Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS

Semiha Köprü; Fatma Dokan; Zekiye Kocakaya; Sedat Per; Mehmet Çadır; Mustafa Kocakaya

doi:10.17475/kastorman.1179052

EN TR

Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS

Öz

Aim of study: Lichens are biological indicators of environmental pollution of both natural and artificial origin in terms of various elements. In 9 samples (Cladonia coniocraea, C. fimbriata, C. firma, C. foliacea, C. furcate, C. pocillum, C. pyxidata, C. rangiformis and C. subulata) belonging to the genus Cladonia collected from different regions of Turkey; Aluminum, Chromium, Manganese, Iron, Cobalt, Nickel, Copper, Zinc, Arsenic, Selenium, Strontium, Cadmium, Tin, Mercury and Lead element amounts were investigated. Area of study: Lichen samples belonging to the same genus were collected in field studies conducted in 7 different cities in Turkey. Material and methods: All samples were analyzed independently after solubilization in acid medium in microwave system and in triplicate. The accuracy of the results has been confirmed by analysis of 1547 Peach Leaf certified reference material. Main results: Sources of metals, metal accumulation mechanisms and how much they are absorbed by lichens were determined. The highest Al, Cr, Ni concentrations in Cladonia firma are 429.3, 3.04, 13.53 µg/g, respectively. The highest Co, Sr, Cu, Se, Hg concentrations in Cladonia subulata are 0.81, 33.59, 13.16, 0.158, 0.060 µg/g, respectively. The highest Pb, Cd, Sn concentrations in Cladonia pyxidata are 5.90, 0.30, 6.50 µg/g, respectively. The highest Fe, Mn, Zn, As concentrations were 228.7, 17.8, 26.44 and 1.335 µg/g, respect. Highlights: The results showed that metal accumulation in lichens was directly related to the environment in which lichens were collected.

Anahtar Kelimeler

ICP-MS, Lichens, Cladonia, Trace element

Türkiye'deki Bazı Cladonia Türlerindeki Eser Elementlerin ICP-MS ile Belirlenmesi

Öz

Çalışmanın amacı: Likenler, çeşitli elementler açısından hem doğal hem de yapay kaynaklı çevresel kirliliğin biyolojik göstergeleridir. Türkiye’nin farklı bölgelerinden toplanmış Cladonia cinsine ait 9 örnekte (Cladonia coniocraea, C. fimbriata, C. firma, C. foliacea, C. furcate, C. pocillum, C. pyxidata, C. rangiformis and C. subulata) Alüminyum, Krom, Mangan, Demir, Kobalt, Nikel, Bakır, Çinko, Arsenik, Selenyum, Stronsiyum, Kadmiyum, Kalay, Cıva ve Kurşun element miktarları araştırılmıştır. Çalışma alanı: Türkiye’de 7 farklı ilde yapılmış arazi çalışmalarında aynı cinse ait liken örnekleri toplanmıştır. Materyal ve yöntem: Tüm örnekler bağımsız olarak mikrodalga sistemde asit ortamında çözünürleştirildikten sonra ve üç paralel halinde analiz edilmiştir. Sonuçların doğruluğu, 1.547 Şeftali Yaprağı sertifikalı referans materyalin analiziyle onaylanmıştır. Temel sonuçlar: Metallerin kaynakları, metal birikim mekanizmaları ve likenler tarafından ne kadar absorblandıkları belirlenmiştir. Cladonia firma’da en yüksek Al, Cr, Ni konsantrasyonları sırasıyla 429.3, 3.04, 13.53 µg/g'dır. Cladonia subulata'da en yüksek Co, Sr, Cu, Se, Hg konsantrasyonları sırasıyla 0.81, 33.59, 13.16, 0.158, 0.060 µg/g'dır. Cladonia pyxidata'da en yüksek Pb, Cd, Sn konsantrasyonları sırasıyla 5.90, 0.30, 6.50 µg/g'dır. En yüksek Fe, Mn, Zn, As konsantrasyonları sırasıyla 228.7, 17.8, 26.44, 1.335 µg/g'dır. Araştırma vurguları: Sonuçlar likenlerde metal birikiminin doğrudan likenlerin toplandığı ortamla ilişkili olduğunu göstermiştir.

