Araştırma Makalesi
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THE EFFECT OF CORROSİON OF 5-(4-Dimethylaminobenzyliden)-rhodanin on MİLD STEEL

Yıl 2019, Cilt: 7 Sayı: 4, 803 - 810, 19.12.2019
https://doi.org/10.21923/jesd.455544

Öz

The inhibition effect
of 5-(4-Dimethylaminobenzyliden)-rhodanin (D-Rh) molecule on mild steel
corrosion has been investigated in 0.5 M H2SO4 solution
using help with electrochemical impedance spectroscopy, linear polarization
resistance, chronoamperometry and potentiodynamic polarization techniques. The
experimental result show that the inhibitor efficiency increases with
increasing inhibitor concentration. The adsorption isotherm is suitable with
Langmuir. The Ea are calculated. 

Kaynakça

  • Abbouda,, Y., Abourrichea, A., Berradaa, T. Saffaja, Charroufa, M., Bennamaraa, M., Hannacheb,A. H.,2009. A novel azo dye, 8-quinolinol-5-azoantipyrine as corrosion inhibitor for mild steel in acidic media, Desalination, 237, 175.
  • Aljourani, J., Raeissi, K., Golozar,M.A., 2009. Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution, Corrosion Science,51,1836.
  • Altunbaş, E., Solmaz,R., Kardaş G.,2010. Corrosion behaviour of polyrhodanine coated copper electrode in 0.1M H2SO4 solution. Material Chemist and Physic, 121,354..
  • Altunbaş,E. 2008. Polirodaninin Bakır Üzerine Elektrokimyasal Sentezi Ve Korozyon Davranışlarının Belirlenmesi, Yüksek Lisans Tezi. Çukurova Üniversitesi.Türkiye.
  • Döner, A., Kardas, G. 2011. N-Aminorhodanine as an effective corrosion inhibitor for mild steel in 0.5 M H2SO4,Corrosion. Science. 53, 4223.
  • Erbil, M., 1984. Korozyon İnhibitörleri, SEGEM, Ankara.
  • Erbil, M., 2012. Korozyon İlkeler Önlemler, Türkiye Korozyon Derneği, Ankara.
  • Foye W.O., Tovivich P.J.,2011. Pharm. Sci. 66,1607.
  • Quartarone, G., Bonaldo,L. Tortato,C.2006. Inhibitive action of indole-5-carboxylic acid towards corrosion of mild steel in deaerated 0.5 M sulfuric acid solutions, Applied Surf.ace Science 252,8251.
  • Kardaş G., 2005. The Inhibition Effect of 2-Thiobarbituric Acid on the Corrosion Performance of Mild Steel in HCl Solutions. Material Science, 41, 337.
  • Li, S.L., Wang,Y.G., Chen S.H., Yu, R., Lei, S.B., Ma, H.Y., Liu, X.De.1999, Some aspects of quantum chemical calculations for the study of Schiff base corrosion inhibitors on copper in NaCl solutions, Corrosion Science.41,1769.
  • Mishra, S., Srivastava, S.K. Indian 1997. J. Chem. Sected. B 36, 826.
  • Momose Y., Meguro K., Ikeda H., Hatanaka C., Oi, S. Sohda, T. 1991. Studies on Antidiabetic Agent Synthesis and Biogical Activities of Pioglitozone and Related Compounds Chem. Pharm. Bull.39,1440.
  • Musa, A. Y., Kadhum,A.A.H., Mohamad,A. B., Daud, A. R. M., Takriff, S., . Kamarudin, S. KA., 2009. comparative study of the corrosion inhibition of mild steel in sulphuric acid by 4,4-dimethyloxazolidine-2-thione, Corrosion Science. 51, 2393.
  • Öztürk S., Düşük karbon çeliğinin asidik ortamdaki korozyonuna karşı inhibitör özelliği gösteren 4-okso-kinazolin türevi katyonik yüzey aktif maddelerin sentezi 2018,Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22 (3), 986-1000
  • Solmaz, R., Kardaş, G., Yazıcı, B., Erbil, M., 2005. The Effect of Rhodanine on the Corrosion Performance of Mild Steel with Immersion Time. chemistry and material science, 41: 581-585.
  • Solmaz, R. 2010Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid, Corros.Sci. 52 3321-3330.
  • Solmaz,R.2014. Investigation of adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by 5-(4-Dimethylaminobenzylidene)rhodanine. Corros.Sci. 79,169.
  • Solmaz, R. Şahin, A. E., Kardas¸ G.2011. Adsorption and corrosion inhibition effect of 2((5mercapto1,3,4thiadiazolylimino)methyl)phenol Schiff base on mild steel, Mater.Chem. Phys.125 ,796.
  • Solmaz,R.,Döner A., Kardaş G.2009, The stability of hydrogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution. International Journal of Hydrogen Energy 34, 2089.
  • Singh, A.K., Quraishi, M.A.,2009. Effect of 2,2′ benzothiazolyl disulfide on the corrosion of mild steel in acid media, Corrosion Science 51-2752.
  • Sudo K., Matsumoto, Y., Matsıshima M., Fujiwara, M. Konno, K. Shimotohno,K. Shiget S., Yokota, T. 1997.Hepatits C virus Protease Inhıbıtors Thioazolidine Derivatives .Biochemical and Biophiysical. Biochem. Biophys. Res. Commun. 238,643.
  • Yıldız, R. 2017 Düşük Karbonlu Çeliğin Korozyon Davranışına Hekzametilen Tetra Amin’in Etkisi Fırat Üniv. Müh. Bil. Dergisi Science and Eng. J of Fırat Univ.29(2), 147.

