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Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone

Yıl 2024, Cilt: 14 Sayı: 3, 1218 - 1227, 01.09.2024
https://doi.org/10.21597/jist.1490644

Öz

In this research, the efficiency of Midyat stone modified with sulphuric acid (H2SO4) in the removal of Methyl Orange (MO) from wastewater is evaluated. Various factors such as contact time, initial MO concentration, and adsorbent dosage were investigated to understand their influence on adsorption efficiency. The optimal conditions for MO removal were as follows: initial concentration 300 mg/L, contact time 70 min, adsorbent dosage 0.5 g. The surface properties of modified Midyat stone (MMS) were investigated using methods such as Fourier transform infrared spectroscopy (FT-IR) and Brunauer, Emmett, and Teller (BET). According to the findings, the isotherm data agreed with the Langmuir isotherm model, indicating both chemical sorption and irreversibility potential. The adsorption capacity of MO at 298, 308 and 318 K was calculated to be 50.02, 54.05 and 58.48 mg/g, respectively. In addition, adsorption kinetics data supported the pseudo-second-order (PSO) kinetic model for MO removal. The research identified MMS as a capable and adaptable substance for capturing MO ions from the aqueous environment due to its significant removal capacity, easy availability, and cost-effectiveness.

Kaynakça

  • Akpomie, K. G., Dawodu, F. A., & Adebowale, K. O. (2015). Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential. Alexandria Engineering Journal, 54(3), 757-767.
  • Altunkaynak, Y. (2022). Effectively removing Cu (II) and Ni (II) ions from aqueous solutions using chemically non-processed Midyat stone: equivalent, kinetic and thermodynamic studies. Journal of the Iranian Chemical Society, 19(8), 3357-3370.
  • Altunkaynak, Y. (2023). Using chemically unprocessed orange peel to effectively remove Hg (II) ions from aqueous solutions: equivalent, thermodynamic, and kinetic investigations. Sakarya University Journal of Science, 27(1), 189-203.
  • Altunkaynak, Y., & Canpolat, M. (2022). Ham Portakal Kabuğu ile Sulu Çözeltilerden Mangan (II) İyonlarının Uzaklaştırılması: Denge, Kinetik ve Termodinamik Çalışmalar. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 22(1), 45-56.
  • Altunkaynak, Y., Canpolat, M., & Aslan, M. (2023). Adsorption of lead (II) ions on kaolinite from aqueous solutions: isothermal, kinetic, and thermodynamic studies. Ionics, 29(10), 4311-4323.
  • Bakalár, T., Kaňuchová, M., Girová, A., Pavolová, H., Hromada, R., & Hajduová, Z. (2020). Characterization of Fe (III) adsorption onto zeolite and bentonite. International Journal of Environmental Research and Public Health, 17(16), 5718.
  • Canpolat, M. (2023). Removing Co (II) and Mn (II) ions effectively from aqueous solutions by means of chemically non‐processed Mardin stone waste: Equivalent, kinetic, and thermodynamic investigations. Environmental Progress & Sustainable Energy, 42(3), e14042.
  • Canpolat, M., & Topal, G. (2023). Synthesis, characterization of cross‐linked poly (ethylene glycol dimethacrylate‐methyl methacrylate‐N‐(1‐phenylethyl) acrylamide) copolymer and removal of copper (II), cobalt (II) ions from aqueous solutions via this copolymer. Environmental Progress & Sustainable Energy, 42(6), e14197.
  • Ekinci, S. (2023). Elimination of Methylene Blue from Aqueous Medium Using an Agricultural Waste Product of Crude Corn Silk (Stylus maydis) and Corn Silk Treated with Sulphuric Acid. ChemistrySelect, 8(18), e202300284.
