Effect of Mechanical Alloying Time on Microstructure, Hardness and Electrical Conductivity Properties of Cu-B4C Composites
Yıl 2024,
Cilt: 10 Sayı: 1, 7 - 14, 28.06.2024
Hasaneen Houssain
,
Ahmet Oğuzhan Cengiz
,
Serkan Islak
Öz
This study aims to investigate the effect of mechanical alloying time on the microstructure, hardness, and electrical conductivity properties of copper (Cu) matrix boron carbide (B4C) reinforced composites. Cu-B4C composites with 2% B4C by volume were subjected to mechanical alloying processes for 0, 1, 5, 10, and 20 hours. The microstructure and phase formation of the composites were examined using scanning electron microscopy (SEM) and X-ray diffraction (XRD). Hardness measurements of the composites were conducted using the microhardness measurement method, and density values were determined using the Archimedes principle. The electrical conductivity values of the samples were measured in terms of the international annealed copper standard (%IACS) based on the eddy current principle. SEM images revealed a more homogeneous distribution of B4C particles in the Cu matrix as the mechanical alloying time increased. Hardness values showed significant increases with the increasing mechanical alloying time, reaching the highest value in the 20 h milled sample with a 90.86 value. The effect on electrical conductivity values was noteworthy, with a measurement of 63% IACS at 0 hours and 25% IACS at 20 hours of mechanical alloying.
Destekleyen Kurum
TÜBİTAK
Proje Numarası
1919B012218302
Teşekkür
This study was funded by project number 1919B012218302 within the scope of the 2209-A University Students Research Projects Support Program, carried out by TÜBİTAK Scientist Support Programs Directorate. As the authors, we would like to thank TÜBİTAK for their support.
Kaynakça
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- Şimşek, İ. (2019). The effect of B4C amount on wear behaviors of Al-Graphite/B4C hybrid composites produced by mechanical alloying. Journal of Boron, 4(2), 100-106.
- Pripanapong, P., & Tachai, L. (2010). Microstructure and mechanical properties of sintered Ti-Cu alloys. Advanced Materials Research, 93, 99-104.
- Chandrakanth, R. G., Rajkumar, K., & Aravindan, S. (2009). Fabrication of copper–TiC–graphite hybrid metal matrix composites through microwave processing. The International Journal of Advanced Manufacturing Technology, 48(5–8), 645–653.
- Hamid, F. S., A. Elkady, O., Essa, A. R. S., El-Nikhaily, A., Elsayed, A., & Eessaa, A. K. (2021). Analysis of microstructure and mechanical properties of bi-modal nanoparticle-reinforced Cu-matrix. Crystals, 11(9), 1081.
- Fathy, A., & El-Kady, O. (2013). Thermal expansion and thermal conductivity characteristics of Cu–Al2O3 nanocomposites. Materials & Design (1980-2015), 46, 355-359.
- Shaik, M. A., & Golla, B. R. (2020). Mechanical, tribological and electrical properties of ZrB2 reinforced Cu processed via milling and high-pressure hot pressing. Ceramics International, 46(12), 20226-20235.
- M.Rohini, P.Reyes, S.Velumani, and Becerril J. I. G. (2014). Effect of Milling Time on Mechanically Alloyed Cu(In,Ga)Se2 Nanoparticles, in 2014 11th International Conference on Electrical Engineering, Computing Science and Automatic Control (CCE), , pp. 413–417.
- Akbarpour M. R. (2021). Effects of mechanical milling time on densification, microstructural characteristics and hardness of Cu–SiC nanocomposites prepared by conventional sintering process. Mater Chem Phys, vol. 261, Mar.
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- Gogebakan, M., Kursun, C., & Eckert, J. (2013). Formation of new Cu-based nanocrystalline powders by mechanical alloying technique. Powder technology, 247, 172-177.
- Salur, E., Acarer, M., & Şavkliyildiz, İ. (2021). Improving mechanical properties of nano-sized TiC particle reinforced AA7075 Al alloy composites produced by ball milling and hot pressing. Materials Today Communications, 27, 102202.
- Liu, G. F., & Chen, T. J. (2022). Effect of ball-milling time on microstructures and mechanical properties of heterogeneity-improved heterostructured 2024Al alloys fabricated through powder thixoforming. Materials Chemistry and Physics, 291, 126684.
- Toozandehjani, M., Matori, K. A., Ostovan, F., Abdul Aziz, S., & Mamat, M. S. (2017). Effect of milling time on the microstructure, physical and mechanical properties of Al-Al2O3 nanocomposite synthesized by ball milling and powder metallurgy. Materials, 10(11), 1232.
