Doğal Adsorbent Kullanarak Sulardan Maxilon Golden Yellow’un Renk Gideriminde Ortam Koşullarının İncelenmesi

Yıl 2021, , 144 - 160, 15.06.2021

Ezgi Güneş Gürdal , Erkan Kalıpcı

https://doi.org/10.31466/kfbd.895685

Öz

Bu çalışmada; Maxilon Golden Yellow GL EC 400% (MGY-GE) boyasının Nevsehir (Türkiye) Cin Deresi dere yatağına ait doğal kil (DK) ile sulu çözeltilerden gideriminde ortam koşulları araştırılmıştır. Adsorpsiyon koşulları; MGY-GE boyasının 100 mg/L konsantrasyonunda, 2.0 g adsorbent kullanılarak, farklı temas süresi, çözelti pH’ı ve sıcaklığında incelenmiştir. Adsorpsiyon sürecinin Langmuir ve Freundlich izotermlerine uygunlukları araştırılmıştır. MGY-GE boyası gideriminde kullanılan DK için deneysel verilerin Langmuir izoterm modeline uyum gösterdiği bulunmuştur. Doğal kil için en yüksek renk giderimi; pH 8’de (%98.44) 300 dakika ve 25 oC'de elde edilmiştir. Sonuç olarak; doğal kilin MGY-GE boyasının sulu çözeltiden gideriminde kulanılabileceği ve bu doğal kilin yüksek tutma kapasitesine sahip olduğu belirlenmiştir. Düşük maliyetli ve bol miktarda bulunan doğal kil, MGY-GE boyasının giderimi için diğer adsorbentlere tercihen kullanılabilir.

Anahtar Kelimeler

Doğal kil, Maxilon golden yellow, Renk giderimi, Adsorpsiyon

Examination of Ambient Conditions of Maxilon Golden Yellow for Color Removal From Waters by Using Natural Adsorbent

Öz

In this study, ambient conditions for removal of Maxilon Golden Yellow GL EC 400% (MGY-GE) dye from aqueous solutions by using natural clay (NC) of Nevsehir (Turkey) Cin stream bed were investigated.Adsorption conditions were examined at 100 mg/L concentration of MGY-GE dye using 2.0 g adsorbent, different contact time, solution pH and temperature.The fitting of adsorption process with respect to Langmuir and Freundlich isotherms was examined. Experimental data for NC used in MGY-GE dye removal has been found to adapt to the Langmuir isotherm model.The highest color removal was obtained during 300 minutes and 25 oC at pH 8 (98.44%) for natural clay. As a result; it was indicated that natural clay can be used for the removal from aqueous solution of MGY-GE dye has high adsorption capacity for dye. Abundantly in nature and low-cost clay can be used for the removal of MGY-GE dye in preference to other adsorbents.

