Typha latifolia ile Sulu Çözeltiden Kristal Viyole Boyasının Adsorpsiyonu; Doğrusal ve Doğrusal Olmayan İzoterm, Kinetik ve Dizayn

Yıl 2024, Cilt: 14 Sayı: 4, 2227 - 2243, 15.12.2024

Dilek Gümüş , Fatih Gümüş

https://doi.org/10.31466/kfbd.1548851

Öz

Boyalar dünya çapında pek çok sektörde yaygın olarak kullanılmaktadır. Boya ile kirlenmiş atıksular hem su kaynakları hem de canlı yaşamı için tehdit oluşturan önemli bir kirlilik unsurudur. Bu nedenle boyalı atıksuların çevreye deşarj edilmeden önce arıtılmaları gerekmektedir. Adsorpsiyon teknolojisi, boyaların gideriminde etkin olarak kullanılan sistemlerden biridir. Sistemin verimliliği ve maliyeti kullanılan adsorbentle yakından ilişkilidir. Çalışma kapsamında sulak alanlarda bol miktarda bulunan bir su bitkisinin (Typha latifolia) modifiye edilerek sulu çözeltiden Kristal Viyole giderimi için verimli bir adsorbent olarak değerlendirilebilirliği araştırılmıştır. Modifikasyon ajanı olarak SDS (sodyum dodesil sülfonat) kullanılmıştır. Adsorbentin pHpzc (sıfır yük noktası) değeri belirlenmiştir. Çalışmalarda 0,5-2 g/L aralığında değişen miktarlarda adsorbent dozajı, 5-20 mg/L aralığında boya konsantrasyonu, 5-8 aralığında pH değeri ve 0-360 dk aralığında temas süresi gibi temel işletme parametreleri araştırılmıştır. Optimum parametreler; pH 8, adsorbent dozajı:0,5 g/L, adsorpsiyon süresi: 240 dakika olarak belirlenmiştir. Çalışma kapsamında 3 farklı İzoterm (Langmuir, Freundlich ve Temkin) modelin doğrusal ve doğrusal olmayan model verileri karşılaştırılmıştır. Temkin izoterm modeli adsorpsiyon sürecini hem doğrusal hem de doğrusal olmayan model denklemleriyle en küçük hata fonksiyonlarını üreterek en iyi şekilde açıklamıştır. Ayrıca, boyalı atıksu için en uyumlu izoterm modele dayalı tek aşamalı bir reaktör sistemi de sunulmuştur. Kinetik model verileri sözde ikinci derece kinetik model çalışma sonuçlarıyla uyumlu bulunmuştur. Yüzey aktif maddeyle modifiye edilerek hazırlanan adsorbentin boyalı atıksuların arıtımında başarılı bir performans sergileyeceği sonucuna varılmıştır.

Anahtar Kelimeler

Adsorpsiyon, Kristal Viyole, modifikasyon, Typha latifolia

Removal of Crystal Violet Dye from Aqueous Solution by a Modified Adsorbent; Optimum Isotherm with Linear and Nonlinear Model Equations, Kinetic and Design

Öz

Dyes are widely used in many industries worldwide. Wastewater contaminated with dyes is an important source of pollution that poses a threat to both water resources and living life. Therefore, dyed wastewater must be treated before being discharged into the environment. Adsorption technology is one of the systems used effectively in the removal of dyes. The efficiency and cost of the system are closely related to the adsorbent used. In this study, an aquatic plant (Typha latifolia), abundantly found in ditches, swamps and wetlands, was modified and its evaluation as an efficient adsorbent for the removal of Crystal Violet from aqueous solution was investigated. SDS (sodium dodecyl sulfonate) was used as modification agent. The pHpzc (zero charge point) value of the adsorbent was determined. Basic operating parameters such as adsorbent dosage in the range of 0.5-2 g/L, dye concentration in the range of 5-20 mg/L, pH value in the range of 5-8 and contact time in the range of 0-360 min were investigated. The optimum parameters were determined as pH 8, adsorbent dosage: 0.5 g/L, adsorption time: 240 minutes. Linear and nonlinear model data of 3 different Isotherm (Langmuir, Freundlich and Temkin) models were compared. Temkin isotherm model explained the adsorption process in the best way by producing the smallest error functions with both linear and nonlinear model equations. A one-stage reactor system based on the best-fit isotherm model for dyed wastewater is also presented. The kinetic model data were in good agreement with the results of the pseudo-second-order model. It is concluded that the adsorbent prepared by modifying with surfactant will perform successfully in the treatment of dyed wastewater.

Anahtar Kelimeler

Adsorption, Crystal Violet, modification, Typha latifolia

Kaynakça

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