  • Güzel, F., Sayğılı, H., Sayğılı, G. A., & Koyuncu, F. (2015). New low-cost nanoporous carbonaceous adsorbent developed from carob (Ceratonia siliqua) processing industry waste for the adsorption of anionic textile dye: Characterization, equilibrium and kinetic modeling. Journal of Molecular Liquids, 206, 244-255.
  • Hasanbeigi, A., & Price, L. (2015). A technical review of emerging technologies for energy and water efficiency and pollution reduction in the textile industry. Journal of Cleaner Production, 95, 30-44.
  • Iwuozor, K. O., Ighalo, J. O., Emenike, E. C., Ogunfowora, L. A., & Igwegbe, C. A. (2021). Adsorption of methyl orange: A review on adsorbent performance. Current Research in Green and Sustainable Chemistry, 4, 100179.
  • Kahvecioğlu, K., Teğin, İ., Yavuz, Ö., & Saka, C. (2023). Phosphorus and oxygen co-doped carbon particles based on almond shells with hydrothermal and microwave irradiation process for adsorption of lead (II) and cadmium (II). Environmental Science and Pollution Research, 30(13), 37946-37960.
  • Kara, I., Tunc, D., Sayin, F., & Akar, S. T. (2018). Study on the performance of metakaolin based geopolymer for Mn (II) and Co (II) removal. Applied clay science, 161, 184-193.
  • Kaushal, S., Kaur, N., Kaur, M., & Singh, P. P. (2020). Dual-Responsive Pectin/Graphene Oxide (Pc/GO) nano-composite as an efficient adsorbent for Cr (III) ions and photocatalyst for degradation of organic dyes in waste water. Journal of Photochemistry and Photobiology A: Chemistry, 403, 112841.
  • Lima, E. C., Hosseini-Bandegharaei, A., Moreno-Piraján, J. C., & Anastopoulos, I. (2019). A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption. Journal of molecular liquids, 273, 425-434.
  • Liu, Q., Li, Y., Chen, H., Lu, J., Yu, G., Möslang, M., & Zhou, Y. (2020). Superior adsorption capacity of functionalised straw adsorbent for dyes and heavy-metal ions. Journal of Hazardous Materials, 382, 121040.
  • Onat, E., & Ekinci, S. (2024). A new material fabricated by the combination of natural mineral perlite and graphene oxide: Synthesis, characterization, and methylene blue removal. Diamond and Related Materials, 110848.
  • Pandey, S., & Ramontja, J. (2016). Natural bentonite clay and its composites for dye removal: current state and future potential. American Journal of Chemistry and Applications, 3(2), 8-19.
  • Sayğılı, H., Güzel, F., & Önal, Y. (2015). Conversion of grape industrial processing waste to activated carbon sorbent and its performance in cationic and anionic dyes adsorption. Journal of Cleaner Production, 93, 84-93.
  • Tamjidi, S., Esmaeili, H., & Moghadas, B. K. (2019). Application of magnetic adsorbents for removal of heavy metals from wastewater: a review study. Materials Research Express, 6(10), 102004.
  • Teğin, İ., Batur, M. Ş., Yavuz, Ö., & Saka, C. (2023). Removal of Cu (II), Pb (II) and Cd (II) metal ions with modified clay composite: kinetics, isotherms and thermodynamics studies. International Journal of Environmental Science and Technology, 20(2), 1341-1356.
  • Tural, B., Ertaş, E., & Tural, S. (2016). Removal of phenolic pollutants from aqueous solutions by a simple magnetic separation. Desalination and water treatment, 57(54), 26153-26164.
  • Tural, B., Ertaş, E., Enez, B., Fincan, S. A., & Tural, S. (2017). Preparation and characterization of a novel magnetic biosorbent functionalized with biomass of Bacillus Subtilis: Kinetic and isotherm studies of biosorption processes in the removal of Methylene Blue. Journal of Environmental Chemical Engineering, 5(5), 4795-4802
  • Zhul-quarnain, A., Ogemdi, I. K., Modupe, I., Gold, E., & Chidubem, E. E. (2018). Adsorption of malachite green dye using orange peel. Journal of Biomaterials, 2(2), 10.
Yıl 2024, Cilt: 14 Sayı: 3, 1218 - 1227, 01.09.2024
https://doi.org/10.21597/jist.1490644

