Vortex-assisted ionic liquid-based dispersive liquid-liquid micro-extraction and spectrofluorometric determination of Rhodamine B in anti-freeze, lipstick, liquid soap, matches and red pencil core

Öz

A simple, centrifugeless vortex-assisted ionic liquid-based dispersive liquid-liquid micro-extraction method was developed for spectrofluorometric determination of Rhodamine B dye. Analytical extraction parameters including pH, type and amount of ionic liquid, salt concentration, vortex rate and time were examined and optimized. Matrix effects of potentially interfering ions and dyes were investigated and their tolerable concentrations were determined by applying optimum conditions. Detection limit and preconcentration factor were determined 0.01 μg L-1 and 30, respectively. Dynamic range of the method was linear at RhB concentration range between 0.025 and 1000 μg L-1. Relative standard deviations were 3.9% for the ten replicates measurements of 0.125 μg L-1 Rhodamine B. The method was successfully applied to different samples including anti-freezes, liquid soap, matches, red pencil core and lipsticks. RhB concentrations of liquid and solid samples were determined between 2.05 μg mL-1 and 10.05 μg mL-1 and 307 μg g-1 and 2.75 mg g-1, respectively.

Anahtar Kelimeler

• Dispersive liquid-liquid micro-extraction
• ionic liquid
• rhodamine B
• spectrofluorometry

Kaynakça

1. Alesso M, Bondioli G, Talío MC, Luconi MO, Fernández LP, 2012. Micelles mediated separation fluorimetric methodology for Rhodamine B determination in condiments, snacks and candies. Food Chemistry, 134: 513–517.
2. Altunay N, Elik A, Gürkan R, 2019. Monitoring of some trace metals in honeys by flame atomic absorption spectrometry after ultrasound assisted-dispersive liquid liquid microextraction using natural deep eutectic solvent. Microchemical Journal, 147: 49-59.
3. Bagheri H, Daliri R, Roostaie A, 2013. A novel magnetic poly(aniline-naphthylamine)-based nanocomposite for micro solid phase extraction of rhodamine B. Analytica Chimica Acta, 794: 38-46.
4. Bağda E, Tüzen M, 2017. A simple and sensitive vortex-assisted ionic liquid-dispersive microextraction and spectrophotometric determination of selenium in food samples Food Chemistry, 232: 98-104.
5. Bakheet AAA, Zhu XS, 2017. Determination of Rhodamine B in Food Samples by Fe3O4@Ionic Liquids-β-Cyclodextrin Cross Linked Polymer Solid Phase Extraction Coupled with Fluorescence Spectrophotometry. Journal of Fluorescence, 27: 1087-1094.
6. Bişgin AT, 2018. Simultaneous Preconcentration and Determination of Brilliant Blue and Sunset Yellow in Foodstuffs by Solid-Phase Extraction Combined UV-Vis Spectrophotometry. Journal of AOAC International, 101: 1850-1856.
7. Bişgin AT, Sürme Y, Uçan M, Narin İ, 2018. Separation, Preconcentration and Spectrophotometric Determination of Rhodamine B in Industrial, Cosmetic and Water Samples by Cloud Point and Solid Phase Extraction. Journal of Analytical Chemistry, 73: 452-458.
8. Bişgin AT, 2019a. Simultaneous Extraction and Determination of Allura Red (E129) and Brilliant Blue FCF (E133) in Foodstuffs by Column Solid-Phase Spectrophotometry. Journal of AOAC International, 102: 181-188.

