BibTex RIS Kaynak Göster

Yeni Mono-Lutesyum Iıı Ftalosiyaninlerin Sentezi, Karakterizasyonu ve Spektroskopik Özellikleri

Yıl 2016, Cilt: 6 Sayı: 2, 307 - 314, 01.06.2016

Mehmet Pişkin , Zafer Odabaş

Öz

Bu çalışmada çeşitli teknolojik uygulamalarda kullanılması amacıyla yeni, oldukça çözünür ve agregasyon yapmayan ftalosiyanin halkasına periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla tetrasübstitüe lutesyum III asetat metalli ftalosiyanin bileşikleri sentezlenmiş ve yapıları elemental analiz, FT-IR, 1H NMR, UV–vis spektroskopisi ve MALDI-TOF Kütle analiz metotları kullanılarak karakterize edilip aydınlatılmıştır. Ayrıca bu bileşiklerin periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla sübstitüe edilmesiyle spektroskopik özelliklerindeki değişiklikler rapor edilmiştir

Anahtar Kelimeler

Lutesyum III asetat Mono-lutesyum ftalosiyanin Agregasyon yapmayan Non-periferal Periferal Çözünür

Kaynakça

  • Simon, J., Andre, JJ. 1985. Photoelectrical Properties and Solar Cells In: Molecular Semiconductors. J.M. Lehn, Ch.W Rees [eds.], Springer-Verlag, Berlin, pp-73-147.
  • Leznoff, CC., Lever, AbP. 1989. Phthalocyanines, Properties and Applications Vol.1, Wiley–VCH, New York, pp-341–392.
  • Leznoff, CC., Lever, AbP. 1993. Phthalocyanines, Properties and Applications Vol.3, Wiley–VCH, New York, pp-119–167.
  • Leznoff, CC., Lever, AbP. 1996. Phthalocyanines, Properties and Applications Vol.4, Wiley–VCH, New York, pp-79–181.
  • Simon, J., bassoul, P. 2000. Design of Molecular Materials: Supramolecular Engineering, John Wiley & Sons, Chichester, pp 197-291.
  • Gould, RD. 1996. Structure and electrical conduction properties of phthalocyanine thin films. Coordın. Chem. Rev., 156: 237- 274.
  • Kudrevich, SV., Van Lier, JE. 1996. Azaanalogs of phthalocyanine: syntheses and properties. Coordın. Chem. Rev., 156:163-182.
  • Rosenthal, I. 1996. In: Phthalocyanines - Properties and Applications, Leznoff, C.C.; Lever, A.B.P. [eds.], Wiley VCH: New York, Vol. 4,; pp. 486-514.
  • buono-Core, GE., Li, H., Marciniak, b. 1990. Quenching of Excited States by Lanthanide Ions and Chelates in Solution. Coordın. Chem. Rev., 90: 55-87.
  • Wu, W.-N., Tang, N., Yan, LJ. 2008. Syntheses, Characterization and Fluorescent Properties of Six Novel Lanthanide Com- plexes with N,N-diphenyl-2-(quinolin-8-yloxy)acetamide. J. Fluoresc.,18:101-107.
  • Edward, A., Chu, TY., Claude, C., Sokolik, I., Okamoto, Y., Dorisinville, R. 1997. Synthesis and characterization of electroluminescent organo-lanthanide (III) complexes. Synth. Met., 84: 433-434.
  • Meares, CF.,Wense TG. 1984. Metal chelates as probes of biological systems. Acc. Chem. Res, 17: 202-209.
  • Kukhta, A., Kolesnik, E., Grabchev, IJ. 2006. Spectral and luminescent properties and electroluminescence of polyvinylcarbazole with 1,8-naphthalimide in the side chain. J.Fluoresc., 16:375-378.
  • Wu, Fb., Zhang C. 2002. A new europium beta-diketone chelate for ultrasensitive time-resolved fluorescence immunoassays, Anal Biochem, 311:57-67.
  • Nicholson, M., Leznoff, CC., Lever. AbP. 1993. The Redox Chemistry of Metallophthalocyanines in Solution. In: Leznoff, CC., Lever ABP [eds.], Phthalocyanines, Properties and Applications, Vol. 3, VCH, Publications, New York, pp.119–167.
  • Zugle, R., Litwinski, C., Nyokong, T. 2011. Photophysical char- acterization of dysprosium, erbium and lutetium phthalocya- nines tetrasubstituted with phenoxy groups at non-peripheral positions. Polyhedron, 30 (9):1612-1619.

Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines

Yıl 2016, Cilt: 6 Sayı: 2, 307 - 314, 01.06.2016

Mehmet Pişkin , Zafer Odabaş

Öz

In this study, the novel, highly soluble and non-aggregated peripherally /non-peripherally tetrakis-2,6-dimethoxyphenoxy substituted lutetium III acetate mono-phthalocyanine complexes have been synthesized for use in different technological applications in this study. The new phthalocyanine complexes have been characterized by elemental analysis, IR, 1H NMR, UV–vis spectroscopy and MALDI-TOF Mass spectra. The effects of the positions peripheral or non-peripheral of the substituents on the spectroscopic properties of 2,6-dimethoxyphenoxy substituted mono-lutetium III phthalocyanines have been also reported.

Anahtar Kelimeler

Mono-phthalocyanine lutetium III acetate soluble non-aggregated peripheral non-peripheral.

