Kobalt Ferrit Nanoparçacıkların Sentezi, Karakterizasyonu ve Fotokataliz Uygulamaları:Farklı Çöktürücü Maddelerin ve Yöntemlerin Etkisi

Öz

Bu çalışmada, birlikte çöktürme ve sol-jel yöntemleri ile hazırlanan kobalt ferrit nanopartiküllerin yapısal ve fotokatalitik özellikleri üzerinde sentez yönteminin etkisine ilişkin bir araştırma sunulmaktadır. Çöktürücü maddeler olarak sodyum hidroksit, potasyum hidroksit ve amonyak, jelleştirici madde olarak sitrik asit kullanılmıştır. Elde edilen kobalt ferrit fotokatalizörlerinin karşılaştırmalı özellikleri X-ışını kırınımı (XRD), Fourier dönüşümü kızılötesi (FTIR) spektroskopisi, taramalı elektron mikroskobu (SEM) ve enerji dağılımlı X Işını analizi (EDX) karakterizasyon teknikleri ile incelenmiştir. Numunelerin fotokatalitik aktiviteleri, görünür bölge ışıması altında Kristal Viyolet (KV) ve Rhodamin B (RhB)'nin fotobozunması ile değerlendirildi. Birlikte çöktürme yöntemiyle ve çöktürücü madde olarak amonyak kullanılarak sentezlenen kobalt ferrit, diğer örneklerle karşılaştırıldığında daha üstün fotokatalitik aktivite sergiledi. Amonyak çöktürücüsü ile sentezlenen kobalt ferrit, fotokatalitik bozunma verimleri KV ve RhB için, 40 dakika ve 120 dakika sürelerden sonra sırasıyla %100 ve %91.2 olarak belirlendi. Boyaların fotobozunmasının yalancı birinci dereceden kinetik modeli takip ettiği bulundu. Amonyak çöktürücüsü ile sentezlenen kobalt ferrit, yalancı birinci dereceden hız sabitleri KV ve RhB için sırasıyla 0.0847 ve 0.0205/dak olarak belirlendi.

Anahtar Kelimeler

• Kobalt ferrit
• Birlikte çöktürme
• Sol-jel
• Karakterizasyon
• Fotokataliz

Synthesis, Characterization and Photocatalysis Applications of Cobalt Ferrite Nanoparticles: The Effect of Different Precipitating Agents and Methods

Öz

In this study, a research on the effect of synthesis method on the structural and photocatalytic properties of cobalt ferrite nanoparticles prepared by co-precipitation and sol-gel methods is presented. Sodium hydroxide, potassium hydroxide and ammonia were used as precipitating agents and citric acid was used as gelling agent. The comparative properties of the obtained cobalt ferrite photocatalysts were investigated by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) characterization techniques. The photocatalytic activities of the samples were evaluated by photodegradation of Crystal Violet (KV) and Rhodamine B (RhB) under visible irradiation. cobalt ferrite synthesized by co-precipitation method and using ammonia as the precipitant showed superior photocatalytic activity compared to other samples. Photocatalytic degradation efficiencies of cobalt ferrite synthesized with ammonia precipitator were determined as 100% and 91.2% for KV and RhB after 40 minutes and 120 minutes, respectively. The photodegradation of the dyes was found to follow the pseudo-first-order kinetic model. The pseudo-first order rate constants of cobalt ferrite synthesized with ammonia precipitator were determined as 0.0847 ve 0.0205/min for KV and RhB, respectively

Anahtar Kelimeler

• • Cobalt ferrite
• Co-precipitation
• Sol-gel
• Characterization
• Photocatalysis

Kaynakça

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