Öz

Kaynakça

  • Akpomie, K. G., Dawodu, F. A., & Adebowale, K. O. (2015). Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential. Alexandria Engineering Journal, 54(3), 757-767.
  • Altunkaynak, Y. (2022). Effectively removing Cu (II) and Ni (II) ions from aqueous solutions using chemically non-processed Midyat stone: equivalent, kinetic and thermodynamic studies. Journal of the Iranian Chemical Society, 19(8), 3357-3370.
  • Altunkaynak, Y. (2023). Using chemically unprocessed orange peel to effectively remove Hg (II) ions from aqueous solutions: equivalent, thermodynamic, and kinetic investigations. Sakarya University Journal of Science, 27(1), 189-203.
  • Altunkaynak, Y., & Canpolat, M. (2022). Ham Portakal Kabuğu ile Sulu Çözeltilerden Mangan (II) İyonlarının Uzaklaştırılması: Denge, Kinetik ve Termodinamik Çalışmalar. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 22(1), 45-56.
  • Altunkaynak, Y., Canpolat, M., & Aslan, M. (2023). Adsorption of lead (II) ions on kaolinite from aqueous solutions: isothermal, kinetic, and thermodynamic studies. Ionics, 29(10), 4311-4323.
  • Bakalár, T., Kaňuchová, M., Girová, A., Pavolová, H., Hromada, R., & Hajduová, Z. (2020). Characterization of Fe (III) adsorption onto zeolite and bentonite. International Journal of Environmental Research and Public Health, 17(16), 5718.
  • Canpolat, M. (2023). Removing Co (II) and Mn (II) ions effectively from aqueous solutions by means of chemically non‐processed Mardin stone waste: Equivalent, kinetic, and thermodynamic investigations. Environmental Progress & Sustainable Energy, 42(3), e14042.
  • Canpolat, M., & Topal, G. (2023). Synthesis, characterization of cross‐linked poly (ethylene glycol dimethacrylate‐methyl methacrylate‐N‐(1‐phenylethyl) acrylamide) copolymer and removal of copper (II), cobalt (II) ions from aqueous solutions via this copolymer. Environmental Progress & Sustainable Energy, 42(6), e14197.
  • Ekinci, S. (2023). Elimination of Methylene Blue from Aqueous Medium Using an Agricultural Waste Product of Crude Corn Silk (Stylus maydis) and Corn Silk Treated with Sulphuric Acid. ChemistrySelect, 8(18), e202300284.
  • Güzel, F., Sayğılı, H., Sayğılı, G. A., & Koyuncu, F. (2015). New low-cost nanoporous carbonaceous adsorbent developed from carob (Ceratonia siliqua) processing industry waste for the adsorption of anionic textile dye: Characterization, equilibrium and kinetic modeling. Journal of Molecular Liquids, 206, 244-255.
  • Hasanbeigi, A., & Price, L. (2015). A technical review of emerging technologies for energy and water efficiency and pollution reduction in the textile industry. Journal of Cleaner Production, 95, 30-44.
  • Iwuozor, K. O., Ighalo, J. O., Emenike, E. C., Ogunfowora, L. A., & Igwegbe, C. A. (2021). Adsorption of methyl orange: A review on adsorbent performance. Current Research in Green and Sustainable Chemistry, 4, 100179.
  • Kahvecioğlu, K., Teğin, İ., Yavuz, Ö., & Saka, C. (2023). Phosphorus and oxygen co-doped carbon particles based on almond shells with hydrothermal and microwave irradiation process for adsorption of lead (II) and cadmium (II). Environmental Science and Pollution Research, 30(13), 37946-37960.
  • Kara, I., Tunc, D., Sayin, F., & Akar, S. T. (2018). Study on the performance of metakaolin based geopolymer for Mn (II) and Co (II) removal. Applied clay science, 161, 184-193.
  • Kaushal, S., Kaur, N., Kaur, M., & Singh, P. P. (2020). Dual-Responsive Pectin/Graphene Oxide (Pc/GO) nano-composite as an efficient adsorbent for Cr (III) ions and photocatalyst for degradation of organic dyes in waste water. Journal of Photochemistry and Photobiology A: Chemistry, 403, 112841.
  • Lima, E. C., Hosseini-Bandegharaei, A., Moreno-Piraján, J. C., & Anastopoulos, I. (2019). A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption. Journal of molecular liquids, 273, 425-434.
  • Liu, Q., Li, Y., Chen, H., Lu, J., Yu, G., Möslang, M., & Zhou, Y. (2020). Superior adsorption capacity of functionalised straw adsorbent for dyes and heavy-metal ions. Journal of Hazardous Materials, 382, 121040.
  • Onat, E., & Ekinci, S. (2024). A new material fabricated by the combination of natural mineral perlite and graphene oxide: Synthesis, characterization, and methylene blue removal. Diamond and Related Materials, 110848.
  • Pandey, S., & Ramontja, J. (2016). Natural bentonite clay and its composites for dye removal: current state and future potential. American Journal of Chemistry and Applications, 3(2), 8-19.
  • Sayğılı, H., Güzel, F., & Önal, Y. (2015). Conversion of grape industrial processing waste to activated carbon sorbent and its performance in cationic and anionic dyes adsorption. Journal of Cleaner Production, 93, 84-93.
  • Tamjidi, S., Esmaeili, H., & Moghadas, B. K. (2019). Application of magnetic adsorbents for removal of heavy metals from wastewater: a review study. Materials Research Express, 6(10), 102004.
  • Teğin, İ., Batur, M. Ş., Yavuz, Ö., & Saka, C. (2023). Removal of Cu (II), Pb (II) and Cd (II) metal ions with modified clay composite: kinetics, isotherms and thermodynamics studies. International Journal of Environmental Science and Technology, 20(2), 1341-1356.
  • Tural, B., Ertaş, E., & Tural, S. (2016). Removal of phenolic pollutants from aqueous solutions by a simple magnetic separation. Desalination and water treatment, 57(54), 26153-26164.
  • Tural, B., Ertaş, E., Enez, B., Fincan, S. A., & Tural, S. (2017). Preparation and characterization of a novel magnetic biosorbent functionalized with biomass of Bacillus Subtilis: Kinetic and isotherm studies of biosorption processes in the removal of Methylene Blue. Journal of Environmental Chemical Engineering, 5(5), 4795-4802
  • Zhul-quarnain, A., Ogemdi, I. K., Modupe, I., Gold, E., & Chidubem, E. E. (2018). Adsorption of malachite green dye using orange peel. Journal of Biomaterials, 2(2), 10.
Toplam 25 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Separasyon Bilimi
Bölüm Kimya / Chemistry
Yazarlar

