapısı, çeşitleri ve kullanım alanları