A Novel and Highly Sensitive Reduced Graphene Oxide Modified Electrochemical Sensor for the Determination of Chlorpyrifos in Real Sample
Yıl 2021,
Cilt: 7 Sayı: 1, 1 - 12, 30.06.2021
Berna Koçak
Hüseyin Çelikkan
Öz
Bu çalışmada, klorpirifosun (CPF) voltametrik davranışı, indirgenmiş grafen oksit modifiye camsı karbon elektrot (RGO / GCE) kullanılarak incelenmiştir. Hummers'ın yöntemiyle hazırlanan grafen oksit ve indirgenmiş grafen oksit ürünlerinin karakterizasyonunda FT-IR, XRD ve TEM yöntemleri kullanıldı. CPF'nin elektrokimyasal karakterizasyonu, döngüsel voltametri (CV) ve diferansiyel puls voltametri (DPV) ile belirlendi. CPF'nin belirlenmesi için RGO / GCE üzerinde diferansiyel darbeli adsorptif sıyırma voltametrisi (DPAdSV) yapıldı. CPF'nin DPAdSV yöntemi ile kalibrasyon grafiği 5.19x10-7-8.12x10-6 M ve 8.12x10-6-2.18x10-3 M ile 1.56x10-7 M LOD olmak üzere iki çalışma aralığı vermiştir. RGO / GCE'de musluk suyu eklenmiş klorpirifos geri kazanımı% 101.0 olmuştur. Sonuç olarak, gerçek numunelerde kullanılabilen CPF tayini için seçici ve duyarlı bir ürün geliştirilmiştir
Destekleyen Kurum
Gazi University Scientific Research Fund/Munzur University Scientific Research Fund
Proje Numarası
(05/2017-15)/(MFTUB013 02)
Teşekkür
The authors gratefully acknowledge the supports of Gazi University under Scientific Research Fund (05/2017-15) and Munzur University under Scientific Research Fund (MFTUB013 02). In addition, we would like to thank Assoc. Prof. Dr. Vahap YÖNTEN for his help with chemical materials.
Kaynakça
- Al‐Meqbali, A. S. R., El‐Shahawi, M. S.and Kamal, M. M.,1998. Differential pulse polarographic analysis of chlorpyrifos insecticide. Electroanalysis: An International Journal Devoted to Fundamental and Practical Aspects of Electroanalysis, 10(11), 784-786.
- Çiplak, Z., Yildiz, N. And Çalimli, A., 2015. Investigation of graphene/Ag nanocomposites synthesis parameters for two different synthesis methods. Fullerenes, Nanotubes and Carbon Nanostructures, 23(4), 361-370.
- Emiru, T. F.,and Ayele, D. W., 2017. Controlled synthesis, characterization and reduction of graphene oxide: A convenient method for large scale production. Egyptian Journal of Basic and Applied Sciences, 4(1), 74-79.
- Geim, A. K. And Novoselov, K. S., 2010. The rise of graphene. In Nanoscience and technology: A Collection Of Reviews From Nature Journals ,11-19.
- Handajani, U. S., Raharjo, Y., And Wantoro, B., 2017. Determination of chlorpyrifos pesticide by effervescence liquid phase microextraction HPLC UV-VIS. Journal Of Chemical Technology And Metallurgy, 52(6), 1056-1061.
- Huan, Y., You Ning, M., Mei Ling, Q., Shuang Shuang, C., Qiao, H., Han Tong, Z., And Ren Xiang, M., 2019. Rapid analysis of chlorpyrifos, carbosulfan and their metabolites residues in rice by HPLC-MS/MS. Shipin Kexue/Food Science, 40(2), 304-309.
- Huang, W., Zhou, X., Luan, Y., Cao, Y., Wang, N., Lu, Y. And Xu, W., 2020 .A sensitive electrochemical sensor modified with multi‐walled carbon nanotubes doped molecularly imprinted silica nanospheres for detecting chlorpyrifos. Journal Of Separation Science, 43(5), 954-961.
- Johra, F. T., Lee, J. W.and Jung, W. G., 2014. Facile and safe graphene preparation on solution based platform. Journal Of Industrial And Engineering Chemistry, 20(5), 2883-2887.
- Koçak, B., Er, E. And Çelikkan, H. , 2015. Stripping voltammetric analysis of dicofol on graphene-modified glassy carbon electrode. Ionics, 21(8), 2337-2344.
- Konios, D., Stylianakis, M. M., Stratakis, E.and Kymakis, E., 2014. Dispersion behaviour of graphene oxide and reduced graphene oxide. Journal Of Colloid And İnterface Science, 430, 108-112.
- Kumaravel, A. And Chandrasekaran, M., 2015. Electrochemical determination of chlorpyrifos on a nano-TiO2/cellulose acetate composite modified glassy carbon electrode. Journal Of Agricultural And Food Chemistry, 63(27), 6150-6156.
- Mane, P. C., Shinde, M. D., Varma, S., Chaudhari, B. P., Fatehmulla, A., Shahabuddin, M. And Chaudhari, R., 2020. D.Highly sensitive label-free bio-interfacial colorimetric sensor based on silk fibroin-gold nanocomposite for facile detection of chlorpyrifos pesticide”. Scientific Reports, 10(1), 1-14.
