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Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films

Yıl 2022, Cilt: 12 Sayı: 3, 1529 - 1538, 01.09.2022
https://doi.org/10.21597/jist.1091686

Öz

Co particles were electrodeposited at an electrode potential of -2.0 V on ITO/PPy (500 nm) substrates. During Co electrodeposition, charge density was changed from 400 to 5000 mC cm-2 in order to control the Co amount. Current density-time transients showed that the dominant reaction is PPy undoping for the initial times and Co deposition for the later times. Structural characterization was done by a Fourier transformed infrared (FTIR) spectrometer and a scanning electron microscope (SEM). FTIR spectra of the Co-PPy composite films have similar to that of the PPy film but peak intensities decrease as the charge density increases due to the surface covering by Co (by SEM). The chemical composition was detected by an energy dispersive spectrometer. For all films, C and N (belonging to PPy layer), O (due to oxidized character of PPy layer), F (doping anion) and Co peaks were obtained. Magnetic properties were measured by a vibrating sample magnetometer. Some films with Co charge density of 600, 700, 4000 and 5000 mC cm-2 have nearly isotropic magnetic behavior and the others are anisotropic. The isotropic behavior may arise from the very weak texture and preferred orientation of the films.

Destekleyen Kurum

Uludag University

Proje Numarası

UAP(F)-2010/56 and AYP (F)-2015/8

Kaynakça

  • Cao Y, Wang Q, Li G, Du J, Wu C, He J, 2013. Effects of high magnetic field on the structure evolution, magnetic and electrical properties of the molecular beam vapor deposited FexNi1-x (0.3<x<0.8) thin films. Journal of Magnetism and Magnetic Materials 332: 38–43.
  • Chipara M, Skomski R, Sellmyer DJ, 2007. Electrodeposition and magnetic properties of polypyrrole–Fe nanocomposites. Material Letters 61: 2412–2415.
  • Chowdhury AN, Islam MS, Azam MS, 2007. Polyaniline matrix containing nickel ferromagnet. Journal of Applied Polymer Science 103: 321–327.
  • Damian A, Omanovic S, 2006. Ni and Ni Mo hydrogen evolution electrocatalysts electrodeposited in a polyaniline matrix. Journal of Power Sources 158: 464–476.
  • Davidson RG, Turner TG, 1995. An IR spectroscopic study of the electrochemical reduction of polypyrrole doped with dodecylsulfate anion. Synthetic Metals 72: 121-128.
  • Garcia B, Lamzoudi A, Pillier F, Le HNT, Deslouis C, 2002. Oxide/polypyrrole composite films for corrosion protection of iron. Journal of Electrochemical Society 149: B560-B566.
  • Haciismailoglu M, 2015. Effects of the PPy layer thickness on Co–PPy composite films. Applied Surface Science 356: 817–826.
  • Haciismailoglu M, Haciismailoglu MC, Alper M,·Schwarzacher W, 2014. Electrodeposition and Characterization of Co Particles on Ultrathin Polypyrrole Films. Journal of Superconductivity and Novel Magnetism 27: 2599-2606.
  • Heinig NF, Kharbanda N, Pynenburg MR, Zhou XJ, Schultz GA, Leung KT, 2008. The growth of nickel nanoparticles on conductive polymer composite electrodes. Material Letters 62: 2285–2288.
  • Hepel M, Chen VM, Stephenson R, 1996. Effect of the composition of polypyrrole substrate on the electrodeposition of copper and nickel. Journal of Electrochemical Society143: 498-505.
  • Iannotti V, Ausanio G, Campana C, D’Orazio F, Hison C, Lucari F, Lanotte L, 2008. Magnetic anisotropy in Ni–Si nanoparticle films produced by ultrashort pulsed laser deposition. . Journal of Magnetism and Magnetic Materials 320: e594–e598.
