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Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries

Yıl 2013, Cilt: 3 Sayı: 4, 53 - 69, 31.12.2013

Öz









The main goals of water treatment at adequate quantity and quality are to improve the living con-
ditions, reduce poverty among the people and to ensure human and economic development. This paper presents
a report on removal of lead using a household waste (spent batteries). Spent batteries were collected, sectioned;
carbon rods (cathode) were removed washed with distilled water and characterized. Carbon rods were ground into
powder and sieved into different particle sizes. Properties of the powdered carbon rods (
PCR) were studied. Ad-
sorption properties of PCR were studied using synthetic lead solutions, typical raw water and domestic institutional
wastewater with a particular attention to its equilibrium isotherms.


The study revealed that PCR has pores, it adsorbed Pb2+ from aqueous solutions (synthetic lead solution, raw water
and domestic institutional wastewater). Equilibrium isotherms for Pb
2+ adsorption from aqueous solutions can be
grouped into two based on the values of correlation coef cient (
R2) as follows: equilibrium isotherms with R2> 0.95
(Langmuir, Freundlich, Sips, Langmuir- Freundlich, Crombie-Quilty and McLoughin,Temkin
,Koble- Corrigan,
Fritz and Schlunder models) and R
2< 0.95 (Hasley and Redlich- Peterson). Applicability of the process to lead ion
removal from aqueous solutions showed that
PCR can be used as an adsorbent for Pb2+ ions removal from aqueous
solutions.


It was concluded that PCR is a good adsorbent for Pb2+ ions removal from aqueous solutions.