Mutlu Canpolat 0000-0002-3771-6737

Erken Görünüm Tarihi 27 Ağustos 2024
Yayımlanma Tarihi 1 Eylül 2024
Gönderilme Tarihi 27 Mayıs 2024
Kabul Tarihi 14 Haziran 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 14 Sayı: 3

Kaynak Göster

APA Canpolat, M. (2024). Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone. Journal of the Institute of Science and Technology, 14(3), 1218-1227. https://doi.org/10.21597/jist.1490644
AMA Canpolat M. Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone. Iğdır Üniv. Fen Bil Enst. Der. Eylül 2024;14(3):1218-1227. doi:10.21597/jist.1490644
Chicago Canpolat, Mutlu. “Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone”. Journal of the Institute of Science and Technology 14, sy. 3 (Eylül 2024): 1218-27. https://doi.org/10.21597/jist.1490644.
EndNote Canpolat M (01 Eylül 2024) Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone. Journal of the Institute of Science and Technology 14 3 1218–1227.
IEEE M. Canpolat, “Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone”, Iğdır Üniv. Fen Bil Enst. Der., c. 14, sy. 3, ss. 1218–1227, 2024, doi: 10.21597/jist.1490644.
ISNAD Canpolat, Mutlu. “Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone”. Journal of the Institute of Science and Technology 14/3 (Eylül 2024), 1218-1227. https://doi.org/10.21597/jist.1490644.
JAMA Canpolat M. Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone. Iğdır Üniv. Fen Bil Enst. Der. 2024;14:1218–1227.
MLA Canpolat, Mutlu. “Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone”. Journal of the Institute of Science and Technology, c. 14, sy. 3, 2024, ss. 1218-27, doi:10.21597/jist.1490644.
Vancouver Canpolat M. Effectively Removing Methyl Orange From Aqueous Solutions Using Sulphuric Acid Modified Midyat Stone. Iğdır Üniv. Fen Bil Enst. Der. 2024;14(3):1218-27.