α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri

Füsun Şeyma Güngör; Ayşe Özdemir

doi:10.31466/kfbd.1393378

TR EN

α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri

Öz

α,β-Konjuge enon bileşikleri ile 2-diazo-5,5-dimetil-1,3-heksandionun dirodyum tetraasetat (Rh2(OAc)4) katalizörlüğünde tepkimeleri gerçekleştirilmiştir. Elde edilen ürünlerin yapıları FT-IR, GC-MS ve 1H NMR ve 13C NMR yöntemleri ile karakterize edilmiştir. Çalışmada kullanılan ilk α,β-konjuge enon bileşiği olan 3-metiliden-bisiklo[2.2.1]heptan-2-onun tepkimesinden 6,6-dimetil-3,5,6,7-tetrahidro-4H-spiro[benzofuran-2,2’-bisiklo[2.2.1]heptan]-3’,4-dion bileşiği tek ürün olarak elde edilmiştir. İkinci α,β-konjuge enon bileşiği olan 1-morfolinoprop-2-en-1-on Rh-karbeni ile tepkime vermemiş olup bu tepkimeden sadece karben dimeri elde edilmiştir.

Anahtar Kelimeler

Diazodikarbonil, Konjuge Enon, Dihidrofuran, Rh2(OAc)4

Destekleyen Kurum

İ.T.Ü. Bilimsel Araştırmalar Proje Birimi

Proje Numarası

İTÜ-Bap proje ID-kod 9039-1819

Etik Beyan

Yapılan çalışmada araştırma ve yayın etiğine uyulmuştur.

Teşekkür

Bu çalışma İ.T.Ü. Bilimsel Araştırmalar Proje Birimi tarafından (Proje no: İTÜ-Bap proje ID-kod 9039-1819) desteklenmiştir.

Kaynakça

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Ayrıntılar

Birincil Dil

Türkçe

Konular

Fiziksel Kimya (Diğer)

Bölüm

Araştırma Makalesi

Yazarlar

Füsun Şeyma Güngör ^*
0000-0003-0870-4048
Türkiye

Ayşe Özdemir
0000-0001-8547-523X
Türkiye

Yayımlanma Tarihi

15 Mart 2024

Gönderilme Tarihi

20 Kasım 2023

Kabul Tarihi

14 Mart 2024

Yayımlandığı Sayı

Yıl 2024 Cilt: 14 Sayı: 1

DOI

https://doi.org/10.31466/kfbd.1393378

IZ

https://izlik.org/JA82DR33CU

APA

Güngör, F. Ş., & Özdemir, A. (2024). α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri. Karadeniz Fen Bilimleri Dergisi, 14(1), 249-261. https://doi.org/10.31466/kfbd.1393378

AMA

1.Güngör FŞ, Özdemir A. α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri. KFBD. 2024;14(1):249-261. doi:10.31466/kfbd.1393378

Chicago

Güngör, Füsun Şeyma, ve Ayşe Özdemir. 2024. “α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri”. Karadeniz Fen Bilimleri Dergisi 14 (1): 249-61. https://doi.org/10.31466/kfbd.1393378.

EndNote

Güngör FŞ, Özdemir A (01 Mart 2024) α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri. Karadeniz Fen Bilimleri Dergisi 14 1 249–261.

IEEE

[1]F. Ş. Güngör ve A. Özdemir, “α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri”, KFBD, c. 14, sy 1, ss. 249–261, Mar. 2024, doi: 10.31466/kfbd.1393378.

ISNAD

Güngör, Füsun Şeyma - Özdemir, Ayşe. “α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri”. Karadeniz Fen Bilimleri Dergisi 14/1 (01 Mart 2024): 249-261. https://doi.org/10.31466/kfbd.1393378.

JAMA

1.Güngör FŞ, Özdemir A. α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri. KFBD. 2024;14:249–261.

MLA

Güngör, Füsun Şeyma, ve Ayşe Özdemir. “α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri”. Karadeniz Fen Bilimleri Dergisi, c. 14, sy 1, Mart 2024, ss. 249-61, doi:10.31466/kfbd.1393378.

Vancouver

1.Füsun Şeyma Güngör, Ayşe Özdemir. α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri. KFBD. 01 Mart 2024;14(1):249-61. doi:10.31466/kfbd.1393378

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α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri

α,β-Konjuge Enon Bileşiklerinin 2-Diazo-5,5-Dimetil-1,3-Sikloheksandion ile Rh2(OAc)4-Katalizli Tepkimeleri

Öz

Anahtar Kelimeler

Destekleyen Kurum

Proje Numarası

Etik Beyan

Teşekkür

Rh2(OAc)4-Catalyzed Reactions of α,β-Conjugated Enon Compounds with 2-Diazo-5,5-Dimethyl-1,3-Cyclohexandione

Öz

Anahtar Kelimeler

Proje Numarası

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