Kaynakça

  • Adie, D.B., Olarinoye, N.O., Oke, I.A., Ismail, A., Otun, J.A., 2010. Removal of lead ions from aqueous solutions using powdered corn cobs. Canadian Journal of Chemical Engineering, 88, 241-255.
  • Aksu, Z., 2002. Determination of the equilibrium, kinetic and ther- modynamic parameters of the batch biosorption of nickel(II) ions onto Chlorella vulgaris, Process Biochem, 38, 89-99.
  • Almeida, M.F., Xará, S.M., Delgado, J., Costa, C.A. 2009. Labo- ratory study on the behaviour of spent AA household alkaline batteries in incineration .Waste Management, 29, 342-349.
  • APHA, 1998.“Standard method for the examination of water and wastewater”, 20th edn, America Water Works Association and Water Pollution Control Federation, Washington DC.
  • Esmaili, A., Nasseri, S., Mahvi, A.H., Atash-Dehghan, R., 2005. “Adsorption of lead and zinc ions from aqueous solutions by volcanic ash soil (VAS)”.Iran. J. Environ. Health. Sci. Eng., 2(4), 159-168.
  • Ho, Y.S., 2006. Isotherms for the sorption of lead onto peat: com- parison of linear and non-linear methods. Polish Journal of Environmental Studies, 15(1), 81-86.
  • Ho, Y.S., 2007. “Bibliometric analysis of adsorption technology in environmental science”. J. of Environmental Protection Sci- ence, 1,1-11.
  • Ho, Y.S., McKay, G., 1998a. “A comparison of chemisorption kinet- ic models applied to pollutant removal on various sorbents”, Process. Saf. Environ. Protect, 76 (B4), 332-340.
  • Ho, Y.S., McKay, G., 1998b. “ Kinetic model for lead (II) sorption onto peat”, Adsorpt. Sci. Technol. 16 (4), 243-255.
  • Hwang, K.S., Seong, Y.G., Won, K.L., 1991. Adsorption equilibria for hydrogen and carbon dioxide on activated carbon at high pressure up to 30 atm. Korean J. of Chem. Eng., 8(3),148-155.
  • Ismail, A., Adie, D.B., Oke, I.A., Otun, J.A., Olarinoye, N.O., Luk- man, S., Okuofu, C.A., 2009. Adsorption kinetics of cadmium ions onto powdered corn cobs. Canadian Journal of Chemical Engineering, 87; 896-906.
  • Khashimova, D., Keil. F.J., Kholmatov, K., 2008. “Alkanes in zeo- lites - molecular simulations, Empirical isotherms, mixtures”. J.l of the Uni. of Chem. Tech. and Metallurgy, 43(3), 335-344.
  • Kim, S.J., Wang G.S., Tae, Y.K., Hee, M., Seung, J.K., Sung, Y.C., 2002. Adsorption equilibrium characteristics of 2, 4-dichloro- phenoxyacetic acid and 2, 4-dinitrophenol on granular activat- ed carbons. Korean J. Chem. Eng., 19(6): 967-977..
  • Kobya, M., 2002. “Adsorption, kinetic and equilibrium studies of Cr(VI) by hazelnut shell activated carbon”. Adsorp. Sci. Tech- nol. 22, 51-64. (2004)
  • LiYH,WangSG,WeiJQ,ZhangXF,XuCL,LuanZK,WuDH,- Wei B Q,. Lead adsorption on carbon nanotubes. The Journal of Chemical Physics Letters, 35; 263-266.
  • Mamdouth, N.N., Kamar, T.E., Ebrahiem, E.E., Yehia, H.M., Man- sour, H.M., 2004. “Adsorption of iron and manganese ions us- ing low cost materials as adsorbents”, Adsorp. Sci. and Tech., 22(1), 25-37.
  • Moon, J.K., Keum, D.K., Lee, W.K., 1989. “Adsorption equilibria form-cresol, quinoline, and 1-naphthol onto silica gel.” Kore- an J. Chem. Eng., 6, 172-178.
  • Myers, A.L., Prausnitz, J.M., 1965. Thermodynamics of mixed gas adsorption. AlChE Journal. 11: 121-126.
  • Nameni, M., Alavi, M.R., Moghadam, M.A., 2008. “ Adsorption of hexavalent chromium from aqueous solutions by wheat bran”. Int. J. Environ. Sci. Tech., 5(2); 161-168.
  • Oke, I.A., Oladepo, K.T., Olarinoye, N.O., Igboro, S.B., Fehinto- la E.O., Fasuyi- Enang, O.T., 2011. Removal of pb2+ from aqueous solutions using a common household waste (used batteries): equilibrium isotherms models. A paper presented at the 2nd International Conference of the Faculty of Technol- ogy, ObafemiAwolowo University, Ile-Ife held on 25th -29th September 2011 (OAUTEKCONF 2011) at OAU Conference Centre.
  • Oke, I.A., 2007. “Development and performance- testing of an electrochemical process for selected industrial wastewaters”. Unpublished PhD. Thesis, (Civil Engineering Department), ObafemiAwolowo University, Ile-Ife.
  • Oke, I.A., Umoru, L.E., Ogedengbe, M.O., 2007a. Properties and stability of a carbon-resin electrode. Journal of Materials and Design. 28(7); 2251-2254.
  • Oke, I.A., Adie, D.B., Asaniand, M.A., Olarinoye, N.O., 2010. En- vironmental pollution control through proper solid waste man- agement: In Solid Waste Management and Environmental Remediation. Editor: TimoFaerber and Johann Herzog. Nova Science Publishers, Inc. New York.
  • Oke, I.A., Olarinoye, N.O., Adewusi, S.R.A., 2008. “Adsorption kinetics for arsenic removal by untreated powdered eggshell from aqueous solutions”. J. of Adsorpt.Soc.. 14(1); 85-92.
  • Oke, I.A., Umoru, L.E., Ogedengbe, M.O., 2007b. 2k factorial ex- periments on factors that in uence stability of carbon resin electrodes. FUTAJEET, 5(2); 135-141.
  • Olarinoye, N.O., Lukman, S., Otun, J.A., Adie, D.B., Adesola, O.I., Igboro, S.B., Temilolaand, F.E.O., Ismail, A., 2011. Multi-component adsorption equilibria of Pb2+and Cd2+onto powdered corn cobs (PCC): In: Water Treatment Processes; Editor: Kostas Demadis., Nova Science Publishers, Inc, New York.
  • Otun, J.A., Oke, I.A., Olarinoye, N.O., Adie, D.B., Okuofu, C.A., 2006b. “Adsorption isotherms of Pb(II), Ni(II) and Cd (II) onto PES”. J.l of Applied Sciences, 6(11); 2368-2376.
  • Otun, J.A., Oke, I.A., Olarinoye, N.O., Adie, D.B., Okuofu, C.A., 2006a. “Factors that in uence adsorption using 2k factorial experiment”.J.l of Applied Sciences, 6(11); 2432- 2437.
  • Toth, J., 1983. “Application of toth’s equation to describe the sin- gle-solute adsorption from dilute solutions on solids, ” J. Col- loid Interface Sci., 94, 573-575.
  • Wu, Y., Wang, Y.H., Lee, H.H., 2006. Performance enhancement of spherical natural graphite by phenol resin in lithium ion batter- ies. Journal of Alloys and Compounds 426; 218-222.
  • Zand, A.D., Abduli, M.A., 2008. Current situation of used house- hold batteries in Iran and appropriate management policies. Waste Management.28, 2085-2090.

