UV ile Işınlanmış Seryum Katkılı Sr3Y2(BO3)4 Fosforunun Termolüminesans Cevabı
Yıl 2019,
Cilt: 9 Sayı: 1, 169 - 176, 01.03.2019
Sibel Uysal Satılmış
Arzu Ege
Öz
Bu çalışmada UV radyasyonu ile ışınlanmış seryum nadir toprak iyonu katkılı stronsiyum itriyum borat (Sr3Y2(BO3)4:Ce) fosforunun termolüminesans özellikleri incelenmiştir. Sr3Y2(BO3)4:Ce fosforu katı-hal reaksiyon metodu ile sentezlenmiş ve X-ışını kırınımı (XRD) ve termolüminesans (TL) teknikleri kullanılarak karakterize edilmiştir. Termolüminesans ölçümleri 254, 302 ve 365 nm dalga boyuna sahip UV radyasyonu ile ışınlanmış fosfor için gerçekleştirilmiştir. Doz cevabı ve sönümleme özellikleri, 254 nm dalga boyuna sahip UV radyasyonu ile ışınlanmış Sr3Y2(BO3)4: Ce fosforu için araştırılmıştır. Şu anki bilgimize göre bu fosforun termolüminesans özellikleri üzerine herhangi bir çalışma bulunmamaktadır.
Kaynakça
- Chang CK, Chen TM, 2007. Sr3B2O6:Ce3+, Eu2+: A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes. Applied Physics Letters, 91 (8): 081902.
- Kafadar VE, Yazıcı AN, Yıldırım RG, 2009. Determination of trapping parameters of dosimetric thermoluminescent glow peak of lithium triborate (LiB3O5) activated by aluminum. Journal of Luminescence, 129 (7): 710–714.
- Kim CH, Kwon IE, Park CH, Hwang YJ, Bae HS, Yu BY, Pyun CH, Hong G Y, 2000. Phosphors for plasma display panels. Journal of Alloys and Compounds, 311 (1): 33-39.
- Kuo TW, Chen TM, 2010. Synthesis and luminescence properties of Eu3+, Ce3+ and Tb3+-activated Sr3La2(BO3)4 under UV excitation. Journal of Luminescence, 130 (3): 483–487.
- Kwon KH, Im WB, Jang HS, Yoo HS, Jeon DY, 2009. Luminescence properties and energy transfer of site-sensitive Ca6−x−yMgx−z(PO4)4:Euy2+, Mnz2+ phosphors and their application to near-UV led-based white LEDs. Inorganıc Chemistry, 48 (24): 11525–11532.
- Li K, Chen DQ, Zhang R, Yu YL, Xu J, Wang YS, 2013. Enhanced luminescence in Ce3+/Dy3+: Sr3Y2(BO3)4 phosphors via energy transfer. Materials Research Bulletin, 48 (5): 1957-1960.
- Qi XD, Liu CM, Kuo CC, 2010. Pr doped LaTiNbO6 as a single phosphor for white LEDs. Journal of Alloys and Compounds, 492 (1-2): L61–L63.
- Rao BV, Jang K, Lee HS, Yi SS, Jeong JH, 2010. Synthesis and photoluminescence characterization of RE3+ (=Eu3+, Dy3+)-activated Ca3La(VO4)3 phosphors for white light-emitting diodes. Journal of Alloys and Compounds, 496 (1-2): 251–255.
- Rui Z and Xiang W, 2011. Preparation and luminescent characteristics of Sr3RE2(BO3)4:Dy3+ (RE = Y, La, Gd) phosphors for white LED. Journal of Alloys and Compounds, 509 (4): 1197–1200.
- Shyichuk AA, Lis S, 2011. Photoluminescence properties of nanosized strontium-yttrium boratephosphor Sr3Y2(BO3)4:Eu3+ obtained by the sol-gel Pechini method. Journal of Rare Earths, 29 (12): 1161-1165.
- Song EH, Zhao WR, Zhang W, Ming HC, Yi YC, Zhou MK, 2010. Fluorescence emission spectrum and energy transfer in Eu and Mn co-doped Ba2Ca(BO3)2 phosphors. Journal of Luminescence, 130 (12): 2495-2499.
