Araştırma Makalesi

Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics

Cilt: 13 Sayı: 3 1 Eylül 2023
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Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics

Öz

Aim of this study, adsorption potential of modified and natural materials is investigated. The adsorbent used is watermelon peel (WP) derived from agricultural wastes to remove crystal violet (CV). The modified and raw adsorbent was characterized by Elemental analysis, Scanning electron microscope (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The studied parameters are temperature, initial metal concentration, and contact time. The most suitable kinetic (R2=0.99) and isotherm (R2=0.99) models were determined as Pseudo-second-order and Langmuir, respectively. The maximum adsorption capacity (qmax) according to Langmuir is 236.9 mg/g at 30°C. Thermodynamic analysis revealed spontaneous and endothermic adsorption of CV on modified watermelon peels. These results demonstrate that crystal violet can be removed from agricultural wastes using a low-cost adsorbent.

Anahtar Kelimeler

Destekleyen Kurum

Tübitak

Proje Numarası

2209-A

Kaynakça

  1. Aldemir, A., Kul, A. R. (2020). Isotherm, kinetic and thermodynamic studies for the adsorption of methylene blue on almond leaf powder. Cumhuriyet Science Journal, 41(3), 651-658. https://doi.org/10.17776/csj.720332.
  2. Al-Ghouti, M.A., Da'ana, D.A., (2020). Guidelines for the use and interpretation of adsorption isotherm models: A review. Journal of Hazardous Materials, 393, 122383. https://doi.org/10.1016/j.jhazmat.2020.122383.
  3. Ali, N.S., Jabbar, N.M., Alardhi, S.M., Majdi, H.S., Albayati, T.M. (2022). Adsorption of methyl violet dye onto a prepared bio-adsorbent from date seeds: isotherm, kinetics, and thermodynamic studies, Heliyon, 8(8), e10276. https://doi.org/10.1016/j.heliyon.2022.e10276.
  4. Bayram, O., Moral, E., Göde, F. (2023). Removal of Crystal Violet Dye from Aqueous Solution Using Biochar Obtained from Oleaster Seeds. Journal of the Institute of Science and Technology,13(1), 448-457. https://doi.org/10.21597/jist.1170769
  5. Ben-Ali, S., Jaouali, I., Souissi-Najar, S., Ouederni, A. (2017). Characterization and adsorption capacity of raw pomegranate peel biosorbent for copper removal. Journal of Cleaner Production, 142(4), 3809-3821. https://doi.org/10.1016/j.jclepro.2016.10.081.
  6. Dinçer, A. Sevildik, M., Aydemir, T. (2019). Optimization, isotherm and kinetics studies of azo dye adsorption on eggshell membrane. International Journal of Chemistry and Technology, 3(1), 52-60. https://doi.org/10.32571/ijct.538736.
  7. Fatma O. E. (2019). Freundlich, Langmuir, Temkin, DR and Harkins-Jura Isotherm Studies on the Adsorption of CO2 on Various Porous Adsorbents. International Journal of Chemical Reactor Engineering, 17(5), 20180134. https://doi.org/10.1515/ijcre-2018-0134.
  8. Foo, K.Y., Hameed, B.H., Insights into the modeling of adsorption isotherm systems, Chemical Engineering Journal, 156(1), 2-10. https://doi.org/10.1016/j.cej.2009.09.013.

Ayrıntılar

Birincil Dil

İngilizce

Konular

Kimya Mühendisliği

Bölüm

Araştırma Makalesi

Erken Görünüm Tarihi

29 Ağustos 2023

Yayımlanma Tarihi

1 Eylül 2023

Gönderilme Tarihi

1 Nisan 2023

Kabul Tarihi

25 Mayıs 2023

Yayımlandığı Sayı

Yıl 2023 Cilt: 13 Sayı: 3

Kaynak Göster

APA
Küçük, İ., & Gözcü, M. (2023). Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics. Journal of the Institute of Science and Technology, 13(3), 1946-1957. https://doi.org/10.21597/jist.1275258
AMA
1.Küçük İ, Gözcü M. Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics. Iğdır Üniv. Fen Bil Enst. Der. 2023;13(3):1946-1957. doi:10.21597/jist.1275258
Chicago
Küçük, İlhan, ve Merve Gözcü. 2023. “Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics”. Journal of the Institute of Science and Technology 13 (3): 1946-57. https://doi.org/10.21597/jist.1275258.
EndNote
Küçük İ, Gözcü M (01 Eylül 2023) Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics. Journal of the Institute of Science and Technology 13 3 1946–1957.
IEEE
[1]İ. Küçük ve M. Gözcü, “Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics”, Iğdır Üniv. Fen Bil Enst. Der., c. 13, sy 3, ss. 1946–1957, Eyl. 2023, doi: 10.21597/jist.1275258.
ISNAD
Küçük, İlhan - Gözcü, Merve. “Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics”. Journal of the Institute of Science and Technology 13/3 (01 Eylül 2023): 1946-1957. https://doi.org/10.21597/jist.1275258.
JAMA
1.Küçük İ, Gözcü M. Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics. Iğdır Üniv. Fen Bil Enst. Der. 2023;13:1946–1957.
MLA
Küçük, İlhan, ve Merve Gözcü. “Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics”. Journal of the Institute of Science and Technology, c. 13, sy 3, Eylül 2023, ss. 1946-57, doi:10.21597/jist.1275258.
Vancouver
1.İlhan Küçük, Merve Gözcü. Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics. Iğdır Üniv. Fen Bil Enst. Der. 01 Eylül 2023;13(3):1946-57. doi:10.21597/jist.1275258