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Current approaches to the synthesis of flame retardant polymers

Yıl 2022, Cilt: 2 Sayı: 2, 95 - 113, 27.07.2022
https://doi.org/10.29228/JIENS.63353

Öz

Polymeric materials are used in every field due to their easy processing and low-weight structure. However, because they are hydrocarbon-based, they are flammable, often producing toxic gases. Therefore, in the polymer industry, the development of flame retardant polymer materials is of great importance to increase the use of polymers. This review focuses on reviewing and classifying the latest developments in the knowledge and technology of flame retardant polymer materials and showing the qualitative and quantitative analyzes performed on their flame retardant properties. In addition, inorganic flame retardants containing hydroxide are disclosed, in addition to phosphorus and nitrogen elements, which replace halogens as flame retardant additives. Finally, it touches on the topic of “anti-flammable polymers,” a new strategy.

Kaynakça

  • Lu S-Y, Hamerton I (2002) Recent developments in the chemistry of halogen-free flame retardant polymers. Progress in Polymer Science 27 (8):1661-1712. https://doi.org/10.1016/S0079-6700(02)00018-7
  • Sinha Ray S, Kuruma M (2020) Polymer combustion and flame retardancy, In: Halogen-Free Flame-Retardant polymers. Springer International Publishing ss 5-9.
  • Gu L, Chen G, Yao Y (2014) Two novel phosphorus–nitrogen-containing halogen-free flame retardants of high performance for epoxy resin. Polymer Degradation and Stability 108:68-75. https://doi.org/10.1016/j.polymdegradstab.2014.05.030
  • Lewin M (1998) Physical and chemical mechanisms of flame retarding of polymers. Fire Retardancy of Polymers: Elsevier, ss 3-32.
  • Akdoğan E, Tarakçılar AR, Topcu M, Yurtseven R (2015) Alüminyum hidroksit ve magnezyum hidroksit katkısının termoplastik poliüretan malzemelerin mekanik özelliklerine etkisi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 21 (8):376-380. https://doi.org/10.5505/pajes.2015.24572
  • Vahabi H, Sonnier R, Ferry L (2015) Effects of ageing on the fire behaviour of flame‐retarded polymers: A review. Polymer International 64(3):313-328. https://doi.org/10.1002/pi.4841
  • Vahabi H, Laoutid F, Mehrpouya M, Saeb MR, Dubois P (2021) Flame retardant polymer materials: An update and the future for 3D printing developments. Materials Science Engineering: R: Reports 144:100604. https://doi.org/10.1016/j.mser.2020.100604
  • Mincheva R, Guemiza H, Hidan C, Moins S, Coulembier O, Dubois P, Laoutid F (2019) Development of inherently flame—retardant phosphorylated PLA by combination of ring-opening polymerization and reactive extrusion. Materials 13(1):13. https://doi.org/10.3390/ma13010013
  • Eren T, Aşçı A (2015) Synthesis and characterization of phosphonate based polynorbornene polymers derived from romp (ring opening metathesis polymerization) method and investigation their flame retardant properties. Sigma: Journal of Engineering & Natural Sciences/Mühendislik ve Fen Bilimleri Dergisi 33(4):615-625. https://eds.yildiz.edu.tr/sigma/
  • Yıldırım S, Çelik E (2014) Alev Geçiktirici Huntit ve Hidromanyezit Nanopartikül Takviyeli Polimetrik Kompozit Kaplamalar. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi 14 (3):387-393.
  • Velencoso MM, Battig A, Markwart JC, Schartel B, Wurm FR (2018) Molecular firefighting—how modern phosphorus chemistry can help solve the challenge of flame retardancy. Angewandte Chemie International Edition 57 (33):10450-10467. https://doi.org/10.1002/anie.201711735
  • Katırcıoğlu-Bayel D (2018) Alev geciktirici mineral dolgu maddeleri. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 7 (3):1175-1179.
  • Çakmakçı E, Güngör A (2013) Preparation and characterization of flame retardant and proton conducting boron phosphate/polyimide composites. Polymer Degradation and Stability 98 (5):927-933. https://doi.org/10.1016/j.polymdegradstab.2013.03.003
  • Gao C, Wang L, Lei Z, Yang L, Xu X, Guo X (2017) Property of intrinsic flame retardant epoxy resin cured by functional magnesium organic composite salt and diethylenetriamine. Fire Materials 41 (2):180-192. https://doi.org/10.1002/fam.2377
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  • Wang X, Kalali EN, Wan J-T, Wang D-Y (2017) Carbon-family materials for flame retardant polymeric materials. Progress in Polymer Science 69:22-46. https://doi.org/10.1016/j.progpolymsci.2017.02.001
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  • Weil ED, Patel NG, Said MM, Hirschler MM, Shakir S (1992) Oxygen index: Correlations to other fire tests. Fire and Materials 16 (4):159-167. https://doi.org/10.1002/fam.810160402
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Alev geciktirici polimerlerin sentezine yönelik güncel yaklaşımlar