- Manisankar, P., Viswanathan, S., Pusphalatha, A. M. And Rani, C., 2005. Electrochemical studies and square wave stripping voltammetry of five common pesticides on poly 3, 4-ethylenedioxythiophene modified wall-jet electrode. Analytica Chimica Acta, 528(2), 157-163.
- Manisankar, P.,Sundari, P. A., Sasikumar, R. And Palaniappan, S. P., 2008 Electroanalysis of some common pesticides using conducting polymer/multiwalled carbon nanotubes modified glassy carbon electrode, Talanta, 76(5), 1022-1028.
- Nallapaneni, A.,Pope, C. N., 2005. Chlorpyrifos. Encyclopedia of Toxicology (Second Edition). Elsevier, 583-586.
- Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., and Firsov, A. A., 2004. Electric field effect in atomically thin carbon films. Science, 306(5696), 666-669.
- Paredes, J. I.,Villar-Rodil, S., Martinez-Alonso, A. and Toscon, J. M. D.,2008.Graphene oxide dispersions in organic solvents, Langmuir, 24(19), 10560-10564.
- Pelit, F. O., Ertaş, H. And Ertaş, F. N., 2011. Development of an adsorptive catalytic stripping voltammetric method for the determination of an endocrine disruptor pesticide chlorpyrifos and its application to the wine samples. Journal of Applied Electrochemistry, 41(11), 1279.
- Pope, C.,Karanth, S. And Liu, J., 2005. Pharmacology and toxicology of cholin esterase inhibitors: uses and misuses of a common mechanism of action. Environmental toxicology and pharmacology, 19(3), 433–446.
- Sinha, S. N., Pal, R., Dewan, A., Mansuri, M. M. And Saiyed, H. N., 2006. Effect of dissociation energy on ion formation and sensitivity of an analytical method for determination of chlorpyrifos in human blood, using gas chromatography–mass spectrometer (GC–MS in MS/MS). International Journal of Mass Spectrometry, 253(1-2), 48-57.
- Sirisha, K., Mallipattu, S. And Jayarama Reddy, S. R., 2007. Differential pulse adsorptive stripping voltammetric determination of chlorpyrifos at a sepiolite modified carbon paste electrode .Analytical letters, 40(10):1939-1950.
- Sreedhar, N. Y., Kumar, M. S. And Krishnaveni, K., 2015. Sensitive determination of chlorpyrifos using Ag/Cu alloy nanoparticles and graphene composite paste electrode. Sensors and Actuators B: Chemical, 210, 475-482.
- Stobinski, L., Lesiak, B., Malolepszy, A., Mazurkiewicz, M., Mierzwa, B., Zemek, J.and Bieloshapka, I., 2014. Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. Journal of Electron Spectroscopy and Related Phenomena, 195, 145-154.
- Wallace, P. R., 1947. The band theory of graphite. Physical review, 71(9), 622.
- William, S., Hummers, J. R.and Offeman, R. E., 1958. Preparation of graphitic oxide. J. Am. Chem. Soc, 80(6), 1339-1339.
- Yang, W., Ratinac, K. R., Ringer, S. P., Thordarson, P., Gooding, J. J. And Braet, F., 2010. Carbon nanomaterials in biosensors: should you use nanotubes or graphene?. Angewandte Chemie International Edition, 49(12), 2114-2138.
Yıl 2021,
Cilt: 7 Sayı: 1, 1 - 12, 30.06.2021
Berna Koçak
Hüseyin Çelikkan
Proje Numarası
(05/2017-15)/(MFTUB013 02)
Kaynakça
- Al‐Meqbali, A. S. R., El‐Shahawi, M. S.and Kamal, M. M.,1998. Differential pulse polarographic analysis of chlorpyrifos insecticide. Electroanalysis: An International Journal Devoted to Fundamental and Practical Aspects of Electroanalysis, 10(11), 784-786.
- Çiplak, Z., Yildiz, N. And Çalimli, A., 2015. Investigation of graphene/Ag nanocomposites synthesis parameters for two different synthesis methods. Fullerenes, Nanotubes and Carbon Nanostructures, 23(4), 361-370.
- Emiru, T. F.,and Ayele, D. W., 2017. Controlled synthesis, characterization and reduction of graphene oxide: A convenient method for large scale production. Egyptian Journal of Basic and Applied Sciences, 4(1), 74-79.
- Geim, A. K. And Novoselov, K. S., 2010. The rise of graphene. In Nanoscience and technology: A Collection Of Reviews From Nature Journals ,11-19.
- Handajani, U. S., Raharjo, Y., And Wantoro, B., 2017. Determination of chlorpyrifos pesticide by effervescence liquid phase microextraction HPLC UV-VIS. Journal Of Chemical Technology And Metallurgy, 52(6), 1056-1061.