Anahtar Kelimeler

ICP-MS, Likenler, Cladonia, Eser element

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

-

Bölüm

Araştırma Makalesi

Yazarlar

Semiha Köprü Bu kişi benim
Türkiye

Fatma Dokan ^* Bu kişi benim
Türkiye

Zekiye Kocakaya Bu kişi benim
Türkiye

Sedat Per Bu kişi benim
Türkiye

Mehmet Çadır Bu kişi benim
Türkiye

Mustafa Kocakaya Bu kişi benim
Türkiye

Yayımlanma Tarihi

27 Eylül 2022

Gönderilme Tarihi

27 Temmuz 2021

Kabul Tarihi

20 Mayıs 2022

Yayımlandığı Sayı

Yıl 2022 Cilt: 22 Sayı: 2

DOI

https://doi.org/10.17475/kastorman.1179052

IZ

https://izlik.org/JA96ZG54GK

APA

Köprü, S., Dokan, F., Kocakaya, Z., Per, S., Çadır, M., & Kocakaya, M. (2022). Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS. Kastamonu University Journal of Forestry Faculty, 22(2), 135-146. https://doi.org/10.17475/kastorman.1179052

AMA

1.Köprü S, Dokan F, Kocakaya Z, Per S, Çadır M, Kocakaya M. Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS. Kastamonu University Journal of Forestry Faculty. 2022;22(2):135-146. doi:10.17475/kastorman.1179052

Chicago

Köprü, Semiha, Fatma Dokan, Zekiye Kocakaya, Sedat Per, Mehmet Çadır, ve Mustafa Kocakaya. 2022. “Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS”. Kastamonu University Journal of Forestry Faculty 22 (2): 135-46. https://doi.org/10.17475/kastorman.1179052.

EndNote

Köprü S, Dokan F, Kocakaya Z, Per S, Çadır M, Kocakaya M (01 Eylül 2022) Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS. Kastamonu University Journal of Forestry Faculty 22 2 135–146.

IEEE

[1]S. Köprü, F. Dokan, Z. Kocakaya, S. Per, M. Çadır, ve M. Kocakaya, “Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS”, Kastamonu University Journal of Forestry Faculty, c. 22, sy 2, ss. 135–146, Eyl. 2022, doi: 10.17475/kastorman.1179052.

ISNAD

Köprü, Semiha - Dokan, Fatma - Kocakaya, Zekiye - Per, Sedat - Çadır, Mehmet - Kocakaya, Mustafa. “Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS”. Kastamonu University Journal of Forestry Faculty 22/2 (01 Eylül 2022): 135-146. https://doi.org/10.17475/kastorman.1179052.

JAMA

1.Köprü S, Dokan F, Kocakaya Z, Per S, Çadır M, Kocakaya M. Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS. Kastamonu University Journal of Forestry Faculty. 2022;22:135–146.

MLA

Köprü, Semiha, vd. “Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS”. Kastamonu University Journal of Forestry Faculty, c. 22, sy 2, Eylül 2022, ss. 135-46, doi:10.17475/kastorman.1179052.

Vancouver

1.Semiha Köprü, Fatma Dokan, Zekiye Kocakaya, Sedat Per, Mehmet Çadır, Mustafa Kocakaya. Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS. Kastamonu University Journal of Forestry Faculty. 01 Eylül 2022;22(2):135-46. doi:10.17475/kastorman.1179052

Determination of Trace Elements of Some Cladonia Species from Turkey by ICP-MS

Öz

Anahtar Kelimeler

Türkiye'deki Bazı Cladonia Türlerindeki Eser Elementlerin ICP-MS ile Belirlenmesi

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster