Fagus orientalis Yüzeyinin ZnO/TiO2/FAS-17 Bazlı Nanopartiküllerle İşlenmesi

Yıl 2023, Cilt: 23 Sayı: 3, 175 - 185, 06.12.2023

Doğu Ramazanoğlu Ferhat Özdemir

https://doi.org/10.17475/kastorman.1394874

Öz

Çalışmanın amacı: Bu araştırmada, kayın ağacının (Fagus Orientalis) yüzeyi, ahşap endüstrisi tarafından yaygın olarak kullanılan güçlü biyoyapısı nedeniyle bir substrat olarak seçilmiştir. Hizmet ömrünü artırmak amacıyla, ZnO, TiO2 ve FAS-17 nanopartiküller ile fonksiyonelleştirilmiştir.
Materyal ve yöntem: FAS-17 (Trimetoksisilan) ve amonyum hekzaflorotitanat Sigma-Aldrich'ten ve çinko borat Etimine S.A.'dan satın alınmıştır. Metanol, etil alkol, hidroklorik asit, sodyum hidroksit ve çinko oksit TEKKİM tarafından sağlanmıştır. Karakterizasyon yöntemleri arasında FTIR, TG/DTA, XRD, SEM ve EDX yer almıştır. Hidrofobiklik KSV Cam101 kullanılarak su temas açısı ile belirlenmiştir. UV-Vis analizinde Shimadzu UV-160 spektrofotometresi kullanılmış, yüzey pürüzlülüğü Marsurf M 300 cihazı (ISO 4287) ile ölçülmüş ve renk analizi Datacolor Elrepho 450 X spektrometresi (ASTM 2021) ile gerçekleştirilmiştir.
Temel sonuçlar: Ahşabın termal stabilitesi, ZnO/TiO2 nanopartiküllerin hidrotermal olarak yerleştirilmesiyle önemli ölçüde iyileştirilmiştir. Ayrıca, FAS-17 olarak adlandırılan Triethoxy-1H,1H,2H,2H-perfluorodesilsilan (C14H19F13O3Si) kullanılarak etkili bir hidrofobizasyon sağlanmıştır.
Araştırma vurguları: ZnO tabanlı nano biyomimetik akıllı yüzeyin sentezi, ahşap malzemeye hidrofobik bir özellik kazandırmıştır. Lignoselülozik yüzeyin bu yeni fonksiyonel özelliği, hijyenin önemli olduğu her türlü alanda tercih edilmesini sağlayabilir.

Anahtar Kelimeler

Fagus Orientalis, Hidrotermal yöntem, ZnO/TiO2/FAS-17 Nanoparçacıkları

Treatment of Fagus orientalis Surface by ZnO/TiO2/FAS-17-Based Nanoparticles

Öz

Aim of study: In this research, the surface of Fagus orientalis (beechwood) was chosen as a substrate due to its widely used strong biostructure in the wood industry. It was functionalized with ZnO, TiO2, and FAS-17 nanoparticles to enhance its service life.
Material and methods: FAS-17 (Trimethoxysilane) and ammonium hexafluorotitanate were purchased from Sigma-Aldrich, and zinc borate from Etimine S.A. Methanol, ethyl alcohol, hydrochloric acid, sodium hydroxide, and zinc oxide were provided by TEKKIM. Characterization methods included FTIR, TG/DTA, XRD, SEM, and EDX. Hydrophobicity was determined by water contact angle using KSV Cam101. UV-Vis analysis used a Shimadzu UV-160 spectrophotometer, surface roughness was measured with a Marsurf M 300 device (ISO 4287), and color analysis was performed with a Datacolor Elrepho 450 X spectrometer (ASTM 2021).
Main results: The thermal stability of wood was significantly improved through the hydrothermal deposition of ZnO/TiO2 nanoparticles. Additionally, hydrophobization was achieved using Triethoxy-1H,1H,1H,2H,2H,2H-perfluorodecylsilane (C14H19F13O3Si), referred to as FAS-17.
Research highlights: The study demonstrated that the introduction of ZnO/TiO2 nanoparticles improved the thermal stability of wood. Furthermore, the use of FAS-17 resulted in effective hydrophobization. The thermal stability of wood was improved with ZnO/TiO2 nanoparticles. In addition, hydrophobization was supplied by FAS-17.

Anahtar Kelimeler

Fagus orientalis, Hydrothermal Method, ZnO/TiO2/FAS-17 Nano Articles

Kaynakça

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