  • Kato H, Nisbikawa O, Matsui T, Honma S, Kokados H, 1991. Fourier transform infrared spectroscopy study of conducting polymer polypyrrole: higher order structure of electrochemically synthesized film. Journal of Physical Chemistry 95: 6014-6016.
  • Kaur D, Chaudhary S, Pandya DK, Gupta R, Kotnala RK, 2013. Magnetization reversal studies in structurally tailored cobalt nanowires. . Journal of Magnetism and Magnetic Materials 344: 72–78.
  • Ko JM, Park DY, Myung NV, Chung JS, Nobe K, 2002. Electrodeposited conducting polymer–magnetic metal composite films. Synthetic Metals 128: 47–50.
  • Lee JY, Tan TC, 1990. Cyclic voltammetry of electrodeposition of metal on electrosynthesized polypyrrole film, . Journal of Electrochemical Society 137: 1402-1408.
  • Lei J, Liang W, Martin CR, 1992. Infrared investigations of pristine, doped and partially doped polypyrrole. Synthetic Metals 48: 301–312.
  • Liu YC, Hwang BJ, 1999. Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles. Thin Solid Films 339: 233-239.
  • Martins dos Santos LM, Lacroix JC, Chane-Ching KI, Adenier A, Abrantes LM, Lacaze PC, 2006. Electrochemical synthesis of polypyrrole films on copper electrodes in acidic and neutral aqueous media. Journal of Electroanalytical Chemistry 587: 67–78.
  • McNally E, Zhitomirsky I, Wilkinson D, 2005. Cathodic electrodeposition of cobalt oxide films using polyelectrolytes. Materials Chemistry and Physics 91: 391-398.
  • Orinakova R, Filkusova M, 2010. Hydrogen evolution on microstructured polypyrrole films modified with nickel. Synthetic Metals 160: 927–931.
  • Street GB, Clarke TC, Krounbi M, Kanazawa K, Lee V, Pfluger P, Scott JC, Weiser G, 1982. Preparation and characterization of neutral and oxidized polypyyrole films. Molecular Crystals and Liquid Crystals 83: 253-264.
  • Tian B, Zerbi G, 1990. Lattice dynamics and vibrational spectra of polypyrrole. Journal of Chemical Physics 92: 3886-3891.
  • Tian L, Qi Y, Wang B, 2009. Electrochemical preparation and structural characterization of platinum thin film on a polypyrrole film modified ITO electrode. Journal of Colloid Interface Science 333: 249–253.
  • Torsi L, Pezzuto M, Siciliano P, Rella R, Sabbatini L, Valli L, Zambonin PG, 1998. Conducting polymers doped with metallic inclusions: New materials for gas sensors. Sensors and Actuators B 48: 362–367.
  • Trung T, Trung TH, Ha CS, 2005. Preparation and cyclic voltammetry studies on nickel-nanoclusters containing polyaniline composites having layer-by-layer structures. Electrochimica Acta 51: 984–990.
  • Tsakova V, 2008. How to affect number, size, and location of metal particles deposited in conducting polymer layers. Journal of Solid State Electrochemistry 12: 1421–1434.
  • Vassar A, Roncali J, Garnier F, 1988. Preparation and electroactivity of poly(thiophene) electrodes modified by electrodeposition of palladium particles. Journal of Electroanalytical Chemistry 255: 53-69.
  • Vork FTA, Janssen LJJ, Barendrechi E, 1986. Oxidation of hydrogen at platinum-polypyrrole electrodes, Electrochimica Acta 31:1569 -1575.
  • Watanabe N, Morais J, Accione SBB, Morrone A, Schmidt JE, Martins Alves MC, 2004. Electronic, Structural, and Magnetic Properties of Cobalt Aggregates Embedded in Polypyrrole. Journal of Physical Chemistry B 108: 4013-4017.
  • Zolopa MW, Gradzka E, Szymanski K, Winkler K, 2013. Electrodeposition of nickel, cobalt, and iron on polypyrrole films, Thin Solid Films 548: 44–51.
Yıl 2022, Cilt: 12 Sayı: 3, 1529 - 1538, 01.09.2022
https://doi.org/10.21597/jist.1091686

