Microwave Assisted and Montmorillonite-K10 Catalyzed Alcohollysis of Benzonorbornadiene Oxide: Synthesis of Regioselective New Alkoxy Alcohols by Wagner–Meerwein Rearrangement

Öz

In this study, microwave assisted ring opening of benzonorbornadiene epoxide with alcohols was investigated. New alkoxy alcohols were synthesized regioselectively by Wagner–Meerwein rearrangement in short reaction times (up to 10 minutes) with high yield in the presence of a cheap and environmentally friendly heterogeneous montmorillonite-K10 catalyst. The products were purified by filtration only.

Anahtar Kelimeler

• Benzonorbornadiene oxide
• alkoxy alcohol
• montmorillonite-K10
• Wagner–Meerwein rearrangement
• microwave

Benzonorbornadien Oksit’in Mikrodalga Destekli ve Montmorillonite-K10 Katalizli Alkolizi: Wagner–Meerwein Düzenlenmesi ile Regioseçici Yeni Alkoksi Alkollerin Sentezi

Öz

Bu çalışmada, benzonorbornadien epoksitinin alkollerle mikrodalga destekli halka açılma tepkimeleri incelendi. Ucuz ve çevreci heterojen montmorillonite-K10 katalizörü eşliğinde yüksek verim ile kısa reaksiyon süresinde (10 dakikaya kadar) Wagner–Meerwein düzenlenmesi ile regioseçici olarak yeni alkoksi alkoller sentezlendi. Ürünler sadece süzme ile saflaştırıldı.

Anahtar Kelimeler

• Benzonorbornadien oksit
• alkoksi alkol
• montmorillonite-K10
• Wagner–Meerwein düzenlenmesi
• mikrodalga

Teşekkür

Bu çalışmaya katkılarından dolayı, Atatürk Üniversitesi Fen Fakültesi Kimya Bölümü’ne teşekkür ederiz.

Kaynakça

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