Camsı Karbon Elektrot ve Nafyon-Grafenle Modifiye Edilmiş Camsı Karbon Elektrot Üzerinde Ethalfluralinin Voltametrik Tayini

Yıl 2021, Cilt: 11 Sayı: 3, 2112 - 2121, 01.09.2021

Berna Koçak

https://doi.org/10.21597/jist.846993

Öz

Bu çalışmada, dinitroanilin grubu bir herbisit olan ethalfluralinin(ETF), camsı karbon elektrot(CKE) ve nafyon-grafenle modifiye edilmiş camsı karbon elektrot(N-GR/CKE) üzerindeki elektrokimyasal davranışı dönüşümlü voltametri (DV) yöntemiyle araştırıldı. ETF'nin voltametrik tayini diferansiyel puls voltametrisi(DPV) yöntemiyle incelendi. ETF'nin DPV yöntemiyle pH 7 fosfat tamponunda 0 ile -1.5 V arasında CKE ile yapılan potansiyel taramasında -0.942V(1.pik akımı),-0.768V (2.pik akımı ); N-GR/CKE ile yapılan potansiyel taramasında ise -0.674 V(1.pik akımı ), -0.563 V (2.pik akımı) görüldü. ETF'nin CKE ve N-GR/CKE üzerindeki optimum deney şartları belirlendikten sonra, kalibrasyon doğrusu, çalışma aralığı, tayin edilebilme sınırı, gözlenebilme sınırı, gün içi ve günler arası tekrar edilebilirlikleri belirlendi. Bunun yanında N-GR/CKE üzerinde ETF’ye etki eden bazı katyonların (Cu2+, Ni2+, Co2+, Ca2+, Pb2+) girişim etkisi incelenmiştir. Elde edilen sonuçlar ETF'nin CKE ve NGR/CKE üzerinde gerçek numunelerde (toprak, su) uygulanabileceğini göstermektedir.

Anahtar Kelimeler

Ethalfluralin, Dinitroanilin, Herbisit, Nafyon-Grafen, Voltametri

Teşekkür

Prof.Dr.Hüseyin ÇELİKKAN'a vermiş olduğu katkılardan dolayı teşekkür ederim.

Voltammetric Determination of Ethalfularin on Glassy Carbon Electrode and Nafion-Graphene Modified Glassy Carbon Electrode

Öz

In this study, the electrochemical behavior of ethalfluraline (ETF), a dinitroaniline group herbicide, on glassy carbon electrode(CKE) and nafion-graphene modified glassy carbon electrode(N-GR /CKE) was investigated by cyclic voltammetry(CV). Voltammetric determination of ETF was examined by differential pulse voltammetry(DPV). Two peaks observed at -0.942V(1st peak current) and -0.768V(2nd peak current) during the potential scan of EFT by DPV method in pH 7 phosphate buffer solution between 0 and -1.5V on CKE and at -0.674 V(1st peak current) and -0.563 V(2nd peak current) during the potential scan on N-GR/CKE. After determining the optimum experimental conditions of ETF on CKE and N-GR /CKE, calibration line, working range, limit of detection(LOD), limit of quantification(LOQ), intra-day and inter-day repeatability were determined. In addition, the interference effect of some cations(Cu2+, Ni2+, Co2+, Ca2+, Pb2+) on N-GR/CKE was also investigated.The results show that EFT can be determined in real samples(water and soil) using CKE and N-GR/CKE.

Anahtar Kelimeler

Ethalfluralin, Dinitroaniline, Herbicide, Nafion-Graphene, Voltammetry

Kaynakça

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