Öz

Proje Numarası

UAP(F)-2010/56 and AYP (F)-2015/8

Kaynakça

  • Cao Y, Wang Q, Li G, Du J, Wu C, He J, 2013. Effects of high magnetic field on the structure evolution, magnetic and electrical properties of the molecular beam vapor deposited FexNi1-x (0.3<x<0.8) thin films. Journal of Magnetism and Magnetic Materials 332: 38–43.
  • Chipara M, Skomski R, Sellmyer DJ, 2007. Electrodeposition and magnetic properties of polypyrrole–Fe nanocomposites. Material Letters 61: 2412–2415.
  • Chowdhury AN, Islam MS, Azam MS, 2007. Polyaniline matrix containing nickel ferromagnet. Journal of Applied Polymer Science 103: 321–327.
  • Damian A, Omanovic S, 2006. Ni and Ni Mo hydrogen evolution electrocatalysts electrodeposited in a polyaniline matrix. Journal of Power Sources 158: 464–476.
  • Davidson RG, Turner TG, 1995. An IR spectroscopic study of the electrochemical reduction of polypyrrole doped with dodecylsulfate anion. Synthetic Metals 72: 121-128.
  • Garcia B, Lamzoudi A, Pillier F, Le HNT, Deslouis C, 2002. Oxide/polypyrrole composite films for corrosion protection of iron. Journal of Electrochemical Society 149: B560-B566.
  • Haciismailoglu M, 2015. Effects of the PPy layer thickness on Co–PPy composite films. Applied Surface Science 356: 817–826.
  • Haciismailoglu M, Haciismailoglu MC, Alper M,·Schwarzacher W, 2014. Electrodeposition and Characterization of Co Particles on Ultrathin Polypyrrole Films. Journal of Superconductivity and Novel Magnetism 27: 2599-2606.
  • Heinig NF, Kharbanda N, Pynenburg MR, Zhou XJ, Schultz GA, Leung KT, 2008. The growth of nickel nanoparticles on conductive polymer composite electrodes. Material Letters 62: 2285–2288.
  • Hepel M, Chen VM, Stephenson R, 1996. Effect of the composition of polypyrrole substrate on the electrodeposition of copper and nickel. Journal of Electrochemical Society143: 498-505.
  • Iannotti V, Ausanio G, Campana C, D’Orazio F, Hison C, Lucari F, Lanotte L, 2008. Magnetic anisotropy in Ni–Si nanoparticle films produced by ultrashort pulsed laser deposition. . Journal of Magnetism and Magnetic Materials 320: e594–e598.
  • Kato H, Nisbikawa O, Matsui T, Honma S, Kokados H, 1991. Fourier transform infrared spectroscopy study of conducting polymer polypyrrole: higher order structure of electrochemically synthesized film. Journal of Physical Chemistry 95: 6014-6016.
  • Kaur D, Chaudhary S, Pandya DK, Gupta R, Kotnala RK, 2013. Magnetization reversal studies in structurally tailored cobalt nanowires. . Journal of Magnetism and Magnetic Materials 344: 72–78.
  • Ko JM, Park DY, Myung NV, Chung JS, Nobe K, 2002. Electrodeposited conducting polymer–magnetic metal composite films. Synthetic Metals 128: 47–50.
  • Lee JY, Tan TC, 1990. Cyclic voltammetry of electrodeposition of metal on electrosynthesized polypyrrole film, . Journal of Electrochemical Society 137: 1402-1408.
  • Lei J, Liang W, Martin CR, 1992. Infrared investigations of pristine, doped and partially doped polypyrrole. Synthetic Metals 48: 301–312.
  • Liu YC, Hwang BJ, 1999. Interaction of copper(I)-polypyrrole complexes prepared by depositing-dissolving copper onto and from polypyrroles. Thin Solid Films 339: 233-239.
  • Martins dos Santos LM, Lacroix JC, Chane-Ching KI, Adenier A, Abrantes LM, Lacaze PC, 2006. Electrochemical synthesis of polypyrrole films on copper electrodes in acidic and neutral aqueous media. Journal of Electroanalytical Chemistry 587: 67–78.
  • McNally E, Zhitomirsky I, Wilkinson D, 2005. Cathodic electrodeposition of cobalt oxide films using polyelectrolytes. Materials Chemistry and Physics 91: 391-398.
  • Orinakova R, Filkusova M, 2010. Hydrogen evolution on microstructured polypyrrole films modified with nickel. Synthetic Metals 160: 927–931.
  • Street GB, Clarke TC, Krounbi M, Kanazawa K, Lee V, Pfluger P, Scott JC, Weiser G, 1982. Preparation and characterization of neutral and oxidized polypyyrole films. Molecular Crystals and Liquid Crystals 83: 253-264.
  • Tian B, Zerbi G, 1990. Lattice dynamics and vibrational spectra of polypyrrole. Journal of Chemical Physics 92: 3886-3891.
  • Tian L, Qi Y, Wang B, 2009. Electrochemical preparation and structural characterization of platinum thin film on a polypyrrole film modified ITO electrode. Journal of Colloid Interface Science 333: 249–253.
  • Torsi L, Pezzuto M, Siciliano P, Rella R, Sabbatini L, Valli L, Zambonin PG, 1998. Conducting polymers doped with metallic inclusions: New materials for gas sensors. Sensors and Actuators B 48: 362–367.
  • Trung T, Trung TH, Ha CS, 2005. Preparation and cyclic voltammetry studies on nickel-nanoclusters containing polyaniline composites having layer-by-layer structures. Electrochimica Acta 51: 984–990.
  • Tsakova V, 2008. How to affect number, size, and location of metal particles deposited in conducting polymer layers. Journal of Solid State Electrochemistry 12: 1421–1434.
  • Vassar A, Roncali J, Garnier F, 1988. Preparation and electroactivity of poly(thiophene) electrodes modified by electrodeposition of palladium particles. Journal of Electroanalytical Chemistry 255: 53-69.
  • Vork FTA, Janssen LJJ, Barendrechi E, 1986. Oxidation of hydrogen at platinum-polypyrrole electrodes, Electrochimica Acta 31:1569 -1575.
  • Watanabe N, Morais J, Accione SBB, Morrone A, Schmidt JE, Martins Alves MC, 2004. Electronic, Structural, and Magnetic Properties of Cobalt Aggregates Embedded in Polypyrrole. Journal of Physical Chemistry B 108: 4013-4017.
  • Zolopa MW, Gradzka E, Szymanski K, Winkler K, 2013. Electrodeposition of nickel, cobalt, and iron on polypyrrole films, Thin Solid Films 548: 44–51.
Toplam 30 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Metroloji,Uygulamalı ve Endüstriyel Fizik
Bölüm Fizik / Physics
Yazarlar