YUMUŞAK ÇELİĞİN ASİDİK ORTAMDAKİ KOROZYON DAVRANIŞINA 5-(4-Dimetilaminobenzyliden)-rodanin MOLEKÜLÜNÜN ETKİSİ

Yıl 2019, Cilt: 7 Sayı: 4, 803 - 810, 19.12.2019
https://doi.org/10.21923/jesd.455544

Öz

5-(4-Dimetilaminobenzyliden)-rodanin (D-Rh) molekülünün, yumuşak çeliğin
korozyonuna inhibisyon etkisi 0,5 M H2SO4 çözeltisinde,
elektrokimyasal impedans spektroskopisi, lineer polarizasyon direnci,
kronoamperimetri ve potansiyodinamik polarizasyon eğrilerinden yararlanılarak
araştırılmıştır. Deneysel sonuçlar inhbisyon etkinliğinin D-Rh’ın derişimi ile
artığını göstermiştir. Adsorpsiyon izotermi Langmuir adsorpsiyon izotermine
uymaktadır.  D-Rh molekülü için
aktivasyon enerjisi hesaplanmıştır. 

Kaynakça

  • Abbouda,, Y., Abourrichea, A., Berradaa, T. Saffaja, Charroufa, M., Bennamaraa, M., Hannacheb,A. H.,2009. A novel azo dye, 8-quinolinol-5-azoantipyrine as corrosion inhibitor for mild steel in acidic media, Desalination, 237, 175.
  • Aljourani, J., Raeissi, K., Golozar,M.A., 2009. Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution, Corrosion Science,51,1836.
  • Altunbaş, E., Solmaz,R., Kardaş G.,2010. Corrosion behaviour of polyrhodanine coated copper electrode in 0.1M H2SO4 solution. Material Chemist and Physic, 121,354..
  • Altunbaş,E. 2008. Polirodaninin Bakır Üzerine Elektrokimyasal Sentezi Ve Korozyon Davranışlarının Belirlenmesi, Yüksek Lisans Tezi. Çukurova Üniversitesi.Türkiye.
  • Döner, A., Kardas, G. 2011. N-Aminorhodanine as an effective corrosion inhibitor for mild steel in 0.5 M H2SO4,Corrosion. Science. 53, 4223.
  • Erbil, M., 1984. Korozyon İnhibitörleri, SEGEM, Ankara.
  • Erbil, M., 2012. Korozyon İlkeler Önlemler, Türkiye Korozyon Derneği, Ankara.
  • Foye W.O., Tovivich P.J.,2011. Pharm. Sci. 66,1607.
  • Quartarone, G., Bonaldo,L. Tortato,C.2006. Inhibitive action of indole-5-carboxylic acid towards corrosion of mild steel in deaerated 0.5 M sulfuric acid solutions, Applied Surf.ace Science 252,8251.
  • Kardaş G., 2005. The Inhibition Effect of 2-Thiobarbituric Acid on the Corrosion Performance of Mild Steel in HCl Solutions. Material Science, 41, 337.
  • Li, S.L., Wang,Y.G., Chen S.H., Yu, R., Lei, S.B., Ma, H.Y., Liu, X.De.1999, Some aspects of quantum chemical calculations for the study of Schiff base corrosion inhibitors on copper in NaCl solutions, Corrosion Science.41,1769.
  • Mishra, S., Srivastava, S.K. Indian 1997. J. Chem. Sected. B 36, 826.
  • Momose Y., Meguro K., Ikeda H., Hatanaka C., Oi, S. Sohda, T. 1991. Studies on Antidiabetic Agent Synthesis and Biogical Activities of Pioglitozone and Related Compounds Chem. Pharm. Bull.39,1440.