- Huan, Y., You Ning, M., Mei Ling, Q., Shuang Shuang, C., Qiao, H., Han Tong, Z., And Ren Xiang, M., 2019. Rapid analysis of chlorpyrifos, carbosulfan and their metabolites residues in rice by HPLC-MS/MS. Shipin Kexue/Food Science, 40(2), 304-309.
- Huang, W., Zhou, X., Luan, Y., Cao, Y., Wang, N., Lu, Y. And Xu, W., 2020 .A sensitive electrochemical sensor modified with multi‐walled carbon nanotubes doped molecularly imprinted silica nanospheres for detecting chlorpyrifos. Journal Of Separation Science, 43(5), 954-961.
- Johra, F. T., Lee, J. W.and Jung, W. G., 2014. Facile and safe graphene preparation on solution based platform. Journal Of Industrial And Engineering Chemistry, 20(5), 2883-2887.
- Koçak, B., Er, E. And Çelikkan, H. , 2015. Stripping voltammetric analysis of dicofol on graphene-modified glassy carbon electrode. Ionics, 21(8), 2337-2344.
- Konios, D., Stylianakis, M. M., Stratakis, E.and Kymakis, E., 2014. Dispersion behaviour of graphene oxide and reduced graphene oxide. Journal Of Colloid And İnterface Science, 430, 108-112.
- Kumaravel, A. And Chandrasekaran, M., 2015. Electrochemical determination of chlorpyrifos on a nano-TiO2/cellulose acetate composite modified glassy carbon electrode. Journal Of Agricultural And Food Chemistry, 63(27), 6150-6156.
- Mane, P. C., Shinde, M. D., Varma, S., Chaudhari, B. P., Fatehmulla, A., Shahabuddin, M. And Chaudhari, R., 2020. D.Highly sensitive label-free bio-interfacial colorimetric sensor based on silk fibroin-gold nanocomposite for facile detection of chlorpyrifos pesticide”. Scientific Reports, 10(1), 1-14.
- Manisankar, P., Viswanathan, S., Pusphalatha, A. M. And Rani, C., 2005. Electrochemical studies and square wave stripping voltammetry of five common pesticides on poly 3, 4-ethylenedioxythiophene modified wall-jet electrode. Analytica Chimica Acta, 528(2), 157-163.
- Manisankar, P.,Sundari, P. A., Sasikumar, R. And Palaniappan, S. P., 2008 Electroanalysis of some common pesticides using conducting polymer/multiwalled carbon nanotubes modified glassy carbon electrode, Talanta, 76(5), 1022-1028.
- Nallapaneni, A.,Pope, C. N., 2005. Chlorpyrifos. Encyclopedia of Toxicology (Second Edition). Elsevier, 583-586.
- Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., and Firsov, A. A., 2004. Electric field effect in atomically thin carbon films. Science, 306(5696), 666-669.
- Paredes, J. I.,Villar-Rodil, S., Martinez-Alonso, A. and Toscon, J. M. D.,2008.Graphene oxide dispersions in organic solvents, Langmuir, 24(19), 10560-10564.
- Pelit, F. O., Ertaş, H. And Ertaş, F. N., 2011. Development of an adsorptive catalytic stripping voltammetric method for the determination of an endocrine disruptor pesticide chlorpyrifos and its application to the wine samples. Journal of Applied Electrochemistry, 41(11), 1279.
- Pope, C.,Karanth, S. And Liu, J., 2005. Pharmacology and toxicology of cholin esterase inhibitors: uses and misuses of a common mechanism of action. Environmental toxicology and pharmacology, 19(3), 433–446.
- Sinha, S. N., Pal, R., Dewan, A., Mansuri, M. M. And Saiyed, H. N., 2006. Effect of dissociation energy on ion formation and sensitivity of an analytical method for determination of chlorpyrifos in human blood, using gas chromatography–mass spectrometer (GC–MS in MS/MS). International Journal of Mass Spectrometry, 253(1-2), 48-57.
- Sirisha, K., Mallipattu, S. And Jayarama Reddy, S. R., 2007. Differential pulse adsorptive stripping voltammetric determination of chlorpyrifos at a sepiolite modified carbon paste electrode .Analytical letters, 40(10):1939-1950.
- Sreedhar, N. Y., Kumar, M. S. And Krishnaveni, K., 2015. Sensitive determination of chlorpyrifos using Ag/Cu alloy nanoparticles and graphene composite paste electrode. Sensors and Actuators B: Chemical, 210, 475-482.
- Stobinski, L., Lesiak, B., Malolepszy, A., Mazurkiewicz, M., Mierzwa, B., Zemek, J.and Bieloshapka, I., 2014. Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. Journal of Electron Spectroscopy and Related Phenomena, 195, 145-154.
- Wallace, P. R., 1947. The band theory of graphite. Physical review, 71(9), 622.
- William, S., Hummers, J. R.and Offeman, R. E., 1958. Preparation of graphitic oxide. J. Am. Chem. Soc, 80(6), 1339-1339.
- Yang, W., Ratinac, K. R., Ringer, S. P., Thordarson, P., Gooding, J. J. And Braet, F., 2010. Carbon nanomaterials in biosensors: should you use nanotubes or graphene?. Angewandte Chemie International Edition, 49(12), 2114-2138.