Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge

Berna Kavacık; Deniz Dölgen

doi:10.31466/kfbd.1063741

TR EN

Zirkonyum Kaplı Su Arıtma Tesisi Çamurları ile Sudan Arsenik ve Antimon Giderimi

Öz

Bu çalışmada, arsenik ve antimon gideriminde içme suyu arıtma çamurlarının adsorban olarak yeniden kullanım potansiyeli araştırılmıştır. Zirkonyum oksit kaplı çamur termal arıtım ve zirkonyum oksit kaplama prosesleriyle üretilmiş ve adsorbanın karakterizasyonu araştırılmıştır. Sonuçlar, zirkonyum oksit kaplı çamurun ağırlıklı olarak amorf olduğu ve yüksek yüzey alanına (170 m2g-1) sahip olduğunu göstermiştir. Arsenik gideriminde optimum koşulların belirlenmesi amacıyla kesikli adsorpsiyon deneyleri gerçekleştirilmiştir. Deney sonucunda optimum pH 3 olarak elde edilmiş, 1 gL-1 adsorban dozunda 180 dk. temas süresinde arsenik konsantrasyonu 50 μgL-1 den 0.25 μgL-1’ye düşmüştür. İzoterm verisi Freundlich izoterm modeline uymuş ve adsorpsiyon kapasitesi 7.38 mgg-1 olarak bulunmuştur. Deneysel verilerin yalancı ikinci derece kinetiğe uyum sağladığı (R2≥ 0.999) saptanmıştır. Ayrıca sürekli akış koşullarında sabit yataklı kolonda arsenik ve antimon gideriminin kolon performansı araştırılmıştır. Adsorpsiyon proses davranışının Thomas ve Yoon–Nelson modelleri tarafından başarıyla tanımlanması, modellerin sabit yataklı kolon dizaynında zirkonyum oksit kaplı çamur için uygun olduğunu göstermektedir.

Anahtar Kelimeler

Adsorpsiyon, Antimon, Arsenik, İçme suyu arıtma çamuru, Zirkonyum oksit kaplama

Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge

Öz

In this study, the reuse potential of drinking water treatment sludge as an adsorbent was investigated for the removal of arsenic and antimony. A sludge-derived adsorbent, zirconium oxide-coated sludge, was produced by using thermal treatment and zirconium oxide coating processes, and characterization of the adsorbent was investigated. The results showed that zirconium oxide-coated sludge was mainly amorphous and had a high surface area (170 m2g-1). Batch adsorption tests were performed to specify the optimum conditions for arsenic removal. The study revealed that the removal of As (T) was best achieved at pH 3. The initial arsenic concentration descended from 50 μgL-1 to the 0.25 μgL-1 at contact time, 180 min, with the adsorbent dose of 1 gL-1. The isotherm data fitted fine to the Freundlich isotherm model, and adsorption capacity was found to be 7.38 mgg-1. The pseudo-second order model fitted well with the experimental data (R2≥ 0.999). Column performance for arsenic and antimony removal in a fixed bed under continuous flow conditions was also studied. The adsorption process behavior was described successfully by Thomas and Yoon–Nelson models, indicating that the models were suitable for a zirconium oxide-coated sludge fix-bed column design.

Anahtar Kelimeler

Adsorption, Antimony, Arsenic, Drinking water treatment sludge, Zirconium oxide coating

Destekleyen Kurum

Dokuz Eylül Üniversitesi

Proje Numarası

BAP 2018.KB.FEN.036

Teşekkür

This study was supported by Dokuz Eylül University, Scientific Research Project Program (Project No: BAP 2018.KB.FEN.036).

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Mühendislik

Bölüm

Araştırma Makalesi

Yazarlar

Berna Kavacık ^*
0000-0002-1756-8917
Türkiye

Deniz Dölgen
0000-0002-5888-3032
Türkiye

Yayımlanma Tarihi

15 Haziran 2022

Gönderilme Tarihi

27 Ocak 2022

Kabul Tarihi

7 Nisan 2022

Yayımlandığı Sayı

Yıl 2022 Cilt: 12 Sayı: 1

DOI

https://doi.org/10.31466/kfbd.1063741

IZ

https://izlik.org/JA64CM46LB

APA

Kavacık, B., & Dölgen, D. (2022). Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge. Karadeniz Fen Bilimleri Dergisi, 12(1), 317-339. https://doi.org/10.31466/kfbd.1063741

AMA

1.Kavacık B, Dölgen D. Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge. KFBD. 2022;12(1):317-339. doi:10.31466/kfbd.1063741

Chicago

Kavacık, Berna, ve Deniz Dölgen. 2022. “Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge”. Karadeniz Fen Bilimleri Dergisi 12 (1): 317-39. https://doi.org/10.31466/kfbd.1063741.

EndNote

Kavacık B, Dölgen D (01 Haziran 2022) Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge. Karadeniz Fen Bilimleri Dergisi 12 1 317–339.

IEEE

[1]B. Kavacık ve D. Dölgen, “Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge”, KFBD, c. 12, sy 1, ss. 317–339, Haz. 2022, doi: 10.31466/kfbd.1063741.

ISNAD

Kavacık, Berna - Dölgen, Deniz. “Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge”. Karadeniz Fen Bilimleri Dergisi 12/1 (01 Haziran 2022): 317-339. https://doi.org/10.31466/kfbd.1063741.

JAMA

1.Kavacık B, Dölgen D. Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge. KFBD. 2022;12:317–339.

MLA

Kavacık, Berna, ve Deniz Dölgen. “Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge”. Karadeniz Fen Bilimleri Dergisi, c. 12, sy 1, Haziran 2022, ss. 317-39, doi:10.31466/kfbd.1063741.

Vancouver

1.Berna Kavacık, Deniz Dölgen. Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge. KFBD. 01 Haziran 2022;12(1):317-39. doi:10.31466/kfbd.1063741

Karadeniz Fen Bilimleri Dergisinde yayınlanan makaleler Creative Commons Attribution-NonCommercial 4.0 International kapsamında lisanslanmıştır.

Zirkonyum Kaplı Su Arıtma Tesisi Çamurları ile Sudan Arsenik ve Antimon Giderimi

Öz

Anahtar Kelimeler

Arsenic and Antimony Removal from Water by Zirconium-Coated Water Treatment Plant Sludge

Öz

Anahtar Kelimeler

Destekleyen Kurum

Proje Numarası

Teşekkür

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

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