TiO2 Nanoparçacık Kaplı Pamuklu Kumaşın Fotokatalitik ve Antibakteriyel Özelliklerinin İncelenmesi

Yıl 2022, Cilt: 12 Sayı: 2, 1017 - 1031, 15.12.2022

Agah Oktay Özdemir , Mehmet Kuzucu , Eda Kelesguner , Bilge Doğan , Bülent Çağlar

https://doi.org/10.31466/kfbd.1183521

Öz

Bu çalışmada, fotokatalitik ve antibakteriyel özelliklere sahip, TiCl4'ün hidroliziyle sentezlenen farklı miktarlarda TiO2 nanoparçacıklar ile yüzey modifiye edilmiş pamuklu kumaşlar hazırlandı. Hazırlanan bu TiO2 nanoparçacıkları kaplı pamuklu kumaşların fotokatalitik aktiviteleri UVA ışınları altında Kristal Viyolet (KV) boyar maddesinin bozunmasında incelendi. KV’nin, TiO2 nanoparçacıkları kaplı pamuklu kumaşlar üzerindeki fotokatalitik bozunması için en uygun şartlar 0,625 mgL-1 başlangıç KV konsantrasyonu ve 57 mgL-1 TiO2 nanoparçacık yükleme miktarı olarak belirlendi. Bu en uygun şartlar altında, ilgili fotokatalizör varlığında 40 dakika içerisinde UVA ışınları altında KV’nin % 89,31’inin bozunmaya uğradığı tespit edildi ve bozunma reaksiyonunun birinci dereceden kinetiği takip ettiği belirlendi. Reaktif tür deneyleri, hidroksil radikallerinin diğer radikal türlere nispeten daha önemli bir rol oynadığını ortaya çıkardı ve elde edilen bu verilere göre olası bozunma mekanizması önerildi. Ayrıca TiO2 kaplanmış pamuklu kumaşların antibakteriyel aktivitesinin incelenmesi için disk difüzyon metodu kullanıldı. Antibakteriyel aktivite tayininde Gram pozitif bakteri olarak Staphylococcus aureus (ATCC 6538), Gram negatif bakteri olarak Escherichia coli (ATCC 25922) üzerinde denemeler gerçekleştirildi. Disk difüzyon deneyi sonuçlarına göre; 38 ve 57 mgL-1 konsantrasyonlarında TiO2 ile kaplanmış pamuklu kumaşlarda, antibiyotik referansların oluşturduğu inhibisyon zonu çapına kıyasla relatif olarak E. coli’ye karşı sırasıyla % 40,9 ve % 60,2 oranlarında antibakteriyel etki görülmüştür. 

Anahtar Kelimeler

TiO2 nanoparçacık, Pamuklu kumaşlar, Fotokatalitik aktivite, Antibakteriyel, TiO2 nanoparticles, Cotton fabrics, Photocatalytic activity, Antibacterial

Destekleyen Kurum

Erzincan Binali Yıldırım Üniversitesi Bilimsel Araştırmalar Birimi

Proje Numarası

FBA-2020-699

Teşekkür

Bu çalışma, Erzincan Binali Yıldırım Üniversitesi Bilimsel Araştırmalar Birimi tarafından FBA-2020-699 kodlu proje ile desteklenmiştir. Finansal desteklerinden dolayı Erzincan Binali Yıldırım Üniversitesi Bilimsel Araştırmalar Birimi’ne teşekkür ederim.

Investigation of Photocatalytic and Antibacterial Properties of TiO2 Nanoparticules Coated Cotton Fabric

Öz

In this study, surface modified cotton fabrics were prepared with different amounts of TiO2 nanoparticles which has photocatalytic and antibacterial properties, synthesized by hydrolysis of TiCl4. The photocatalytic activities of the prepared cotton fabrics with coated TiO2 nanoparticles were investigated in the degradation of the Crystal Violet (KV) dyestuff under UV light irradiation. The TiO2 coated cotton fabric showed good photocatalytic performance for the degradation of Crystal Violet (KV) under UV light irradiation. The optimum conditions for photocatalytic degradation of KV on TiO2 nanoparticles coated cotton fabrics were determined as 0.625 mgL-1 initial KV concentration and 57 mgL-1 TiO2 nanoparticle loading amount. Under these optimum conditions, it was determined that 89.31% of the KV was decomposed under UV light irradiation within 40 minutes in the presence of the relevant photocatalyst, and it was determined that the degradation reaction followed first-order kinetics. Reactive species experiments revealed that hydroxyl radicals play a more important role than other radical species, and according to the results, possible degradation mechanism was suggested. In addition, disc diffusion method was used to examine the antibacterial activity of TiO2 coated cotton fabrics. Trials were performed on Staphylococcus aureus (ATCC 6538) as Gram-positive bacteria and Escherichia coli (ATCC 25922) as Gram-negative bacteria in the determination of antibacterial activity. According to the results of disk diffusion experiment; In cotton fabrics coated with TiO2 at 38 and 57 mgL-1 concentrations, approximately 40.9% and 60.2% antibacterial activity was observed against E. coli, respectively, compared to the diameter of the inhibition zone formed by the antibiotic references.

Anahtar Kelimeler

TiO2 nanoparticles, Cotton fabrics, Photocatalytic activity, Antibacterial

Proje Numarası

FBA-2020-699

Kaynakça

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