Maxilon Blue 5G Removal by Bimetallic Pt/Co Loaded on GO Material under Ultrasonic Conditions from Aquatic Medium

Yıl 2021, Cilt: 11 Sayı: 2, 1362 - 1373, 01.06.2021

Mehmet Harbi Çalımlı

https://doi.org/10.21597/jist.893416

Öz

Bimetallic Pt/Co loaded on GO adsorbance was produced following a series of simple hydrothermal methods. The produced bimetallic Pt/Co loaded GO material was used in the maxilon blue 5G removal (MB 5G) and investigated its adsorption studies. The adsorption studies on removal of MB 5G using the bimetallic Pt/Co loaded on GO material were carried out performing different experimental conditions like ultrasonic irradiation time (1-120 min), temperature (24-55 oC), initial MB 5G concentration (0.7.10-5- 1.5.10-5 M), and pH (4- 10) to detect optimum removal conditions. The reaction kinetics were investigated by pairing the so-called first-order pseudo-second-order and intraparticle diffusion in the adsorption process study. In addition, enthalpy, entropy and Gibbs free energy, and thermodynamic activation functions were investigated in order to understand the adsorption mechanism. These data showed that the bimetallic Pt/Co loaded on GO material can be used as an effective nano adsorbent for the removal of MB 5G as an organic pollutant in an aquatic medium.

Anahtar Kelimeler

Bimetallic, adsorption, removal, kinetic, Maxilon Blue 5G

Su Ortamından Ultrasonik Koşullar Altında GO Malzemesine Yüklenen Bimetalik Pt / Co ile Maxilon Blue 5G Kaldırma

Öz

Bimetalik Pt/Co’nin GO üzerine yüklenmiş adsorbent bir seri hidrotermal metod ile sentezlendi. Elde edilen adsorbance maxilon blue 5G (MB 5G)’inin giderilmesinde kullanıldı ve adsorbsiyon çalışmaları incelendi. MB 5G’inin Pt/Co yüklü GO material ile yapılan adsorbsiyon çalışmaları farklı deneysel durumlarda olan ultrasonic ışıma zamanı (1-120 min), sıcaklık (24-55 oC), başlangıç MB 5G konstrasyonu (0.7.10-5- 1.5.10-5 M), ve pH (4- 10) gibi deneysel koşullar altında yapıldı. Kinetik reaksiyonlar birinci dereceden, ikinci dereceden ve intrapartikül düfüzyonu metodları ile incelendi. Buna ilaveten, entalpi, entropi, Gibbs serbest enerjisi ve termodinamik aktivasyon fonksiyoları aktivasyon mekanizmasını tespit etmek için incelendi. Elde edilen sonuçlar ile bimetallik Pt/Co’nin GO üzerine yüklenmiş adsorbent MB 5G organik boyasının giderilmesinde etkin bir şekilde kullanılabileceği sonucuna varıldı.

Anahtar Kelimeler

Bimetalik, adsorpsiyon, uzaklaştırma, kinetik, Maxilon Blue 5G

Kaynakça

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