Atık Pilleri Kullanarak Sıvı Çözeltilerden Kaldırılan Pb2+nin Absorbsiyon Denklemi

Yıl 2013, Cilt: 3 Sayı: 4, 53 - 69, 31.12.2013

Öz





Yeterli miktar ve kalitede su temin etmenin amaçları, yaşam koşullarını geliştirmek, insanlar arasındaki
yoksulluğu (sefaleti) azaltmak, ve insanı ve ekonomik gelişimi garanti altına almaktır. Bu makale, evdeki atık
maddeleri (atık pilleri) kullanarak kurşunun giderimi ile ilgili bir rapor sunmaktadır. Kullanılmış piller toplanıldı,
bölümlere ayrıldı; katotlar, distile edilmiş suyla yıkandı ve özellikleri belirlendi. Karbon çubuklar, toz haline geti
-
rilip, farklı partikül büyüklüğe sahip eleklerden geçirilmiştir. Toz haline getirilmiş karbon çubuklarının (THGKÇ)
özellikleri araştırıldı. THGKÇ’nın denge izotermlerine olan ilgiden dolayı; sentetik kurşun çözeltisi, tipik ham su
ve yerli kurumsal atık kullanarak THGKÇ’nin absorbsiyon özellikleri incelendi.


Bu çalışmada, gözenekleri olan THGKÇ, sulu çözeltiden (sentetik kurşun çözeltisi, tipik ham su, ve yerli
kurumsal atık) Pb
2+ absorbe edildiği ortaya çıkmıştır. Sulu çözeltisindeki Pb2+ absorbsiyonu için korelasyon
katsayıları baz alınarak denge izotermleri iki gruba ayrılabilir. Bunlar, R
2> 0.95 (Langmuir, Freundlich, Sips,
Langmuir- Freundlich, Crombie-Quilty and McLoughin,Temkin
,Koble- Corrigan, Fritz and Schlunder models) ve
R
2< 0.95 (Hasley and Redlich- Peterson) şeklinde ifade edilebilir.


Bu çalışmada, sulu çözeltiden kurşun iyonunun giderimi (kaldırılması) ile ilgili bu prosesinin uygulanabilirliği,
THGKÇ’nin, sulu çözeltilerden Pb
2+ iyonlarının giderilmesini sağlayan bir absorbent olabileceğini göstermiştir. 