Yıl 2022, Cilt: 2 Sayı: 2, 95 - 113, 27.07.2022
https://doi.org/10.29228/JIENS.63353

Öz

Günümüzde polimerik malzemeler kolay işlenebilmeleri ve düşük ağırlıklı yapıları nedeniyle her alanda kullanılmaktadır. Bununla birlikte, hidrokarbon esaslı olduklarından dolayı yanıcıdırlar, çoğu zaman zehirli gaz üretirler. Polimer sektöründe, alev geciktirici polimer malzemelerin gelişimi polimerlerin kullanımlarının arttırılması için büyük bir öneme sahiptir. Bu derleme, alev geciktirici polimer malzemelerin bilgi ve teknolojisindeki son gelişmeleri incelemeye, sınıflandırmaya ve alev geciktirici özellikleri üzerinde gerçekleştirilen kalitatif ve kantitatif analizleri göstermeye odaklanmaktadır. Ayrıca, alev geciktirici katkı maddesi olarak halojenlerin yerini tutan fosfor ve azot elementlerine ilave olarak hidroksit içerikli inorganik alev geciktiriciler açıklanmaktadır. Son olarak, alev geciktirici katkı maddelerinin zamanla ortamdan salınması nedeniyle polimer matrisi ile homojen olarak karışabilirliği sınırlı olduğundan ve mekanik özellikler üzerinde olumsuz etkisinden dolayı yeni bir strateji olan “yanmaz polimerler” konusuna değinmektedir.

