Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights

Erk İnger

doi:10.53525/jster.1593599

TR EN

Sodyum borohidrit çözeltilerinden hidrojen üretimi için katalizör incelemesi ve Uzun süreli uzay uçuşlarında canlıların hayatta kalma yeteneği

Öz

Hidrojen (H2), borohidrürden (NaBH4) kolayca elde edilen, diğer hidratlardan daha güvenli olan ve çeşitli katalizörlerin kullanımını gerektiren daha yüksek hidrojen (H2) üretim hızlarına (HGR'ler) sahip, en avantajlı yanma yan ürünlerine sahip, çevre dostu, etkili bir enerji taşıyıcısıdır. Katalizörlerin performansları, hidroliz veya metanoliz reaksiyonlarından bağımsız olarak NaBH4'ten gelen yüksek HGR'de ana faktörlerdir. HGR, NaBH4 konsantrasyonlarından, reaksiyon sıcaklığından ve katalizör miktarlarından etkilenir. Rutenyum (Ru), platin (Pt), Rodyum (Rh) vb. gibi Nobel metallerinin, etanol, metanol ve etilen glikolü içeren NaBH4 çözeltilerinden hızlı H2 üretimi için oldukça etkili katalizörler olduğu rapor edilmiştir. Soy metallerin kıtlığı ve maliyet kaygıları nedeniyle, kobalt (Co), nikel (Ni) ve manganez (Mn) gibi geçiş metali bazlı katalizörler, NaBH4 hidrolizi/alkolizinden H2 üretimi için büyük ilgi kazanmıştır. Metal nanoparçacık bazlı katalizörler ve bunların sentetik ve doğal polimer kompozitlerinin yanı sıra mikro/nanojeller, toplu hidrojeller, kriyojeller ve polimerik iyonik sıvılar (PIL'ler) içeren metalik olmayan katalizörler, daha düşük değerlere ulaşmak için NaBH4'ün metanolizinde/hidrolizinde, düşük aktivasyon enerjisi, Ea ve yüksek HGR değerlileri katalizör olarak kullanılmıştır. Bu nedenle bu derlemede H2 üretim reaksiyonlarında kullanılan katalizörlerin metal veya metal olmayan olup olmadığı araştırılacak, ayrıca H2 enerji sistemlerinin uzay uygulamaları ve gelecekte kullanım için ticari uygulamaları değerlendirilecektir

Anahtar Kelimeler

enerji , hidrojel , hidrojen üretimi , hidrojen üretim hızı , aktivasyon enerjisi , sodium bor hidrur , yakıt pili

Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights

Abstract

Hydrogen (H2), environmentally friendly effective energy carrier with the most advantageous combustion by-products, readily attained from borohydride (NaBH4) with higher hydrogen (H2) generation rates (HGRs) as safer than e other hydrates necessitating the use of various catalysts. The catalysts' performances are major factors in high HGR from NaBH4 regardless of hydrolysis or methanolysis reactions. The HGR is influenced by NaBH4 concentrations, reaction temperature, and the catalyst amounts. Nobel metals e.g., ruthenium (Ru), platinum (Pt), Rhodium (Rh) etc reported as highly effective catalysts for fast H2 production from NaBH4 solutions including ethanol, methanol, and ethylene glycol. Due to shortage and cost considerations of noble metals, transition metal-based catalysts e.g., cobalt (Co), nickel (Ni), and manganese (Mn) have gained great interest for H2 production from NaBH4 hydrolysis/alcoholysis. Metal nanoparticle-based catalysts, and their synthetic and natural polymer composites along with non-metallic catalyst including micro/nanogels, bulk hydrogels, cryogels, and polymeric ionic liquids (PILs) have been employed as catalysts in methanolysis/hydrolysis of NaBH4 to attain lower Ea and high HGR values. Therefore, in this review catalysts whether metal or non-metal used in H2 generation reactions will be surveyed, Moreover, space application of H2 energy systems with their commercial application for future use will be assessed.

Keywords

hydrogel , metal organic frame , supporting material , energy , hydrogen generation. , sodium borohydride

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Elektrik Enerjisi Depolama , Enerji , Yenilenebilir Enerji Sistemleri , Hava-Uzay Ulaşımı

Bölüm

İnceleme Makalesi

Yazarlar

Erk İnger ^*
0000-0002-1857-8180
Türkiye

Yayımlanma Tarihi

21 Aralık 2024

Gönderilme Tarihi

29 Kasım 2024

Kabul Tarihi

16 Aralık 2024

Yayımlandığı Sayı

Yıl 2024 Cilt: 5 Sayı: 2

DOI

https://doi.org/10.53525/jster.1593599

IZ

https://izlik.org/JA88KD35FW

APA

İnger, E. (2024). Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights. Journal of Science, Technology and Engineering Research, 5(2), 199-222. https://doi.org/10.53525/jster.1593599

AMA

1.İnger E. Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights. Journal of Science, Technology and Engineering Research. 2024;5(2):199-222. doi:10.53525/jster.1593599

Chicago

İnger, Erk. 2024. “Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights”. Journal of Science, Technology and Engineering Research 5 (2): 199-222. https://doi.org/10.53525/jster.1593599.

EndNote

İnger E (01 Aralık 2024) Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights. Journal of Science, Technology and Engineering Research 5 2 199–222.

IEEE

[1]E. İnger, “Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights”, Journal of Science, Technology and Engineering Research, c. 5, sy 2, ss. 199–222, Ara. 2024, doi: 10.53525/jster.1593599.

ISNAD

İnger, Erk. “Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights”. Journal of Science, Technology and Engineering Research 5/2 (01 Aralık 2024): 199-222. https://doi.org/10.53525/jster.1593599.

JAMA

1.İnger E. Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights. Journal of Science, Technology and Engineering Research. 2024;5:199–222.

MLA

İnger, Erk. “Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights”. Journal of Science, Technology and Engineering Research, c. 5, sy 2, Aralık 2024, ss. 199-22, doi:10.53525/jster.1593599.

Vancouver

1.Erk İnger. Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights. Journal of Science, Technology and Engineering Research. 01 Aralık 2024;5(2):199-222. doi:10.53525/jster.1593599

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Hydrogen generation from sodium borohydride solutions using different catalysts for the survival of living beings in the long-time space flights

Abstract

Keywords

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

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