Kaynakça

  • Adie, D.B., Olarinoye, N.O., Oke, I.A., Ismail, A., Otun, J.A., 2010. Removal of lead ions from aqueous solutions using powdered corn cobs. Canadian Journal of Chemical Engineering, 88, 241-255.
  • Aksu, Z., 2002. Determination of the equilibrium, kinetic and ther- modynamic parameters of the batch biosorption of nickel(II) ions onto Chlorella vulgaris, Process Biochem, 38, 89-99.
  • Almeida, M.F., Xará, S.M., Delgado, J., Costa, C.A. 2009. Labo- ratory study on the behaviour of spent AA household alkaline batteries in incineration .Waste Management, 29, 342-349.
  • APHA, 1998.“Standard method for the examination of water and wastewater”, 20th edn, America Water Works Association and Water Pollution Control Federation, Washington DC.
  • Esmaili, A., Nasseri, S., Mahvi, A.H., Atash-Dehghan, R., 2005. “Adsorption of lead and zinc ions from aqueous solutions by volcanic ash soil (VAS)”.Iran. J. Environ. Health. Sci. Eng., 2(4), 159-168.
  • Ho, Y.S., 2006. Isotherms for the sorption of lead onto peat: com- parison of linear and non-linear methods. Polish Journal of Environmental Studies, 15(1), 81-86.
  • Ho, Y.S., 2007. “Bibliometric analysis of adsorption technology in environmental science”. J. of Environmental Protection Sci- ence, 1,1-11.
  • Ho, Y.S., McKay, G., 1998a. “A comparison of chemisorption kinet- ic models applied to pollutant removal on various sorbents”, Process. Saf. Environ. Protect, 76 (B4), 332-340.
  • Ho, Y.S., McKay, G., 1998b. “ Kinetic model for lead (II) sorption onto peat”, Adsorpt. Sci. Technol. 16 (4), 243-255.
  • Hwang, K.S., Seong, Y.G., Won, K.L., 1991. Adsorption equilibria for hydrogen and carbon dioxide on activated carbon at high pressure up to 30 atm. Korean J. of Chem. Eng., 8(3),148-155.
  • Ismail, A., Adie, D.B., Oke, I.A., Otun, J.A., Olarinoye, N.O., Luk- man, S., Okuofu, C.A., 2009. Adsorption kinetics of cadmium ions onto powdered corn cobs. Canadian Journal of Chemical Engineering, 87; 896-906.
  • Khashimova, D., Keil. F.J., Kholmatov, K., 2008. “Alkanes in zeo- lites - molecular simulations, Empirical isotherms, mixtures”. J.l of the Uni. of Chem. Tech. and Metallurgy, 43(3), 335-344.
  • Kim, S.J., Wang G.S., Tae, Y.K., Hee, M., Seung, J.K., Sung, Y.C., 2002. Adsorption equilibrium characteristics of 2, 4-dichloro- phenoxyacetic acid and 2, 4-dinitrophenol on granular activat- ed carbons. Korean J. Chem. Eng., 19(6): 967-977..
  • Kobya, M., 2002. “Adsorption, kinetic and equilibrium studies of Cr(VI) by hazelnut shell activated carbon”. Adsorp. Sci. Tech- nol. 22, 51-64. (2004)
  • LiYH,WangSG,WeiJQ,ZhangXF,XuCL,LuanZK,WuDH,- Wei B Q,. Lead adsorption on carbon nanotubes. The Journal of Chemical Physics Letters, 35; 263-266.
  • Mamdouth, N.N., Kamar, T.E., Ebrahiem, E.E., Yehia, H.M., Man- sour, H.M., 2004. “Adsorption of iron and manganese ions us- ing low cost materials as adsorbents”, Adsorp. Sci. and Tech., 22(1), 25-37.
  • Moon, J.K., Keum, D.K., Lee, W.K., 1989. “Adsorption equilibria form-cresol, quinoline, and 1-naphthol onto silica gel.” Kore- an J. Chem. Eng., 6, 172-178.
  • Myers, A.L., Prausnitz, J.M., 1965. Thermodynamics of mixed gas adsorption. AlChE Journal. 11: 121-126.
  • Nameni, M., Alavi, M.R., Moghadam, M.A., 2008. “ Adsorption of hexavalent chromium from aqueous solutions by wheat bran”. Int. J. Environ. Sci. Tech., 5(2); 161-168.
  • Oke, I.A., Oladepo, K.T., Olarinoye, N.O., Igboro, S.B., Fehinto- la E.O., Fasuyi- Enang, O.T., 2011. Removal of pb2+ from aqueous solutions using a common household waste (used batteries): equilibrium isotherms models. A paper presented at the 2nd International Conference of the Faculty of Technol- ogy, ObafemiAwolowo University, Ile-Ife held on 25th -29th September 2011 (OAUTEKCONF 2011) at OAU Conference Centre.
  • Oke, I.A., 2007. “Development and performance- testing of an electrochemical process for selected industrial wastewaters”. Unpublished PhD. Thesis, (Civil Engineering Department), ObafemiAwolowo University, Ile-Ife.
  • Oke, I.A., Umoru, L.E., Ogedengbe, M.O., 2007a. Properties and stability of a carbon-resin electrode. Journal of Materials and Design. 28(7); 2251-2254.
  • Oke, I.A., Adie, D.B., Asaniand, M.A., Olarinoye, N.O., 2010. En- vironmental pollution control through proper solid waste man- agement: In Solid Waste Management and Environmental Remediation. Editor: TimoFaerber and Johann Herzog. Nova Science Publishers, Inc. New York.
  • Oke, I.A., Olarinoye, N.O., Adewusi, S.R.A., 2008. “Adsorption kinetics for arsenic removal by untreated powdered eggshell from aqueous solutions”. J. of Adsorpt.Soc.. 14(1); 85-92.
  • Oke, I.A., Umoru, L.E., Ogedengbe, M.O., 2007b. 2k factorial ex- periments on factors that in uence stability of carbon resin electrodes. FUTAJEET, 5(2); 135-141.
  • Olarinoye, N.O., Lukman, S., Otun, J.A., Adie, D.B., Adesola, O.I., Igboro, S.B., Temilolaand, F.E.O., Ismail, A., 2011. Multi-component adsorption equilibria of Pb2+and Cd2+onto powdered corn cobs (PCC): In: Water Treatment Processes; Editor: Kostas Demadis., Nova Science Publishers, Inc, New York.
  • Otun, J.A., Oke, I.A., Olarinoye, N.O., Adie, D.B., Okuofu, C.A., 2006b. “Adsorption isotherms of Pb(II), Ni(II) and Cd (II) onto PES”. J.l of Applied Sciences, 6(11); 2368-2376.
  • Otun, J.A., Oke, I.A., Olarinoye, N.O., Adie, D.B., Okuofu, C.A., 2006a. “Factors that in uence adsorption using 2k factorial experiment”.J.l of Applied Sciences, 6(11); 2432- 2437.
  • Toth, J., 1983. “Application of toth’s equation to describe the sin- gle-solute adsorption from dilute solutions on solids, ” J. Col- loid Interface Sci., 94, 573-575.
  • Wu, Y., Wang, Y.H., Lee, H.H., 2006. Performance enhancement of spherical natural graphite by phenol resin in lithium ion batter- ies. Journal of Alloys and Compounds 426; 218-222.
  • Zand, A.D., Abduli, M.A., 2008. Current situation of used house- hold batteries in Iran and appropriate management policies. Waste Management.28, 2085-2090.
Toplam 31 adet kaynakça vardır.

