Effect of Efficiencies of Adding Silver Nanoparticles' to PEDOT:PSS in The Polymer Solar Cell

Yıl 2021, Cilt: 11 Sayı: 3, 2009 - 2015, 01.09.2021

Abuzer Yaman

https://doi.org/10.21597/jist.838826

Öz

In this study, silver (Ag) nanoparticles of different sizes (5 nm, 10 nm, 20 nm and 30 nm) were doped on Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), which is used as a hole conducting layer in polymer solar cells, and coated on Indium tin oxide (ITO) by Spin Coating method. PEDOT:PSS samples with and without additives were annealed at 110 °C, 130 °C and 150 °C. Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61 butyric acid methyl ester (PCBM) mixture were coated on PEDOT:PSS to produce polymer solar cells with ITO/PEDOT:PSS/P3HT:PCBM/Al structure and It was annealed at 110°C for 20 minutes. Currentvoltage (I-V) measurements of the produced samples were taken and their graphics were drawn. According to the data obtained from the calculations, it was determined that the highest photovoltaic efficiency of 2.59% was obtained by annealing at 130°C for the 5 nm Ag doped sample.

Anahtar Kelimeler

Polymer solar cells, organic, nanoparticles, spin coating method, efficiency

Proje Numarası

2013-FBE-D001

Polimer Güneş Hücrelerinde PEDOT:PSS’ye Gümüş Nanoparçacık Katkılamanın Verime Etkisi

Öz

Bu çalışmada, polimer güneş hücrelerinde boşluk ileten katman olarak kullanılan Poly(3,4-
ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS)’ye değişik boyutlardaki (5 nm, 10 nm, 20 nm ve 30 nm) gümüş (Ag) nanoparçacıkları katkılanarak ITO (Indium tin (kalay) oxide) üzerine Döndürerek Kaplama (Spin Coating) yöntemiyle kaplandı. Katkılı ve katkısız PEDOT:PSS numuneleri, 110 °C, 130 °C ve 150 °C sıcaklıklarında tavlandı. Daha sonra Poly(3-hexylthiophene) (P3HT) ve [6,6]-phenyl C61 butyric acid methyl ester (PCBM) karışımı PEDOT:PSS üzerine kaplanarak ITO/PEDOT:PSS/P3HT:PCBM/Al yapıdaki polimer güneş hücreleri üretildi ve 110°C sıcaklıkta 20 dakika süreyle tavlandı. Üretilen numunelerin akım-voltaj (I-V) ölçümleri alınarak grafikleri çizildi. Yapılan hesaplamalardan elde edilen verilere göre en yüksek fotovoltaik verim %2.59 ile 5 nm Ag katkılı numunenin 130°C’deki tavlama ile elde edildiği tespit edildi.

Anahtar Kelimeler

Polimer güneş hücreleri, organik, nanoparçacıklar, döndürerek kaplama yöntemi, verim

Destekleyen Kurum

Yüzüncü Yıl Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi

Proje Numarası

2013-FBE-D001

Kaynakça

• Camaioni N, Ridolfi G, Casalbore-Miceli G, Possamai G, Maggini M, 2002. The Effect of a Mild Thermal Treatment on the Performance of Poly(3‐alkylthiophene)/Fullerene Solar Cells. Advanced Materials, 14: 1735-1738.
• Coakley KM, McGehee MD, 2004. Conjugated polymer photovoltaic cells. Chemistry of Materials, 16: 4533–4542.
• Halls JJM, Walsh CA, Greenham NC, Marseglia EA, Friend RH, Moratti SC, Holmes AB, 1995. Efficient Photodiodes from Interpenetrating Polymer Networks. Nature, 376: 498-500.
• Horley P, Jimenez L, Garcia S, Quintana JA, Vorobiev YV, Bon RR, Makhniy VP, Hernandez JG, 2013. Thin Film Solar Cells: Modeling, Obtaining and Applications, 1th Edition, InTech.
• Kawano K, Ito N, Nishimori T, Sakai J, 2006. Open Circuit Voltage of Stacked Bulk Heterojunction Organic Solar Cells. Applied Physics Letters, 88: 073514.
• Kim H., Gilmore, C. M., Piqué, A., Horwitz, J. S., Mattoussi, H., Murata, H., Kafafi, Z. H., Chrisey, D. B., 1999. Electrical, Optical, and Structural Properties of Indium–Tin–Oxide Thin Films for Organic Light-Emitting Devices. Journal of Applied Physics, 86 (11), 6451-6461.
• Kim SH, Park BM, Kim GP, Yuh J, Chang YC, Chang HJ, 2014. Annealing effects of Au nanoparticles embedded PEDOT:PSS in bulkheterojunction organic solar cells. Synthetic Metals, 192: 101-105.
• Lawrence CJ, Zhou W, 1991. Spin Coating of Non-Newtonian Fluids. Journal of Non-Newtonian Fluid Mechanics, 39(2): 137-187.
• Li G, Shrotriya V, Yao Y, Yang YJ, 2005. Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene). Applied Physics, 98: 043704.
• Louwet F, Groenendaal L, Dhaen J, Manca J, Van Luppen J, Verdonck E, Leenders L, 2003. PEDOT/PSS: Synthesis, Characterization, Properties and Applications. Synthetic Metals, 135-136: 115.
• Padinger F, Rittberger RS, Sariciftci NS, 2003. Effects of Postproduction Treatment on Plastic Solar Cell. Advanced Functional Materials, 13: 85-88.
• Schraber MS, Sariciftci NS, 2013. Efficiency of Bulk Heterojunction Organic Solar Cells. Progress in Polymer Science, 38(12): 1929-1940.
• Thompson BC, Frechet JM, 2008. Polymer-Fullerene Composite Solar Cells. Angewandte Chemie, 47 58-77.
• Wright M, Uddin A, 2012. Organic-Inorganic Hybrid Solar Cell: A Comparative Review. Solar Energy Materials & Solar Cells, 107: 87-111.
• Yang X, Loos J, Veenstra SC, Verhees WJH, Wienk MM, Kroon JM, Michels MAJ, Janssen RAJ, 2005. Nanoscale Morphology of High-Performance Polymer Solar Cells. Nano Letters, 5: 579–583.
• Yu G, Heeger AJ, 1995. Charge Separation and Photovoltaic Emission Conversion in Polymer Composites with Internal Donor/Acceptor Heterojunctions. Journal of Applied Physics, 78: 4510.