Yıl 2020, Cilt 10 , Sayı 1, Sayfalar 418 - 426 2020-03-01

A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions
A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions

Ömer GÜNGÖR [1]


The liquid-phase extraction performance of phthalonitrile (3 and 4) and isoindoline (5 and 6) substituted calix[4]aren derivatives was studied towards (i) some selected divalent heavy metal cations (i.e Co2+, Ni2+, Cu2+, Cd2+, Hg2+, and Pb2+), (ii) dichromate (Cr2O72-/HCr2O7-), and (iii) arsenate (H2AsO4−/HAsO42−). In general, extraction yield was observed to be higher in the case of compounds 3 and 5 (cone conformation) when compared to 4 and 6 (1,3-alternate conformation). This indicated a somehow positive effect of cone conformation on the extraction performance rather than 1,3-alternate conformation. The stoichiometric ratio between the compound 3 and 4 with mercury picrate was estimated through job’s plot analysis method.

The liquid-phase extraction performance of phthalonitrile (3 and 4) and isoindoline (5 and 6) substituted calix[4]aren derivatives was studied towards (i) some selected divalent heavy metal cations (i.e Co2+, Ni2+, Cu2+, Cd2+, Hg2+, and Pb2+), (ii) dichromate (Cr2O72-/HCr2O7-), and (iii) arsenate (H2AsO4−/HAsO42−). In general, extraction yield was observed to be higher in the case of compounds 3 and 5 (cone conformation) when compared to 4 and 6 (1,3-alternate conformation). This indicated a somehow positive effect of cone conformation on the extraction performance rather than 1,3-alternate conformation. The stoichiometric ratio between the compound 3 and 4 with mercury picrate was estimated through job’s plot analysis method.

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Birincil Dil en
Konular Mühendislik, Kimya
Yayımlanma Tarihi Mart-2020
Bölüm Kimya / Chemistry, Kimya Mühendisliği / Chemical Engineering
Yazarlar

Orcid: 0000-0002-3835-2920
Yazar: Ömer GÜNGÖR (Sorumlu Yazar)
Kurum: Kocaeli Üniversitesi
Ülke: Turkey


Tarihler

Başvuru Tarihi : 25 Ağustos 2019
Kabul Tarihi : 7 Kasım 2019
Yayımlanma Tarihi : 1 Mart 2020

Bibtex @araştırma makalesi { jist610489, journal = {Journal of the Institute of Science and Technology}, issn = {2146-0574}, eissn = {2536-4618}, address = {}, publisher = {Iğdır Üniversitesi}, year = {2020}, volume = {10}, pages = {418 - 426}, doi = {10.21597/jist.610489}, title = {A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions}, key = {cite}, author = {GÜNGÖR, Ömer} }
APA GÜNGÖR, Ö . (2020). A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions. Journal of the Institute of Science and Technology , 10 (1) , 418-426 . DOI: 10.21597/jist.610489
MLA GÜNGÖR, Ö . "A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions". Journal of the Institute of Science and Technology 10 (2020 ): 418-426 <https://dergipark.org.tr/tr/pub/jist/issue/52503/610489>
Chicago GÜNGÖR, Ö . "A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions". Journal of the Institute of Science and Technology 10 (2020 ): 418-426
RIS TY - JOUR T1 - A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions AU - Ömer GÜNGÖR Y1 - 2020 PY - 2020 N1 - doi: 10.21597/jist.610489 DO - 10.21597/jist.610489 T2 - Journal of the Institute of Science and Technology JF - Journal JO - JOR SP - 418 EP - 426 VL - 10 IS - 1 SN - 2146-0574-2536-4618 M3 - doi: 10.21597/jist.610489 UR - https://doi.org/10.21597/jist.610489 Y2 - 2019 ER -
EndNote %0 Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions %A Ömer GÜNGÖR %T A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions %D 2020 %J Journal of the Institute of Science and Technology %P 2146-0574-2536-4618 %V 10 %N 1 %R doi: 10.21597/jist.610489 %U 10.21597/jist.610489
ISNAD GÜNGÖR, Ömer . "A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions". Journal of the Institute of Science and Technology 10 / 1 (Mart 2020): 418-426 . https://doi.org/10.21597/jist.610489
AMA GÜNGÖR Ö . A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions. Iğdır Üniv. Fen Bil Enst. Der.. 2020; 10(1): 418-426.
Vancouver GÜNGÖR Ö . A Study on The Usability of Some Phthalonitrile and Diiminoisoindoline Substituted Calixarenes as Liquid-Phase Extraction Agents for Some Toxic Ions. Journal of the Institute of Science and Technology. 2020; 10(1): 426-418.