Investigation of Adsorption Characteristic of Basic Blue 41 (BB41) onto Raw Kütahya Ca-Bentonite

Öz

The objective of this research concerns the adsorption characteristic of the cationic azo dye namely Basic Blue 41(BB41) from aqueous solution was investigated on raw Kütahya Ca-Bentonite. In batch configuration, the effects of experimental parameters, such as contact time (0–300 min.), pH (3−8), Ca-Bentonite dose (0.01–0.1 g) and initial dye concentration (40–100 mg L−1) on the removal efficiency were studied. Optimum conditions from experimentally data, to be concentration of 40 mg L-1, pH: 4.0, contact time: 90 min. and amount of adsorbent to be 0.02 g were obtained. Two parameter (Freundlich, Langmuir and Dubinin-Radushkevich) adsorption isotherm models were applied on obtained experimental result and the model constant were calculated. The best equilibrium model was chosen based on the linear square regression correlation coefficient, R2. The experimental data for the adsorption equilibrium of BB41 has been interpreted with the linearized Langmuir model (R2~1) compared to Freundlich one (R2=0.9333). Maximum adsorption capacity of bentonite was obtained 119.4 mg g-1.

Anahtar Kelimeler

• Adsorption,bentonite,dye removal,adsorption isotherms,Blue Basic41

İşlem Görmemiş Kütahya Ca-Bentonitinin Bazik Mavi 41 (BB41) Adsorpsiyon Karakteristiğinin İncelenmesi

Öz

Bu araştırmanın amacı, katyonik azo boyar madde olan ve Bazik Mavi 41 (BB41) olarak isimlendirilen boyar maddenin sulu çözeltilerden işlem görmemiş Kütahya Ca-Bentoniti üzerine adsorpsiyon karakteristiğinin incelenmesidir. Kesikli çalışma yöntemiyle, temas süresi (0-300dak.), pH (3-8), Ca−Bentonit dozu (0.01-0.1 g) ve başlangıç boya konsantrasyonu (40-100 mg L-1) gibi deneysel parametrelerin giderim verimi üzerindeki etkileri çalışılmıştır. Deneysel verilerden optimum koşullar, 40 (mg L-1) başlangıç konsantrasyonu için; pH:4.0, temas süresi: 90 dak. ve 0.02 g adsorbant miktarı olarak elde edilmiştir. İki parametreli adsorpsiyon izoterm modelleri (Freundlich, Langmuir ve Dubinin-Radushkevich) deneysel olarak elde edilen sonuçlara uygulanıp model sabitleri hesaplanmıştır. En iyi denge modeli lineer regresyon korelasyon katsayısı, R2’ye bağlı olarak seçilmiştir. BB41’in denge adsorpsiyonu için elde edilen deneysel veriler lineerleştirilmiş Langmuir modeli (R2~1) ile Freundlich modeli (R2=0.9333) karşılaştırılarak yorumlanmıştır. Bentonitin maksimum adsorpsiyon kapasitesi 119.4 mg g-1 olarak elde edilmiştir.

Anahtar Kelimeler

• Adsorpsiyon,bentonit,boyar madde giderimi,adsorpsiyon izotermleri,Bazik Mavi 41

Kaynakça

1. Abadulla, T., Tzanov, S., Costa, K. H., Robra, A., Cavaco-Paulo, G. G., 2000. Decolorization and Detoxification of Textile Dyes with a Laccase from Trametes Hirsuta, Applied Environmental Microbiology 66: 3357-3362.
2. Afshin A, Mokhtari S. A, Vosoughi M, Sadeghi H, Rasthbari Y, 2018. Data of Adsorption of BB41 Dye from Aqueous Solutions by Activated Carbon Prepared from Filamentous Algae, Data in Brief, 21: 1008-1013.
3. Boudechichea N, Faresb M, Ouyahiab S, Yazida H, Traric M, Sadaouia Z, 2019. Comparative Study on Removal of Two Basic Dyes in Aqueous Medium by Adsorption Using Activated Carbon from Ziziphus Lotus Stones, Microchemical Journal 146: 1010–1018.
4. Dubinin, M. M, Radushkevic, L.V, 1947. Equation of the Characteristic Curve of Activated Charcoal, Chem. Zentr, 1: 875.
5. Faraji H, Mazloomi S, Mohammadi F, Ahmadi, Soheil Arezoomand HR, 2016. Raw and Modified Rice Husk Performance in Removal of Basic Blue 41 from Aqueous Solutions. Journal of Occupational and Environmental Health, 1(1): 41-49.
6. Ghanei M, Rashidi A, Tayebi H, Yazdanshenas M, 2018. Removal of Acid Blue 25 from Aqueous Media by Magnetic-SBA-15/CPAA Super Adsorbent: Adsorption Isotherm, Kinetic, and Thermodynamic Studies. Journal of Chemical and Engineering Data, 63(9), 3592–3605.
7. Giles C. H, MacEwan T. H, Nakhwa S. N, Smith D, 1960. Studies in Adsorption. Part XI. A System of Classification of Solution Adsorption Isotherms, and Its Use in Diagnosis of Adsorption Mechanisms and In Measurements of Specific Surface Areas of Solids, 3973–3993.
8. Günay A, Dikmen S, Ersoy B, Evcin A, 2014. Bazik Mavi-16 Boyar Maddesinin Kil Üzerine Adsorpsiyonu. Avrupa Bilim ve Teknoloji Dergisi, 1 (2): 29-38.