Mürşide Hacıismailoğlu 0000-0001-5648-3230

Proje Numarası UAP(F)-2010/56 and AYP (F)-2015/8
Erken Görünüm Tarihi 26 Ağustos 2022
Yayımlanma Tarihi 1 Eylül 2022
Gönderilme Tarihi 22 Mart 2022
Kabul Tarihi 15 Haziran 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 12 Sayı: 3

Kaynak Göster

APA Hacıismailoğlu, M. (2022). Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films. Journal of the Institute of Science and Technology, 12(3), 1529-1538. https://doi.org/10.21597/jist.1091686
AMA Hacıismailoğlu M. Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films. Iğdır Üniv. Fen Bil Enst. Der. Eylül 2022;12(3):1529-1538. doi:10.21597/jist.1091686
Chicago Hacıismailoğlu, Mürşide. “Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films”. Journal of the Institute of Science and Technology 12, sy. 3 (Eylül 2022): 1529-38. https://doi.org/10.21597/jist.1091686.
EndNote Hacıismailoğlu M (01 Eylül 2022) Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films. Journal of the Institute of Science and Technology 12 3 1529–1538.
IEEE M. Hacıismailoğlu, “Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films”, Iğdır Üniv. Fen Bil Enst. Der., c. 12, sy. 3, ss. 1529–1538, 2022, doi: 10.21597/jist.1091686.
ISNAD Hacıismailoğlu, Mürşide. “Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films”. Journal of the Institute of Science and Technology 12/3 (Eylül 2022), 1529-1538. https://doi.org/10.21597/jist.1091686.
JAMA Hacıismailoğlu M. Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films. Iğdır Üniv. Fen Bil Enst. Der. 2022;12:1529–1538.
MLA Hacıismailoğlu, Mürşide. “Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films”. Journal of the Institute of Science and Technology, c. 12, sy. 3, 2022, ss. 1529-38, doi:10.21597/jist.1091686.
Vancouver Hacıismailoğlu M. Structural and Magnetic Properties of Electrodeposited Cobalt-Polypyrrole Composite Films. Iğdır Üniv. Fen Bil Enst. Der. 2022;12(3):1529-38.