The Utilisation of NaOH-Modified Poly(2,5-dihydroxy-2,5-dimethoxyfuran) for The Removal of Cationic Dye

Öz

In this study, NaOH modified poly(2,5-dihydro-2,5-dimethoxyfuran) was synthesized and its structure was characterized by FT-IR spectroscopy technique for its potential use as an adsorbent in the removal of methyl violet (MV), a textile dye, from aqueous solutions. The optimum conditions for adsorption by batch method were evaluated by varying various parameters such as contact time, initial pH and concentration of the solution. The equilibrium adsorption concentration was found to be maximum 637.04 mg/g at the end of 60 min at a concentration of 200 mg/L MV at stock solution pH of the dye. The adsorption was in good agreement with the Langmuir isotherm model. MV adsorption is in good agreement with the pseudo-second-order rate kinetic model. These results indicate that the modified polymer has a high potential, especially for removing cationic dyes from waste water.

Anahtar Kelimeler

• Environmental pollution
• Waste water
• Dye removal
• Methyl violet
• Adsorption

NaOH ile Modifiye Edilmiş Poli(2,5-dihidro-2,5-dimetoksifuran)’ın Katyonik Boya Gideriminde Kullanımı

Öz

Bu çalışmada bir tekstil boyası olan metil viyole (MV)’nin sulu çözeltilerden gideriminde, potansiyel bir adsorban olarak kullanılması için NaOH ile modifiye edilen poli(2,5-dihidro-2,5-dimetoksifuran) sentezlendi ve bu polimerin yapısı FT-IR spektrokopisi tekniği kullanılarak karakterize edildi. Kesikli yöntem ile adsorpsiyon için optimum koşullar, temas süresi, çözeltinin başlangıç pH'sı ve konsantrasyonu gibi çeşitli parametreler değerlendirildi. Denge adsorpsiyon derişimi boyanın stok çözelti pH’sında 200 mg/L MV derişiminde 60 dakika sonunda maksimum 637.04 mg/g olarak bulundu. Adsorpsiyon Langmuir izoterm modeli ile iyi bir şekilde uyuşmaktadır. MV adsorpsiyonu, ikinci dereceden hız kinetik modeli ile uyumludur. Bu sonuçlar, modifiye polimerin özellikle katyonik boyaların atık sulardan gideriminde yüksek bir potansiyele sahip olduğunu göstermektedir.

Anahtar Kelimeler

• Çevre kirliliği
• Atık su
• Boya giderimi
• Metil viyole
• Adsorpsiyon

Kaynakça

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