Mangan(II) ile 2-hydroxy-1,4-naphthoquinone Kompleksinin Hazırlanması, Infrard ve Raman Spektrumları Yardımıyla Moleküler Yapının Aydınlatılması ve Titreşim Bantlarının Teorik Olarak Hesaplaması

Öz

2-hydroxy-1,4-naphthoquinone molekülü ile Mn(II) kompleksi ((2HNQ)2Mn) ilk kez hazırlandı. Hazırlanan bu kompleksin elemental analizleri yapıldı, infrared ve Raman spektrumları 4000-30 cm-1 aralığında kaydedildi ve yapısı hakkında tahminde bulunuldu. Yine Deneysel olarak gözlenen titreşim bantları ve şiddetleri, teorik olarak, HF metoduyla 6-31G(dp) temel fonksiyonu kullanılarak hesaplandı. Deneysel ve teorik olarak elde edilen değerler bire-bir karşılaştırıldı.

Anahtar Kelimeler

• Hf
• infrared
• raman
• 2-hydroxy-1
• 4-naphthoquinone

Preparation of Manganese (II) Complexed with 2-hydroxy-1,4- naphthoquinone, Identification of Molecular Structure with the Help the Infrared and Raman Spectra and Theoretical Calculations of Vibration Bands

Öz

Manganese(II) complex of 2-hydroxy-1,4-naphthoquinone ((2HNQ)2Mn) (Mn: Manganese) have been prepared for the frst time, elemental analysis of this complex prepared was obtained, infrared and Raman spectra were recorded in 4000-30 cm-1 range and molecular structure were estimated. However, the experimentally observed vibrational bands and intensity was calculated at HF using the 6-31G (dp) basic function. The obtained experimental and theoretical values were compared one-to-one.

Anahtar Kelimeler

• Hf
• infrared
• raman
• 2-hydroxy-1
• 4-naphthoquinone

Kaynakça

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