9. Bişgin AT, 2019b. Surfactant-Assisted Emulsification and Surfactant-Based Dispersive Liquid–Liquid Microextraction Method for Determination of Cu(II) in Food and Water Samples by Flame Atomic Absorption Spectrometry. Journal of AOAC International, 102: 1516-1522.
10. Chen D, Zhao Y, Miao H, Wu Y, 2014. A novel cation exchange polymer as a reversed-dispersive solid phase extraction sorbent for the rapid determination of rhodamine B residue in chili powder and chili oil. Journal of Chromatography A, 1374: 268-272.
11. Chen J, Zhu X, 2016. Magnetic solid phase extraction using ionic liquid-coated core-shell magnetic nanoparticles followed by high-performance liquid chromatography for determination of Rhodamine B in food samples. Food Chemistry, 200: 10-15.
12. Cheng YY, Tsai TH, 2016. A validated LC–MS/MS determination method for the illegal foodadditive rhodamine B: Applications of a pharmacokinetic study in rats. Journal of Pharmaceutical and Biomedical Analysis, 125: 394–399.
13. Elik A, Altunay N, Gürkan R, 2017. Microextraction and preconcentration of Mn and Cd from vegetables, grains and nuts prior to their determination by flame atomic absorption spectrometry using room temperature ionic liquid. Journal of Molecular Liquids, 247: 262-268.
14. Fu DS, Wu PP, Zhong XD, Liu Q, Luo HD, Li YQ, 2015. A Simple Synchronous Fluorescence Approach for Rapid and Sensitive Determination of Rhodamine B in Chilli Products. Food Analytical Methods, 8: 189-194.
15. Ghasemi E, Kaykhaii M, 2016. Application of Micro-cloud point extraction for spectrophotometric determination of Malachite green, Crystal violet and Rhodamine B in aqueous samples. Spectrochimica Acta A, 164: 93–97.
16. Li J, Ding XM, Liu DD, Guo F, Chen Y, Zhang YB, Liu HM, 2013. Simultaneous determination of eight illegal dyes in chili products by liquid chromatography–tandem mass spectrometry. Journal of Chromatography B, 942-943: 46-52.
17. Li L, Chen W, Li H, Iqba J, Zhu Y, Wu T, Du Y, 2020. Rapid determination of fumonisin (FB1) by syringe SPE coupled with solid-phase fluorescence spectrometry. Spectrochimica Acta A, 226: 117549 1-6.
18. Liang F, Jin D, Ma P, Wang D, Yang Q, Song D, Wang X, 2015. Rapid Determination of Rhodamine B in Chili Powder by Surface-Enhanced Raman Spectroscopy. Analytical Letters, 48:1918-1929.
19. Liu X, Zhang X, Zhou Q, Bai B, Ji S, 2013. Spectrometric Determination of Rhodamine B in Chili Powder After Molecularly Imprinted Solid Phase Extraction. Bulletin of the Korean Chemical Society, 34: 3381-3386.
20. Nekoeinia M, Dehkordi MK, Kolahdoozan M, Yousefinejad S, 2016. Preparation of epoxidized soybean oil-grafted Fe3O4–SiO2 as a water-dispersible hydrophobic nanocomposite for solid-phase extraction of rhodamine B. Microchemical Journal, 129: 236–242.
21. Pourreza N, Rastegarzadeh S, Larki A, 2008. Micelle-mediated cloud point extraction and spectrophotometric determination of rhodamine B using Triton X-100. Talanta, 77: 733-736.
22. Qi P, Lin Z, Li J, Wang CL, Meng WW, Hong H, Zhang X, 2014. Development of a rapid, simple and sensitive HPLC-FLD method for determination of rhodamine B in chili-containing products. Food Chemistry, 164: 98-103.
23. Ranjbari E, Hadjmohammadi MR, 2015. Optimization of magnetic stirring assisted dispersive liquid–liquid microextraction of rhodamine B and rhodamine 6G by response surface methodology: Application in water samples, soft drink, and cosmetic products. Talanta, 139: 216-225.
24. Roostaie A, Allahnoori F, Ehteshami S, 2017. Composite Magnetic Nanoparticles (CuFe2O4) as a New Microsorbent for Extraction of Rhodamine B from Water Samples. Journal of AOAC International, 100: 1539-1543.
25. Sadeghi M, Shiri F, Kordestani D, Mohammadi P, Alizadeh A, 2018. SBA‑15/Metformin as a novel sorbent combined with surfactant‑assisted dispersive liquid–liquid microextraction (SA‑DLLME) for highly sensitive determination of Pb, Cd and Ni in food and environmental samples. Journal of Iranian Chemical Society, 15: 753–768.
26. Soylak M, Unsal YE, Yilmaz E, Tuzen M, 2011. Determination of rhodamine B in soft drink, waste water and lipstick samples after solid phase extraction. Food and Chemical Toxicology, 49: 1796–1799.
27. Su X, Li X, Li J, Liu M, Lei F, Tan X, Li P, Luo W, 2015. Synthesis and characterization of core–shell magnetic molecularly imprinted polymers for solid-phase extraction and determination of Rhodamine B in food. Food Chemistry, 171: 292-297.
28. Sun D, Yang X, 2017. Rapid Determination of Toxic Rhodamine B in Food Samples Using Exfoliated Graphene-Modified Electrode. Food Analytical Methods, 10: 2046-2052.
29. Tatebe C, Zhong X, Ohtsuki T, Kubota H, Sato K, Akiyama H, 2014. A simple and rapid chromatographic method to determine unauthorized basic colorants (rhodamine B, auramine O, and pararosaniline) in processed foods. Food Science and Nutrition, 2: 547–556.
30. Unsal YE, Soylak M, Tuzen M, 2014a. Dispersive liquid–liquid microextraction–spectrophotometry combination for determination of rhodamine B in food, water, and environmental samples. Desalination and Water Treatment, 55: 2103-2108.
31. Unsal YE, Soylak M, Tuzen M, 2014b. Spectrophotometric Detection of Rhodamine B after Separation-Enrichment by Using Multi-walled Carbon Nanotubes. Journal of AOAC International, 97: 1459-1462.
32. Wang W, Du Y, Xiao Z, Li Y, Li B, Yang G, 2017. Determination of Trace Rhodamine B in Chili Oil by Deep Eutectic Solvent Extraction and an Ultra High-Performance Liquid Chromatograph Equipped with a Fluorescence Detector. Analytical Science, 33: 715-717.
33. Xiao N, Deng J, Huang K, Ju S, Hu C, Liang J, 2014. Application of derivative and derivative ratio spectrophotometry to simultaneous trace determination of rhodamine B and Rhodamine 6G after dispersive liquid–liquid microextraction. Spectrochimica Acta A, 128: 312–318.
34. Xu X, Zhang M, Wang L, Zhang S, Liu M, Long N, Qi X, Cui Z, Zhang L, 2016. Determination of Rhodamine B in Food Using Ionic Liquid–Coated Multiwalled Carbon Nanotube–Based Ultrasound-Assisted Dispersive Solid-Phase Microextraction Followed by High-Performance Liquid Chromatography. Food Analytical Methods, 9: 1696-1705.
35. Yan J, Cen JM, Tan XC, Tan SF, Wu YY, Zhang H, Wang Q, 2017. Determination of trace rhodamine B by spectrofluorometry and magnetic solid phase extraction based on a 3D reduced graphene oxide composite. Analytical Methods, 9: 5433–5440.
36. Yilmaz E, Soylak M, 2018. A novel and simple deep eutectic solvent based liquid phase microextraction method for rhodamine B in cosmetic products and water samples prior to its spectrophotometric determination. Spectrochimica Acta A, 202: 81-86.