- Zhou, J., & Duszczyk, J. (1999). Liquid phase sintering of an AA2014-based composite prepared from an elemental powder mixture. Journal of materials science, 34(3), 545-550.
- Kriewah, O. A. E., & Islak, S. (2022). Synthesis of Cu-Cr-B4C-CNF hybrid composites. Kastamonu University Journal of Engineering and Sciences, 8(2), 90-97.
- Asghar, Z., Latif, M. A., Rafi-ud-Din, Nazar, Z., Ali, F., Basit, A., ... & Subhani, T. (2018). Effect of distribution of B4C on the mechanical behaviour of Al-6061/B4C composite. Powder Metallurgy, 61(4), 293-300.
- Rahimian, M., Ehsani, N., Parvin, N., & reza Baharvandi, H. (2009). The effect of particle size, sintering temperature and sintering time on the properties of Al–Al2O3 composites, made by powder metallurgy. Journal of Materials Processing Technology, 209(14), 5387-5393.
- Şevik, H., & Kurnaz, S. C. (2006). Properties of alumina particulate reinforced aluminum alloy produced by pressure die casting. Materials in Engineering, 27(8), 676–683.
- Alizadeh, A., & Taheri-Nassaj, E. (2012). Mechanical properties and wear behavior of Al–2wt.% Cu alloy composites reinforced by B4C nanoparticles and fabricated by mechanical milling and hot extrusion. Materials Characterization, 67, 119–128.
- Suryanarayana, C. (2001). Mechanical alloying and milling. Progress in materials science, 46(1-2), 1-184.
- Lokesh, G. N., & Karunakara, S. (2020). Impact of Particle size distribution for variable mixing time on mechanical properties and microstructural evaluation of Al-Cu/B4C composite. Materials Today: Proceedings, 22, 1715-1722.
- Shukla, A. K., Nayan, N., Murty, S. V. S. N., Sharma, S. C., Chandran, P., Bakshi, S. R., & George, K. M. (2013). Processing of copper–carbon nanotube composites by vacuum hot pressing technique. Materials Science and Engineering: A, 560, 365-371.
- Shu, D., Li, X., & Yang, Q. (2021). Effect on Microstructure and Performance of B4C Content in B4C/Cu Composite. Metals, 11(8), 1250.
- Guo, X. F., Jia, L., Lu, Z. L., Xie, H., & Kondoh, K. (2024). Enhanced combination of strength and electrical conductivity properties with CrB2 reinforced Cu matrix composites fabricated by powder metallurgy. Materials Today Communications, 38, 107980.
- Altinsoy, I., Efe, F. G. C., Aytaş, D., Kılıç, M., Ozbek, I., & Bindal, C. (2013). Some properties of Cu-B4C composites manufactured by powder metallurgy. Periodicals of Engineering and Natural Sciences, 1(1).
Yıl 2024,
Cilt: 10 Sayı: 1, 7 - 14, 28.06.2024
Hasaneen Houssain
,
Ahmet Oğuzhan Cengiz
,
Serkan Islak
Proje Numarası
1919B012218302
Kaynakça
- Taya, M., & Arsenault, R. J. (1989). Introduction. In Elsevier eBooks (pp. 1–8).
- Şimşek, İ. (2019). The effect of B4C amount on wear behaviors of Al-Graphite/B4C hybrid composites produced by mechanical alloying. Journal of Boron, 4(2), 100-106.
- Pripanapong, P., & Tachai, L. (2010). Microstructure and mechanical properties of sintered Ti-Cu alloys. Advanced Materials Research, 93, 99-104.
- Chandrakanth, R. G., Rajkumar, K., & Aravindan, S. (2009). Fabrication of copper–TiC–graphite hybrid metal matrix composites through microwave processing. The International Journal of Advanced Manufacturing Technology, 48(5–8), 645–653.
- Hamid, F. S., A. Elkady, O., Essa, A. R. S., El-Nikhaily, A., Elsayed, A., & Eessaa, A. K. (2021). Analysis of microstructure and mechanical properties of bi-modal nanoparticle-reinforced Cu-matrix. Crystals, 11(9), 1081.
- Fathy, A., & El-Kady, O. (2013). Thermal expansion and thermal conductivity characteristics of Cu–Al2O3 nanocomposites. Materials & Design (1980-2015), 46, 355-359.
- Shaik, M. A., & Golla, B. R. (2020). Mechanical, tribological and electrical properties of ZrB2 reinforced Cu processed via milling and high-pressure hot pressing. Ceramics International, 46(12), 20226-20235.