- Wang Q, Deng DG, Hua YJ, Huang LH, Wang HP, Zhao SL, Jia GH, Li CX, Xu SQ, 2012. Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes. Journal of Luminescence, 132 (2): 434-438.
- Wei Q, Li XZ, Wang GJ, Song MJ, Wang ZJ, Wang GF, Long XF, 2008. Growth and spectroscopic properties of Ho3+ doped Sr3Y2(BO3)4 crystal Optical Materials, 30 (10): 1495-1498.
- Wei Q, Li XZ, Wang ZJ, Long XF, 2009. Growth and spectroscopic properties of Pr3+ doped Sr3Y2(BO3)4 crystal, Materials Research Innovations, 13 (1): 2-6.
- Wu X, Liang Y, Liu S, Zhu Y, Xu R, Tong M & Li, 2017. Investigation of the luminescence properties and thermal stability of dysprosium, terbium, and europium ions singly- and co-doped strontium yttrium borate phosphors. Spectroscopy Letters, 50 (1): 48–54.
- Ye S, Xiao F, Pan YX, Ma YY, Zhang QY, 2010. Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties. Materials Science and Engineering: R: Reports, 71 (1): 1-34.
- Zhang XM, Seo HJ, 2011. Thermally stable luminescence and energy transfer in Ce3+, Mn2+ doped Sr2Mg(BO3)2 phosphor. Optical Materials, 33 (11): 1704-1709.
- Zhang Y, Li Y, 2004. Red photoluminescence and crystal structure of Sr3Y2(BO3)4. Journal of Alloys and Compounds, 384 (1): 88–92.
- Zhang Y, Lin ZB, Hu ZS, Wang GF, 2004. Growth and spectroscopic properties of Nd3+-doped Sr3Y2 (BO3)4 crystal. Journal of Solid State Chemistry, 177 (9): 3183-3186.
- Zhang Y, Wang GF, 2010. Growth and optical properties of Yb3+ doped Sr3Y2(BO3)4 crystal. Materials Research Innovations. 14 (4): 277-279.
- Zhang Y, Lin Z, Wang, G, 2013. Synthesis, growth, structure and characterization of the new laser host crystal Sr3Y2(BO3)4. Laser Physics Letters. 10 (7): 075806 (7pp).
Thermoluminescence Response of UV Irradiated Cerium Doped Sr3Y2(BO3)4 Phosphor
Yıl 2019,
Cilt: 9 Sayı: 1, 169 - 176, 01.03.2019
Sibel Uysal Satılmış
Arzu Ege
Öz
The thermoluminescence (TL) properties of cerium rare earth ion doped strontium yttrium borate (Sr3Y2(BO3)4: Ce) phosphor irradiated with UV radiation were investigated in the present study. Sr3Y2(BO3)4: Ce phosphor was synthetized by the solid-state reaction method and characterized by using X-ray diffraction (XRD) and thermoluminescence techniques. Thermoluminescence measurements were carried out for the phosphor irradiated with UV radiation having 254, 302 and 365 nm wavelength. The dose response and fading properties were examined for the Sr3Y2(BO3)4: Ce phosphor irradiated with UV radiation having 254 nm wavelength. As far as we know there is no earlier work on thermoluminescence properties of these phosphors in literature.
Kaynakça
- Chang CK, Chen TM, 2007. Sr3B2O6:Ce3+, Eu2+: A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes. Applied Physics Letters, 91 (8): 081902.
- Kafadar VE, Yazıcı AN, Yıldırım RG, 2009. Determination of trapping parameters of dosimetric thermoluminescent glow peak of lithium triborate (LiB3O5) activated by aluminum. Journal of Luminescence, 129 (7): 710–714.
- Kim CH, Kwon IE, Park CH, Hwang YJ, Bae HS, Yu BY, Pyun CH, Hong G Y, 2000. Phosphors for plasma display panels. Journal of Alloys and Compounds, 311 (1): 33-39.
- Kuo TW, Chen TM, 2010. Synthesis and luminescence properties of Eu3+, Ce3+ and Tb3+-activated Sr3La2(BO3)4 under UV excitation. Journal of Luminescence, 130 (3): 483–487.