Anahtar Kelimeler

Natural clay, Maxilon golden yellow, Color removal, Adsorption

Kaynakça

• Adeyemo, A.A., Adeoye, I.O., Bello, O.S. (2017). Adsorption of Dyes Using Different Types of Clay: A Review. Applied Water Science.7:543-568.
• Doğan, M., Karaoğlu, M. H., Alkan, M. (2009). Adsorption Kinetics of Maxilon Yellow 4GL and Maxilon Red GRL Dyes on Kaolinite. J. Hazard. Mater., 165(1-3):1142-51.
• Dogan, M., Alkan, M. (2010).Adsorption Kinetics of Methyl Violet Onto Perlite. Chemosphere, 50:517-528.
• Elmoubarki, R., Mahjoubi, F.Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., Albani, A. El, Barka, N. (2015). Adsorption Of Textile Dyes On Raw And Decanted Moroccan Clays: Kinetics, Equilibrium And Thermodynamics. Water Resources and Industry.9:16–29.
• Freundlich, H.M.F. (1906). Over the adsorption in solution, J. Phys. Chem.57:385-471.
• Fytıanos, K., Voudrıas, E., Kokkalıs, E. (2000). Sorption-Desorption Behaviour of 2,4-Dichlorophenol by Marine Sediments. Chemosphere.40(1): 3-6.
• Gürses, A., Yalcın, M., Dogar, C. (2002). Electrocoagulation of Some Reactive Dyes: A Statistical Investigation Of Some Electrochemical Variables. Waste Management. 22:491-499.
• Gupta, V.K., Suhas, T.L. (2009). Application of Lowcost Adsorbents For Dye Removal-A Review. Journal of Environmental Management. 90:2313-2342.
• Gok, O., Ozcan, A.S., Ozcan, A.(2010).Adsorption Behavior of A Textile Dye of Reactive Blue 19 From Aqueous Solutions Onto Modified Bentonite. Appl. Surf. Sci. 256:5439–5443.
• Juang, R.S.,Wu, F.C., Tseng, R.L. (1997). The Ability of Activated Clay For The Adsorption of Dyes From Aqueous Solutions. Environmental Technology.18:525-531.
• Kadhom, M., Albayati, N., Alalwan, H., & Al-Furaiji, M. (2020). Removal of Dyes By Agricultural Waste. Sustainable Chemistry and Pharmacy, 16: 100259.
• Kayacan, S.(2007). Removal of Dye Materials From Aqueous Solutions by Adsorption on Coals and Cokes, Yüksek Lisans Tezi, Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Ankara.
• Kalıpcı, E., Sahinkaya, S., Dortkol, M., Aras, S. (2016). Decolorization of Basic Textile Dyes Using A Novel Adsorbent Modification Method: Ultrasonic-Acid Modification. International Journal of Environmental Research. 10(1):31-40.
• Kalıpcı, E. (2016). Removal of Methylene Blue From Aqueous Solution by Natural Olive Pomace Modified with Ultrasounds and Acid. Environment Protection Engineering. 42(3):5-17.
• Kalıpcı, E. (2019). Adsorption of Cadmium (II) By Using Clays Modified With Ultrasound. International Journal of Global Warming.18(2):155-172.
• Kaykıoğlu, G., Güneş, E. (2014). Pirinç Kabuğu Kullanılarak Üretilen Manyetik Nanopartiküller İle Sulu Çözeltilerden Renk Giderimi, NKUBAP.00.17.AR.12.07 Nolu BAP Projesi, Namık Kemal Üniversitesi, 1-55.
• Kuleyin, A., Aydin, F. (2011). Removal of Reactive Textile Dyes (Remazol Brillant Blue R And Remazol Yellow) by Surfactant‐Modified Natural Zeolite. Environmental Progress & Sustainable Energy. 30(2):141-151.
• Li, P., Gao, B., Li, A.,Yang, H. (2020). Evaluation of The Selective Adsorption of Silica-Sand/Anionized-Starch Composite For Removal of Dyes and Cupper (II) From Their Aqueous Mixtures. International journal of Biological Macromolecules. 149: 1285-1293.
• Mingfei, Z., Peng, L.(2009).Adsorption of Methylene Blue From Aqueous Solutions by Modified Expanded Graphite Powder. Desalination, 249 (1):331-336, 2009.
• Ngulube, T., Gumbo, J.R., Masindi, V., Maity, A. (2017). An Update On Synthetic Dyes Adsorption Onto Clay Based Minerals: A State-Of-Art Review. Journal of Environmental Management. 191:35-57.
• Ouardi, M. El, Qourzal, S., Alahiane, S., Assabbane, A., Douch, J., (2015). Effective Removal of Nitrates Ions from Aqueous Solution Using New Clay as Potential Low-Cost Adsorbent. Journal of Encapsulation and Adsorption Sciences.5(4):178-190.
• Öden, M., Küçükçongar, S. (2017). Removal of Dyes from Wastewater by Adsorption Using Modified Boron Enrichment Waste: Thermodynamic Criteria. Eurasian Journal of Environmental Research. 1(1):12-18.
• Sun, Q., Yang, L. (2003).The Adsorption of Basic Dyes From Aqueous Solution on Modified Peat-Resin Particle. Water Research. 37:1535-1544.
• Tara, N., Siddiqui, S. I., Rathi, G., Chaudhry, S. A., Asiri, A. M. (2020). Nano-Engineered Adsorbent For The Removal of Dyes From Water: A Review. Current Analytical Chemistry. 16(1):14-40.
• Uyar, G. (2012). A Low-Cost Adsorbent For Dye Removal:Methylene Blue Removal By Alginate-Montmorillonite Hybride Beads. Yüksek Lisans Tezi, İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü.
• Uysal, Y., Kereci, F.N. (2016).Tekstil Atık Külü İle Tekstil Atıksuyundan Renk Giderimi. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 19(3):82-86.
• URL-1:https://pubchem.ncbi.nlm.nih.gov/compound/Basic-Yellow-28, (Erişim Tarihi: 09 Mart 2021).
• URL-2:http://www.rsc.org/suppdata/c5/ra/c5ra13004b/c5ra13004b1.pdf,2015.,(Erişim Tarihi:12 Mart 2018).
• Weber, W., Dıgıano, F. (1996). Process Dynamics in Environmental Systems. Wiley, 1st Ed.:New York, USA.
• Wu, J., Yang, J., Feng, P., Huang, G., Xu, C., Lin, B. (2020). High-Efficiency Removal Of Dyes From Wastewater By Fully Recycling Litchi Peel Biochar. Chemosphere, 246:125734.
• Xia, L., Zhou, S., Zhang, C., Fu, Z., Wang, A., Zhang, Q., ... & Xu, W. (2020). Environment-Friendly Juncus Effusus-Based Adsorbent With A Three-Dimensional Network Structure For Highly Efficient Removal of Dyes From Wastewater. Journal of Cleaner Production, 259, 120812.