Araştırma Makalesi

Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties

Cilt: 14 Sayı: 1 1 Mart 2024
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Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties

Öz

The design and synthesis of polyoxometalates (POMs), a type of inorganic compounds, are of great interest due to their interesting structural properties as well as their extensive theoretical and practical applications in catalysis, electrical conductivity, magnetism, optics and medicine. Therefore, in this study two molybdovanadates [Cu(phen)2]3[Mo6V2O26]·4H2O and [Cu(bpy)2]3[Mo6V2O26]·4H2O have been prepared by the reaction of the [Mo6V2O26]6- anion with Cu(CH3COO)2 and 1,10-phenanthroline/2,2'-bipyridine in aqueous medium; characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Nuclear Magnetic Resonance (1H NMR), Inductively coupled plasma mass spectrometry (ICP-MS), Thermogravimetric Analysis (TGA) and elemental analysis. The compounds show antibacterial activity against Escherichia coli (E. Coli) and Staphylococcus aureus (S. Aureus).

Anahtar Kelimeler

Kaynakça

  1. Abebe, A., Bayeh, Y., Belay, M., Gebretsadik, T., Thomas, M., Linert, W. (2020). Mono and binuclear cobalt(II) mixed ligand complexes containing 1,10-phenanthroline and adenine using 1,3-diaminopropane as a spacer: synthesis, characterization, and antibacterial activity investigations. Future Journal of Pharmaceutical Sciences, 6, 13.
  2. Avcı Özbek, H., Kopar, E., Demirhan, F. (2021). Synthesis, structure, and antimicrobial properties of mixed-metal organometallic polyoxometalates. [Cp*2M5VO17]- (M=Mo, W). Journal of Coordination Chemistry, 74, 1794-1809.
  3. Avcı Özbek, H. (2023). V-subtituted lindqvist-type polyoxometalates: preparation, structural characterization and antibacterial activity. Chemical Papers, 77, 5663-5669.
  4. Bijelic, A., Aureliano, M. and Rompel, A. (2015). The antibacterial activity of polyoxometalates: structures, antibiotic effects and future perspectives. Chemical Communications, 54, 1153-1169.
  5. Bijelic, A., Rompel, A. (2015). The use of polyoxometalates in protein crystallography – An attempt to widen a well-known bottleneck. Coordination Chemistry Reviews. 299, 22-38.
  6. Bildirici, I., Cetin, A., Menges, N., Alan Y. (2023). Synthesis and SAR studies of pyrazole-3-carboxamides and -3-carbonyl thioureides including chiral moiety: Novel candidates as antibacterial agents. Journal of the Serbian Chemical Society. 83 (7-8), 795-807.
  7. Björnberg, A., (1975). Multicomponent polyanions. 26. The crystal structure of Na6Mo6V2O26(H2O)16, a compound containing sodium-coordinated hexamolybdodi vanadate anions. Acta Crystallographica, B35, 1995-1999.
  8. Buvailo, H.I., Makhankova, V.G., Kokozay, V.N., Omelchenko, I. V., Shishkina,S. V., Jezierska, J., Pavliuk M.V., Shylin, S.I. (2019). Copper-containing hybrid compounds based on extremely rare [V2Mo6O26]6- POM as water oxidation catalysts. Inorganic Chemistry Frontiers, 6, 1813–1823.

Ayrıntılar

Birincil Dil

İngilizce

Konular

Organik Kimya (Diğer)

Bölüm

Araştırma Makalesi

Erken Görünüm Tarihi

20 Şubat 2024

Yayımlanma Tarihi

1 Mart 2024

Gönderilme Tarihi

22 Ağustos 2023

Kabul Tarihi

4 Aralık 2023

Yayımlandığı Sayı

Yıl 2024 Cilt: 14 Sayı: 1

Kaynak Göster

APA
Avcı Özbek, H. (2024). Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Journal of the Institute of Science and Technology, 14(1), 356-362. https://doi.org/10.21597/jist.1347906
AMA
1.Avcı Özbek H. Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Iğdır Üniv. Fen Bil Enst. Der. 2024;14(1):356-362. doi:10.21597/jist.1347906
Chicago
Avcı Özbek, Hülya. 2024. “Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties”. Journal of the Institute of Science and Technology 14 (1): 356-62. https://doi.org/10.21597/jist.1347906.
EndNote
Avcı Özbek H (01 Mart 2024) Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Journal of the Institute of Science and Technology 14 1 356–362.
IEEE
[1]H. Avcı Özbek, “Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties”, Iğdır Üniv. Fen Bil Enst. Der., c. 14, sy 1, ss. 356–362, Mar. 2024, doi: 10.21597/jist.1347906.
ISNAD
Avcı Özbek, Hülya. “Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties”. Journal of the Institute of Science and Technology 14/1 (01 Mart 2024): 356-362. https://doi.org/10.21597/jist.1347906.
JAMA
1.Avcı Özbek H. Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Iğdır Üniv. Fen Bil Enst. Der. 2024;14:356–362.
MLA
Avcı Özbek, Hülya. “Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties”. Journal of the Institute of Science and Technology, c. 14, sy 1, Mart 2024, ss. 356-62, doi:10.21597/jist.1347906.
Vancouver
1.Hülya Avcı Özbek. Molybdenum–Vanadium Oxide Clusters: Syntheses, Structures and Antibacterial Properties. Iğdır Üniv. Fen Bil Enst. Der. 01 Mart 2024;14(1):356-62. doi:10.21597/jist.1347906

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