9. Hassan H. M, Elkady, M. F, El-Shazly A.H, Bamufleh H. S, 2014. Formulation of Synthesized Zinc Oxide Nanopowder into Hybrid Beads for Dye Separation. Journal of Nanomaterials.
10. Humelnicu I, Baiceanu A, Ignat M, Dulman V, 2016. The Removal of Basic Blue 41 Textile Dye from Aqueous Solution by Adsorption onto Natural Zeolitic Tuff: Kinetics and Thermodynamics. Process Safety and Environment Protection, 105: 274-287.
11. Jiang Y, Luo Y, Zhang F, Guo L, Ni L, 2013. Equilibrium and Kinetic Studies of C.I. BB41 Adsorption onto N, F-Codoped Flower-like TiO2 Microspheres. Applied Surface Science, 273: 448-456
12. Kalpaklı Y, 2018. İşlem Görmemiş Ca-Bentonit Üzerine Çinko Adsorpsiyonunun Reaksiyon Koşullarının Belirlenmesi. ÖHÜ Müh. Bilim. Derg. 7 (2): 1004-1012.
13. Kalpaklı Y, Toygun Ş, Köneçoğlu G, Akgün M, 2014. Equilibrium and Kinetic Study on the Adsorption of Basic Dye (BY28) onto Raw Ca-bentonite. Desalination and Water Treatment, 52: 7389-7399.
14. Kayacan S, 2007. Kömür ve Koklarla Sulu Çözeltilerden Boyar Maddelerin Uzaklaştırılması, Ankara Üniversitesi Fen Bilimleri Enstitü, Yüksek Lisans Tezi.
15. Kılıçaslan, R, 1999. Yeni Bazı Azo Boyar Maddelerin Metal Komplekslerinin Sentezi ve Yapılarının Aydınlatılması, Pamukkale Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi.
16. Kooli F, Yan L, Al-Faze R, Al-Sehimi A, 2015a. Removal Enhancement of Basic Blue 41 by Brick Waste from an Aqueous Solution. Arabian Journal of Chemistry, 8: 333-342.
17. Kooli F, Yan L, Al-Faze R, Suhaimi A, 2015b. Effect of Acid Activation of Saudi Local Clay Mineral on Removal Properties of BB41 from an Aqueous Solution. Applied Clay Science 116-117: 23-30.
18. Lian L, Guo L, Guo C, 2009. Adsorption of Congo Red from Aqueous Solutions onto Ca-bentonite. Journal of Hazardous Materials, 161: 126–131.
19. Mahmoodi N. M, Hayati B, Arami M, 2012. Kinetic, Equilibrium and Thermodynamic Studies of Ternary System Dye Removal Using a Biopolymer. Industrial Crops and Products, 35: 295-301.
20. Namal O, 2017. Tekstil Endüstrisi Atıksularının Arıtımında Kullanılan Proseslerin Araştırılması. Nevşehir Bilim ve Teknoloji Dergisi, 6 (Özel Sayı): 388-396.
21. Ncibi M. C, Mahjoub B, Seffen M, 2007. Kinetic and Equilibrium Studies of Methylene Blue Biosorption by Posidonia Oceanica (L.) Fibres. Journal of Hazardous Materials, 139: 280-258.
22. Nwodika C, Onukwuli O, 2017. Adsorption Study of Kinetics and Equilibrium of Basic Dye on Kola Nut Pod Carbon. GU J Sci, 30(4): 86-102.
23. Pirkarami A, Olya M, 2017. Removal of Dye from Industrial Wastewater with an Emphasis on Improving Economic Efficiency and Degradation Mechanism. Journal of Saudi Chemical Society, 21: 179–186
24. Salleh M. A. M, Mahmoud D. K, Karim W. A. W. A, Idris A, 2011. Cationic and Anionic Dye Adsorption by Agricultural Solid Wastes: A Comprehensive Review. Desalination, 1(3): 1-13.
25. Sivaram, N. M., Gopal, P. M. 2019. Toxic Waste from Textile Industries. Energy from Toxic Organic Waste for Heat and Power Generation Cambridge: Woodhead Publishing pp. 44-54.
26. Soleimani-Gorgani A, Taylor J. A, 2011. Synthesis and Evaluation of a Novel Blue Cationic Reactive Dye for Modified Nylon 6.6 ‘Tactel Coloursafe’. Society of Dyers and Colourists / Coloration Technology, 127: 227-234.
27. Uysal Y, Kereci F, 2016. Tekstil Atık Külü ile Tekstil Atık Suyundan Renk Giderimi. KSU Mühendislik Bilimleri Dergisi, 19(3): 82-86.
28. Worch E, 2012. Adsorpiton Technology in Water Treatment; Fundamentals, Proc. and Mod. pp. 41-58, Dresden-Germany.
29. Yeddou-Mezenner N, 2010. Kinetics and Mechanism of Dye Biosorption onto an Untreated Antibiotic Waste. Desalination, 262: 251-259.
30. Zarezadeh-Mehrizi M, Badiei A, 2014. Highly Efficient Removal of BB41 with Nanoporous Silica. Water Resources and Industry, 5: 49-57.