Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization

Ergül Meyvacı; Efkan Çatıker; Temel Öztürk

doi:10.31466/kfbd.1260147

TR EN

Poli(β-Propiyolakton)-b-Poli(Metil Metakrilat) Üç Kollu Blok Kopolimerinin Atom Transfer Radikal Polimerizasyonuyla Sentezi ve Karakterizasyonu

Öz

Son uçları dibromlanmış poli(β-propiyolakton), sırasıyla β-propiyolaktonun halka açma polimerizasyonu ve poli(β-propiolakton)un dibrominasyonu yoluyla hazırlandı. Poli(β-propiyolakton)-b-poli(metil metakrilat) üç kollu blok kopolimer sentezi, metil metakrilatın bromür uç gruplarına sahip poli(β-propiyolakton) üzerine atom transferiyle radikal polimerizasyonuyla elde edildi. Polimerlerin karakterizasyonu, 1H-NMR, DSC, TGA ve GPC kullanılarak gerçekleştirildi. Son ürünün GPC analizi, 9353 g.mol-1 ortalama molekül ağırlığına karşılık gelen bir tek dağılımlı eğri gösterdi. Üç kollu blok kopolimerin TGA analizi, 212 oC ve 411 oC'de sırasıyla β-propiyolakton ve metil metakrilat bloklarına karşılık gelen iki basamaklı bozunma eğrisi sergiledi. Poli(β-propiolakton)-b-poli(metil metakrilat) üç kollu blok kopolimerinin DSC analizi, -22.02 oC ve 86.55 oC'de sırasıyla β-propiyolakton ve metil metakrilat bloklarına karşılık gelen iki camsı geçiş sıcaklığı gösterdi. Spektroskopik ve termal analizler, üç kollu blok kopolimerin sırasıyla halka açma polimerizasyonu ve atom transfer radikal polimerizasyonu yoluyla başarılı bir şekilde sentezlendiğini kanıtladı.

Anahtar Kelimeler

Atom Transfer Radikal Polimerizasyonu, Makro Başlatıcı, Poli(β-propiyolakton), Halka Açılması Polimerizasyonu, Üç Kollu Blok Kopolimer.

Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization

Öz

Terminally dibrominated poly(β-propiolactone) was prepared through sequentially ring-opening polymerization of β-propiolactone and dibromination of the former product. Synthesis of poly(β-propiolactone)-b poly(methyl methacrylate) tri-arm block copolymer was achieved by atom transfer radical polymerization of methyl methacrylate onto the poly(β-propiolactone) with bromide end groups. The characterization of the polymers was carried out using 1H-NMR, DSC, TGA, and GPC. GPC analysis of the final product resulted in an unimodal curve corresponding to the weight average molecular weight of 9353 g.mol-1. TGA analysis of the tri-arm block copolymer exhibited a two-step decomposition curve corresponding to the β-propiolactone and the methyl methacrylate blocks at 212 oC and 411 oC, respectively. DSC analysis of poly(β-propiolactone)-b poly(methyl methacrylate) tri-arm block copolymer showed two glass temperatures corresponding to the β-propiolactone and the methyl methacrylate blocks at -22.02 oC and 86.55 oC, respectively. The spectroscopic and thermal analyses proved that the tri-arm block copolymer was successfully synthesized through ring-opening polymerization and atom transfer radical polymerization, respectively.

Anahtar Kelimeler

Atom Transfer Radical Polymerization, Macro Initiator, Poly(β-Propiolactone), Ring-Opening Polymerization, Tri-Arm Block Copolymer.

Kaynakça

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Ayrıntılar

Birincil Dil

İngilizce

Konular

Kimya Mühendisliği (Diğer)

Bölüm

Araştırma Makalesi

Yazarlar

Ergül Meyvacı
0000-0003-3530-1316
Türkiye

Efkan Çatıker
0000-0003-2493-7570
Türkiye

Temel Öztürk ^*
0000-0002-7856-9809
Türkiye

Yayımlanma Tarihi

15 Eylül 2023

Gönderilme Tarihi

4 Mart 2023

Kabul Tarihi

1 Ağustos 2023

Yayımlandığı Sayı

Yıl 2023 Cilt: 13 Sayı: 3

DOI

https://doi.org/10.31466/kfbd.1260147

IZ

https://izlik.org/JA67TK28SA

APA

Meyvacı, E., Çatıker, E., & Öztürk, T. (2023). Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization. Karadeniz Fen Bilimleri Dergisi, 13(3), 882-893. https://doi.org/10.31466/kfbd.1260147

AMA

1.Meyvacı E, Çatıker E, Öztürk T. Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization. KFBD. 2023;13(3):882-893. doi:10.31466/kfbd.1260147

Chicago

Meyvacı, Ergül, Efkan Çatıker, ve Temel Öztürk. 2023. “Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization”. Karadeniz Fen Bilimleri Dergisi 13 (3): 882-93. https://doi.org/10.31466/kfbd.1260147.

EndNote

Meyvacı E, Çatıker E, Öztürk T (01 Eylül 2023) Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization. Karadeniz Fen Bilimleri Dergisi 13 3 882–893.

IEEE

[1]E. Meyvacı, E. Çatıker, ve T. Öztürk, “Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization”, KFBD, c. 13, sy 3, ss. 882–893, Eyl. 2023, doi: 10.31466/kfbd.1260147.

ISNAD

Meyvacı, Ergül - Çatıker, Efkan - Öztürk, Temel. “Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization”. Karadeniz Fen Bilimleri Dergisi 13/3 (01 Eylül 2023): 882-893. https://doi.org/10.31466/kfbd.1260147.

JAMA

1.Meyvacı E, Çatıker E, Öztürk T. Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization. KFBD. 2023;13:882–893.

MLA

Meyvacı, Ergül, vd. “Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization”. Karadeniz Fen Bilimleri Dergisi, c. 13, sy 3, Eylül 2023, ss. 882-93, doi:10.31466/kfbd.1260147.

Vancouver

1.Ergül Meyvacı, Efkan Çatıker, Temel Öztürk. Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization. KFBD. 01 Eylül 2023;13(3):882-93. doi:10.31466/kfbd.1260147

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Poli(β-Propiyolakton)-b-Poli(Metil Metakrilat) Üç Kollu Blok Kopolimerinin Atom Transfer Radikal Polimerizasyonuyla Sentezi ve Karakterizasyonu

Öz

Anahtar Kelimeler

Synthesis and Characterization of Poly(β-Propiolactone) b-Poly(methyl methacrylate) Tri-arm Block Copolymer Using Atom Transfer Radical Polymerization

Öz

Anahtar Kelimeler

Kaynakça

Ayrıntılar

Birincil Dil

Konular

Bölüm

Yazarlar

Yayımlanma Tarihi

Gönderilme Tarihi

Kabul Tarihi

Yayımlandığı Sayı

DOI

IZ

Kaynak Göster

Cited By

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Acrylonitrile-Containing Copolymer Synthesis and Magnesium Ions Adsorption of the Copolymer

Synthesis, Characteristics and Thermally Induced Self-Assembly of Silicon-Based Thermo/Photo-Responsive Block Copolymers Prepared from Monomer Bearing Paired Side-Chain Azo Mesogens Using RAFT Process

The Impact of Hypericum perforatum L. as an Organic Free-Radical Scavenger in Biodiesel-Diesel Blends