- M.Rohini, P.Reyes, S.Velumani, and Becerril J. I. G. (2014). Effect of Milling Time on Mechanically Alloyed Cu(In,Ga)Se2 Nanoparticles, in 2014 11th International Conference on Electrical Engineering, Computing Science and Automatic Control (CCE), , pp. 413–417.
- Akbarpour M. R. (2021). Effects of mechanical milling time on densification, microstructural characteristics and hardness of Cu–SiC nanocomposites prepared by conventional sintering process. Mater Chem Phys, vol. 261, Mar.
- StandardTest Methods for Density of Compacted or Sintered Powder Metallurgy (PM) Products Using Archimedes’ Principle1. 2008.
- Gogebakan, M., Kursun, C., & Eckert, J. (2013). Formation of new Cu-based nanocrystalline powders by mechanical alloying technique. Powder technology, 247, 172-177.
- Salur, E., Acarer, M., & Şavkliyildiz, İ. (2021). Improving mechanical properties of nano-sized TiC particle reinforced AA7075 Al alloy composites produced by ball milling and hot pressing. Materials Today Communications, 27, 102202.
- Liu, G. F., & Chen, T. J. (2022). Effect of ball-milling time on microstructures and mechanical properties of heterogeneity-improved heterostructured 2024Al alloys fabricated through powder thixoforming. Materials Chemistry and Physics, 291, 126684.
- Toozandehjani, M., Matori, K. A., Ostovan, F., Abdul Aziz, S., & Mamat, M. S. (2017). Effect of milling time on the microstructure, physical and mechanical properties of Al-Al2O3 nanocomposite synthesized by ball milling and powder metallurgy. Materials, 10(11), 1232.
- Zhou, J., & Duszczyk, J. (1999). Liquid phase sintering of an AA2014-based composite prepared from an elemental powder mixture. Journal of materials science, 34(3), 545-550.
- Kriewah, O. A. E., & Islak, S. (2022). Synthesis of Cu-Cr-B4C-CNF hybrid composites. Kastamonu University Journal of Engineering and Sciences, 8(2), 90-97.
- Asghar, Z., Latif, M. A., Rafi-ud-Din, Nazar, Z., Ali, F., Basit, A., ... & Subhani, T. (2018). Effect of distribution of B4C on the mechanical behaviour of Al-6061/B4C composite. Powder Metallurgy, 61(4), 293-300.
- Rahimian, M., Ehsani, N., Parvin, N., & reza Baharvandi, H. (2009). The effect of particle size, sintering temperature and sintering time on the properties of Al–Al2O3 composites, made by powder metallurgy. Journal of Materials Processing Technology, 209(14), 5387-5393.
- Şevik, H., & Kurnaz, S. C. (2006). Properties of alumina particulate reinforced aluminum alloy produced by pressure die casting. Materials in Engineering, 27(8), 676–683.
- Alizadeh, A., & Taheri-Nassaj, E. (2012). Mechanical properties and wear behavior of Al–2wt.% Cu alloy composites reinforced by B4C nanoparticles and fabricated by mechanical milling and hot extrusion. Materials Characterization, 67, 119–128.
- Suryanarayana, C. (2001). Mechanical alloying and milling. Progress in materials science, 46(1-2), 1-184.
- Lokesh, G. N., & Karunakara, S. (2020). Impact of Particle size distribution for variable mixing time on mechanical properties and microstructural evaluation of Al-Cu/B4C composite. Materials Today: Proceedings, 22, 1715-1722.
- Shukla, A. K., Nayan, N., Murty, S. V. S. N., Sharma, S. C., Chandran, P., Bakshi, S. R., & George, K. M. (2013). Processing of copper–carbon nanotube composites by vacuum hot pressing technique. Materials Science and Engineering: A, 560, 365-371.
- Shu, D., Li, X., & Yang, Q. (2021). Effect on Microstructure and Performance of B4C Content in B4C/Cu Composite. Metals, 11(8), 1250.
- Guo, X. F., Jia, L., Lu, Z. L., Xie, H., & Kondoh, K. (2024). Enhanced combination of strength and electrical conductivity properties with CrB2 reinforced Cu matrix composites fabricated by powder metallurgy. Materials Today Communications, 38, 107980.
- Altinsoy, I., Efe, F. G. C., Aytaş, D., Kılıç, M., Ozbek, I., & Bindal, C. (2013). Some properties of Cu-B4C composites manufactured by powder metallurgy. Periodicals of Engineering and Natural Sciences, 1(1).