Ayrıntılar

Bölüm İnşaat Mühendisliği / Civil Engineering
Yazarlar

Isaiah Adesola Oke

Yayımlanma Tarihi 31 Aralık 2013
Gönderilme Tarihi 26 Şubat 2013
Kabul Tarihi 27 Mayıs 2013
Yayımlandığı Sayı Yıl 2013 Cilt: 3 Sayı: 4

Kaynak Göster

APA Oke, I. A. (2013). Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries. Journal of the Institute of Science and Technology, 3(4), 53-69.
AMA Oke IA. Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries. Iğdır Üniv. Fen Bil Enst. Der. Aralık 2013;3(4):53-69.
Chicago Oke, Isaiah Adesola. “Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries”. Journal of the Institute of Science and Technology 3, sy. 4 (Aralık 2013): 53-69.
EndNote Oke IA (01 Aralık 2013) Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries. Journal of the Institute of Science and Technology 3 4 53–69.
IEEE I. A. Oke, “Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries”, Iğdır Üniv. Fen Bil Enst. Der., c. 3, sy. 4, ss. 53–69, 2013.
ISNAD Oke, Isaiah Adesola. “Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries”. Journal of the Institute of Science and Technology 3/4 (Aralık 2013), 53-69.
JAMA Oke IA. Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries. Iğdır Üniv. Fen Bil Enst. Der. 2013;3:53–69.
MLA Oke, Isaiah Adesola. “Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries”. Journal of the Institute of Science and Technology, c. 3, sy. 4, 2013, ss. 53-69.
Vancouver Oke IA. Adsorption Equilibrium of Pb2+ Removal from Aqueous Solutions Using Spent Batteries. Iğdır Üniv. Fen Bil Enst. Der. 2013;3(4):53-69.