Kaynakça

  • Simon, J., Andre, JJ. 1985. Photoelectrical Properties and Solar Cells In: Molecular Semiconductors. J.M. Lehn, Ch.W Rees [eds.], Springer-Verlag, Berlin, pp-73-147.
  • Leznoff, CC., Lever, AbP. 1989. Phthalocyanines, Properties and Applications Vol.1, Wiley–VCH, New York, pp-341–392.
  • Leznoff, CC., Lever, AbP. 1993. Phthalocyanines, Properties and Applications Vol.3, Wiley–VCH, New York, pp-119–167.
  • Leznoff, CC., Lever, AbP. 1996. Phthalocyanines, Properties and Applications Vol.4, Wiley–VCH, New York, pp-79–181.
  • Simon, J., bassoul, P. 2000. Design of Molecular Materials: Supramolecular Engineering, John Wiley & Sons, Chichester, pp 197-291.
  • Gould, RD. 1996. Structure and electrical conduction properties of phthalocyanine thin films. Coordın. Chem. Rev., 156: 237- 274.
  • Kudrevich, SV., Van Lier, JE. 1996. Azaanalogs of phthalocyanine: syntheses and properties. Coordın. Chem. Rev., 156:163-182.
  • Rosenthal, I. 1996. In: Phthalocyanines - Properties and Applications, Leznoff, C.C.; Lever, A.B.P. [eds.], Wiley VCH: New York, Vol. 4,; pp. 486-514.
  • buono-Core, GE., Li, H., Marciniak, b. 1990. Quenching of Excited States by Lanthanide Ions and Chelates in Solution. Coordın. Chem. Rev., 90: 55-87.
  • Wu, W.-N., Tang, N., Yan, LJ. 2008. Syntheses, Characterization and Fluorescent Properties of Six Novel Lanthanide Com- plexes with N,N-diphenyl-2-(quinolin-8-yloxy)acetamide. J. Fluoresc.,18:101-107.
  • Edward, A., Chu, TY., Claude, C., Sokolik, I., Okamoto, Y., Dorisinville, R. 1997. Synthesis and characterization of electroluminescent organo-lanthanide (III) complexes. Synth. Met., 84: 433-434.
  • Meares, CF.,Wense TG. 1984. Metal chelates as probes of biological systems. Acc. Chem. Res, 17: 202-209.
  • Kukhta, A., Kolesnik, E., Grabchev, IJ. 2006. Spectral and luminescent properties and electroluminescence of polyvinylcarbazole with 1,8-naphthalimide in the side chain. J.Fluoresc., 16:375-378.
  • Wu, Fb., Zhang C. 2002. A new europium beta-diketone chelate for ultrasensitive time-resolved fluorescence immunoassays, Anal Biochem, 311:57-67.
  • Nicholson, M., Leznoff, CC., Lever. AbP. 1993. The Redox Chemistry of Metallophthalocyanines in Solution. In: Leznoff, CC., Lever ABP [eds.], Phthalocyanines, Properties and Applications, Vol. 3, VCH, Publications, New York, pp.119–167.
  • Zugle, R., Litwinski, C., Nyokong, T. 2011. Photophysical char- acterization of dysprosium, erbium and lutetium phthalocya- nines tetrasubstituted with phenoxy groups at non-peripheral positions. Polyhedron, 30 (9):1612-1619.
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Research Article
Yazarlar

Mehmet Pişkin

Zafer Odabaş Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2016
Yayımlandığı Sayı Yıl 2016 Cilt: 6 Sayı: 2

Kaynak Göster

APA Pişkin, M., & Odabaş, Z. (2016). Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines. Karaelmas Fen Ve Mühendislik Dergisi, 6(2), 307-314.
AMA Pişkin M, Odabaş Z. Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines. Karaelmas Fen ve Mühendislik Dergisi. Haziran 2016;6(2):307-314.
Chicago Pişkin, Mehmet, ve Zafer Odabaş. “Synthesis, Characterization and Spectroscopic Properties of Novel Mono-Lutetium III Phthalocyanines”. Karaelmas Fen Ve Mühendislik Dergisi 6, sy. 2 (Haziran 2016): 307-14.
EndNote Pişkin M, Odabaş Z (01 Haziran 2016) Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines. Karaelmas Fen ve Mühendislik Dergisi 6 2 307–314.
IEEE M. Pişkin ve Z. Odabaş, “Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines”, Karaelmas Fen ve Mühendislik Dergisi, c. 6, sy. 2, ss. 307–314, 2016.
ISNAD Pişkin, Mehmet - Odabaş, Zafer. “Synthesis, Characterization and Spectroscopic Properties of Novel Mono-Lutetium III Phthalocyanines”. Karaelmas Fen ve Mühendislik Dergisi 6/2 (Haziran 2016), 307-314.
JAMA Pişkin M, Odabaş Z. Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines. Karaelmas Fen ve Mühendislik Dergisi. 2016;6:307–314.
MLA Pişkin, Mehmet ve Zafer Odabaş. “Synthesis, Characterization and Spectroscopic Properties of Novel Mono-Lutetium III Phthalocyanines”. Karaelmas Fen Ve Mühendislik Dergisi, c. 6, sy. 2, 2016, ss. 307-14.
Vancouver Pişkin M, Odabaş Z. Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines. Karaelmas Fen ve Mühendislik Dergisi. 2016;6(2):307-14.