Kaynakça

  • Lu S-Y, Hamerton I (2002) Recent developments in the chemistry of halogen-free flame retardant polymers. Progress in Polymer Science 27 (8):1661-1712. https://doi.org/10.1016/S0079-6700(02)00018-7
  • Sinha Ray S, Kuruma M (2020) Polymer combustion and flame retardancy, In: Halogen-Free Flame-Retardant polymers. Springer International Publishing ss 5-9.
  • Gu L, Chen G, Yao Y (2014) Two novel phosphorus–nitrogen-containing halogen-free flame retardants of high performance for epoxy resin. Polymer Degradation and Stability 108:68-75. https://doi.org/10.1016/j.polymdegradstab.2014.05.030
  • Lewin M (1998) Physical and chemical mechanisms of flame retarding of polymers. Fire Retardancy of Polymers: Elsevier, ss 3-32.
  • Akdoğan E, Tarakçılar AR, Topcu M, Yurtseven R (2015) Alüminyum hidroksit ve magnezyum hidroksit katkısının termoplastik poliüretan malzemelerin mekanik özelliklerine etkisi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 21 (8):376-380. https://doi.org/10.5505/pajes.2015.24572
  • Vahabi H, Sonnier R, Ferry L (2015) Effects of ageing on the fire behaviour of flame‐retarded polymers: A review. Polymer International 64(3):313-328. https://doi.org/10.1002/pi.4841
  • Vahabi H, Laoutid F, Mehrpouya M, Saeb MR, Dubois P (2021) Flame retardant polymer materials: An update and the future for 3D printing developments. Materials Science Engineering: R: Reports 144:100604. https://doi.org/10.1016/j.mser.2020.100604
  • Mincheva R, Guemiza H, Hidan C, Moins S, Coulembier O, Dubois P, Laoutid F (2019) Development of inherently flame—retardant phosphorylated PLA by combination of ring-opening polymerization and reactive extrusion. Materials 13(1):13. https://doi.org/10.3390/ma13010013
  • Eren T, Aşçı A (2015) Synthesis and characterization of phosphonate based polynorbornene polymers derived from romp (ring opening metathesis polymerization) method and investigation their flame retardant properties. Sigma: Journal of Engineering & Natural Sciences/Mühendislik ve Fen Bilimleri Dergisi 33(4):615-625. https://eds.yildiz.edu.tr/sigma/
  • Yıldırım S, Çelik E (2014) Alev Geçiktirici Huntit ve Hidromanyezit Nanopartikül Takviyeli Polimetrik Kompozit Kaplamalar. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi 14 (3):387-393.
  • Velencoso MM, Battig A, Markwart JC, Schartel B, Wurm FR (2018) Molecular firefighting—how modern phosphorus chemistry can help solve the challenge of flame retardancy. Angewandte Chemie International Edition 57 (33):10450-10467. https://doi.org/10.1002/anie.201711735
  • Katırcıoğlu-Bayel D (2018) Alev geciktirici mineral dolgu maddeleri. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 7 (3):1175-1179.
  • Çakmakçı E, Güngör A (2013) Preparation and characterization of flame retardant and proton conducting boron phosphate/polyimide composites. Polymer Degradation and Stability 98 (5):927-933. https://doi.org/10.1016/j.polymdegradstab.2013.03.003
  • Gao C, Wang L, Lei Z, Yang L, Xu X, Guo X (2017) Property of intrinsic flame retardant epoxy resin cured by functional magnesium organic composite salt and diethylenetriamine. Fire Materials 41 (2):180-192. https://doi.org/10.1002/fam.2377
  • Weil ED, Zhu W, Patel N, Mukhopadhyay SM (1996) A systems approach to flame retardancy and comments on modes of action. Polymer Degradation and Stability 54 (2-3):125-136. https://doi.org/10.1016/S0141-3910(96)00036-5
  • Wang X, Kalali EN, Wan J-T, Wang D-Y (2017) Carbon-family materials for flame retardant polymeric materials. Progress in Polymer Science 69:22-46. https://doi.org/10.1016/j.progpolymsci.2017.02.001
  • Nelson GL (1995) Fire and polymers: An overview. Fire and Polymers II ss 1-26.
  • Sinha Ray S, Kuruma M (2020) Flame-retardancy testing. In: Halogen-Free Flame-Retardant Polymers. Cham: Springer International Publishing ss 11-14.
  • Weil ED, Patel NG, Said MM, Hirschler MM, Shakir S (1992) Oxygen index: Correlations to other fire tests. Fire and Materials 16 (4):159-167. https://doi.org/10.1002/fam.810160402
  • Wan L, Deng C, Zhao Z-Y, Chen H, Wang Y-Z (2020) Flame retardation of natural rubber: strategy and recent progress. Polymers 12 (2):429. https://doi.org/10.3390/polym12020429
  • Akkurt S (2007) Plastik malzeme bilimi teknolojisi ve kalıp tasarımı. Birsen Yayınevi, İstanbul.
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  • Shan F, Ohashi S, Erlichman A, Ishida H (2018) Non-flammable thiazole-functional monobenzoxazines: Synthesis, polymerization, thermal and thermomechanical properties, and flammability studies. Polymer 157:38-49. https://doi.org/10.1016/j.polymer.2018.09.061
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Toplam 80 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Polimerler ve Plastikler
Bölüm Derlemeler
Yazarlar

Neşe Çakır Yiğit Bu kişi benim 0000-0002-4714-4488

Yayımlanma Tarihi 27 Temmuz 2022
Gönderilme Tarihi 29 Haziran 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 2 Sayı: 2

Kaynak Göster

APA Çakır Yiğit, N. (2022). Alev geciktirici polimerlerin sentezine yönelik güncel yaklaşımlar. Journal of Innovative Engineering and Natural Science, 2(2), 95-113. https://doi.org/10.29228/JIENS.63353


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