- Kwon KH, Im WB, Jang HS, Yoo HS, Jeon DY, 2009. Luminescence properties and energy transfer of site-sensitive Ca6−x−yMgx−z(PO4)4:Euy2+, Mnz2+ phosphors and their application to near-UV led-based white LEDs. Inorganıc Chemistry, 48 (24): 11525–11532.
- Li K, Chen DQ, Zhang R, Yu YL, Xu J, Wang YS, 2013. Enhanced luminescence in Ce3+/Dy3+: Sr3Y2(BO3)4 phosphors via energy transfer. Materials Research Bulletin, 48 (5): 1957-1960.
- Qi XD, Liu CM, Kuo CC, 2010. Pr doped LaTiNbO6 as a single phosphor for white LEDs. Journal of Alloys and Compounds, 492 (1-2): L61–L63.
- Rao BV, Jang K, Lee HS, Yi SS, Jeong JH, 2010. Synthesis and photoluminescence characterization of RE3+ (=Eu3+, Dy3+)-activated Ca3La(VO4)3 phosphors for white light-emitting diodes. Journal of Alloys and Compounds, 496 (1-2): 251–255.
- Rui Z and Xiang W, 2011. Preparation and luminescent characteristics of Sr3RE2(BO3)4:Dy3+ (RE = Y, La, Gd) phosphors for white LED. Journal of Alloys and Compounds, 509 (4): 1197–1200.
- Shyichuk AA, Lis S, 2011. Photoluminescence properties of nanosized strontium-yttrium boratephosphor Sr3Y2(BO3)4:Eu3+ obtained by the sol-gel Pechini method. Journal of Rare Earths, 29 (12): 1161-1165.
- Song EH, Zhao WR, Zhang W, Ming HC, Yi YC, Zhou MK, 2010. Fluorescence emission spectrum and energy transfer in Eu and Mn co-doped Ba2Ca(BO3)2 phosphors. Journal of Luminescence, 130 (12): 2495-2499.
- Wang Q, Deng DG, Hua YJ, Huang LH, Wang HP, Zhao SL, Jia GH, Li CX, Xu SQ, 2012. Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes. Journal of Luminescence, 132 (2): 434-438.
- Wei Q, Li XZ, Wang GJ, Song MJ, Wang ZJ, Wang GF, Long XF, 2008. Growth and spectroscopic properties of Ho3+ doped Sr3Y2(BO3)4 crystal Optical Materials, 30 (10): 1495-1498.
- Wei Q, Li XZ, Wang ZJ, Long XF, 2009. Growth and spectroscopic properties of Pr3+ doped Sr3Y2(BO3)4 crystal, Materials Research Innovations, 13 (1): 2-6.
- Wu X, Liang Y, Liu S, Zhu Y, Xu R, Tong M & Li, 2017. Investigation of the luminescence properties and thermal stability of dysprosium, terbium, and europium ions singly- and co-doped strontium yttrium borate phosphors. Spectroscopy Letters, 50 (1): 48–54.
- Ye S, Xiao F, Pan YX, Ma YY, Zhang QY, 2010. Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties. Materials Science and Engineering: R: Reports, 71 (1): 1-34.
- Zhang XM, Seo HJ, 2011. Thermally stable luminescence and energy transfer in Ce3+, Mn2+ doped Sr2Mg(BO3)2 phosphor. Optical Materials, 33 (11): 1704-1709.
- Zhang Y, Li Y, 2004. Red photoluminescence and crystal structure of Sr3Y2(BO3)4. Journal of Alloys and Compounds, 384 (1): 88–92.
- Zhang Y, Lin ZB, Hu ZS, Wang GF, 2004. Growth and spectroscopic properties of Nd3+-doped Sr3Y2 (BO3)4 crystal. Journal of Solid State Chemistry, 177 (9): 3183-3186.
- Zhang Y, Wang GF, 2010. Growth and optical properties of Yb3+ doped Sr3Y2(BO3)4 crystal. Materials Research Innovations. 14 (4): 277-279.
- Zhang Y, Lin Z, Wang, G, 2013. Synthesis, growth, structure and characterization of the new laser host crystal Sr3Y2(BO3)4. Laser Physics Letters. 10 (7): 075806 (7pp).