  • Musa, A. Y., Kadhum,A.A.H., Mohamad,A. B., Daud, A. R. M., Takriff, S., . Kamarudin, S. KA., 2009. comparative study of the corrosion inhibition of mild steel in sulphuric acid by 4,4-dimethyloxazolidine-2-thione, Corrosion Science. 51, 2393.
  • Öztürk S., Düşük karbon çeliğinin asidik ortamdaki korozyonuna karşı inhibitör özelliği gösteren 4-okso-kinazolin türevi katyonik yüzey aktif maddelerin sentezi 2018,Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22 (3), 986-1000
  • Solmaz, R., Kardaş, G., Yazıcı, B., Erbil, M., 2005. The Effect of Rhodanine on the Corrosion Performance of Mild Steel with Immersion Time. chemistry and material science, 41: 581-585.
  • Solmaz, R. 2010Investigation of the inhibition effect of 5-((E)-4-phenylbuta-1,3-dienylideneamino)-1,3,4-thiadiazole-2-thiol Schiff base on mild steel corrosion in hydrochloric acid, Corros.Sci. 52 3321-3330.
  • Solmaz,R.2014. Investigation of adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by 5-(4-Dimethylaminobenzylidene)rhodanine. Corros.Sci. 79,169.
  • Solmaz, R. Şahin, A. E., Kardas¸ G.2011. Adsorption and corrosion inhibition effect of 2((5mercapto1,3,4thiadiazolylimino)methyl)phenol Schiff base on mild steel, Mater.Chem. Phys.125 ,796.
  • Solmaz,R.,Döner A., Kardaş G.2009, The stability of hydrogen evolution activity and corrosion behavior of NiCu coatings with long-term electrolysis in alkaline solution. International Journal of Hydrogen Energy 34, 2089.
  • Singh, A.K., Quraishi, M.A.,2009. Effect of 2,2′ benzothiazolyl disulfide on the corrosion of mild steel in acid media, Corrosion Science 51-2752.
  • Sudo K., Matsumoto, Y., Matsıshima M., Fujiwara, M. Konno, K. Shimotohno,K. Shiget S., Yokota, T. 1997.Hepatits C virus Protease Inhıbıtors Thioazolidine Derivatives .Biochemical and Biophiysical. Biochem. Biophys. Res. Commun. 238,643.
  • Yıldız, R. 2017 Düşük Karbonlu Çeliğin Korozyon Davranışına Hekzametilen Tetra Amin’in Etkisi Fırat Üniv. Müh. Bil. Dergisi Science and Eng. J of Fırat Univ.29(2), 147.
Toplam 23 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Araştırma Makalesi \ Research Makaleler
Yazarlar

Ece Altunbaş Şahin 0000-0002-3201-0487

Yayımlanma Tarihi 19 Aralık 2019
Gönderilme Tarihi 28 Ağustos 2018
Kabul Tarihi 27 Mayıs 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 7 Sayı: 4

Kaynak Göster

APA Altunbaş Şahin, E. (2019). YUMUŞAK ÇELİĞİN ASİDİK ORTAMDAKİ KOROZYON DAVRANIŞINA 5-(4-Dimetilaminobenzyliden)-rodanin MOLEKÜLÜNÜN ETKİSİ. Mühendislik Bilimleri Ve Tasarım Dergisi, 7(4), 803-810. https://doi.org/10.21923/jesd.455544