Yeni Mono-Lutesyum Iıı Ftalosiyaninlerin Sentezi, Karakterizasyonu ve Spektroskopik Özellikleri

Yıl 2016, Cilt: 6 Sayı: 2, 307 - 314, 01.06.2016

Mehmet Pişkin Zafer Odabaş

Öz

Bu çalışmada çeşitli teknolojik uygulamalarda kullanılması amacıyla yeni, oldukça çözünür ve agregasyon yapmayan ftalosiyanin halkasına periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla tetrasübstitüe lutesyum III asetat metalli ftalosiyanin bileşikleri sentezlenmiş ve yapıları elemental analiz, FT-IR, 1H NMR, UV–vis spektroskopisi ve MALDI-TOF Kütle analiz metotları kullanılarak karakterize edilip aydınlatılmıştır. Ayrıca bu bileşiklerin periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla sübstitüe edilmesiyle spektroskopik özelliklerindeki değişiklikler rapor edilmiştir

Anahtar Kelimeler

Lutesyum III asetat, Mono-lutesyum ftalosiyanin, Agregasyon yapmayan, Non-periferal, Periferal, Çözünür

Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines

Öz

In this study, the novel, highly soluble and non-aggregated peripherally /non-peripherally tetrakis-2,6-dimethoxyphenoxy substituted lutetium III acetate mono-phthalocyanine complexes have been synthesized for use in different technological applications in this study. The new phthalocyanine complexes have been characterized by elemental analysis, IR, 1H NMR, UV–vis spectroscopy and MALDI-TOF Mass spectra. The effects of the positions peripheral or non-peripheral of the substituents on the spectroscopic properties of 2,6-dimethoxyphenoxy substituted mono-lutetium III phthalocyanines have been also reported.

Anahtar Kelimeler

Mono-phthalocyanine, lutetium III acetate, soluble, non-aggregated, peripheral, non-peripheral.

Kaynakça

• Simon, J., Andre, JJ. 1985. Photoelectrical Properties and Solar Cells In: Molecular Semiconductors. J.M. Lehn, Ch.W Rees [eds.], Springer-Verlag, Berlin, pp-73-147.
• Leznoff, CC., Lever, AbP. 1989. Phthalocyanines, Properties and Applications Vol.1, Wiley–VCH, New York, pp-341–392.
• Leznoff, CC., Lever, AbP. 1993. Phthalocyanines, Properties and Applications Vol.3, Wiley–VCH, New York, pp-119–167.
• Leznoff, CC., Lever, AbP. 1996. Phthalocyanines, Properties and Applications Vol.4, Wiley–VCH, New York, pp-79–181.
• Simon, J., bassoul, P. 2000. Design of Molecular Materials: Supramolecular Engineering, John Wiley & Sons, Chichester, pp 197-291.
• Gould, RD. 1996. Structure and electrical conduction properties of phthalocyanine thin films. Coordın. Chem. Rev., 156: 237- 274.
• Kudrevich, SV., Van Lier, JE. 1996. Azaanalogs of phthalocyanine: syntheses and properties. Coordın. Chem. Rev., 156:163-182.
• Rosenthal, I. 1996. In: Phthalocyanines - Properties and Applications, Leznoff, C.C.; Lever, A.B.P. [eds.], Wiley VCH: New York, Vol. 4,; pp. 486-514.
• buono-Core, GE., Li, H., Marciniak, b. 1990. Quenching of Excited States by Lanthanide Ions and Chelates in Solution. Coordın. Chem. Rev., 90: 55-87.
• Wu, W.-N., Tang, N., Yan, LJ. 2008. Syntheses, Characterization and Fluorescent Properties of Six Novel Lanthanide Com- plexes with N,N-diphenyl-2-(quinolin-8-yloxy)acetamide. J. Fluoresc.,18:101-107.
• Edward, A., Chu, TY., Claude, C., Sokolik, I., Okamoto, Y., Dorisinville, R. 1997. Synthesis and characterization of electroluminescent organo-lanthanide (III) complexes. Synth. Met., 84: 433-434.
• Meares, CF.,Wense TG. 1984. Metal chelates as probes of biological systems. Acc. Chem. Res, 17: 202-209.
• Kukhta, A., Kolesnik, E., Grabchev, IJ. 2006. Spectral and luminescent properties and electroluminescence of polyvinylcarbazole with 1,8-naphthalimide in the side chain. J.Fluoresc., 16:375-378.
• Wu, Fb., Zhang C. 2002. A new europium beta-diketone chelate for ultrasensitive time-resolved fluorescence immunoassays, Anal Biochem, 311:57-67.
• Nicholson, M., Leznoff, CC., Lever. AbP. 1993. The Redox Chemistry of Metallophthalocyanines in Solution. In: Leznoff, CC., Lever ABP [eds.], Phthalocyanines, Properties and Applications, Vol. 3, VCH, Publications, New York, pp.119–167.
• Zugle, R., Litwinski, C., Nyokong, T. 2011. Photophysical char- acterization of dysprosium, erbium and lutetium phthalocya- nines tetrasubstituted with phenoxy groups at non-peripheral positions. Polyhedron, 30 (9):1612-1619.