Yıl 2020, Cilt 59 , Sayı 1, Sayfalar 7 - 14 2020-03-01

TÜRK TERMİK SANTRALLERİNDEN İKİ FARKLI UÇUCU KÜL KULLANARAK ALKALİ YAKMA METODUYLA ZEOLİT SENTEZİ
ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS

Soner TOP [1] , Hüseyin VAPUR [2]


Bu çalışmada, Sugözü termik santrali uçucu küllerinden sonrasında su liçi ile desteklenen bazik füzyon tekniği kullanılarak fojasit (Na-LSX) (3.5(Ca0.3)3.5(Na0.6)3.5(Mg0.1)Al7Si17O48•32(H2O)) türü, Çatalağzı uçucu küllerinden ise aynı tekniği kullanarak Ca-Filipsit (CaK0.6Na0.4Si5.2Al2.8O16•6(H2O)) türü zeolitler sentezlenmiştir. Bu yöntemlerde öncelikle yüksek sıcaklıkta kül fırınında uçucu küller ve sodyum hidroksit (NaOH) belirli oranlarda karıştırılarak 600 °C’de sinterlenmiş sonrasında öğütülen malzemelerden saf suda liç işlemi ile zeolitler elde edilmiştir. Katyon Değiştirme Kapasitesi (KDK), X-Işını Kırınımı (XRD), Taramalı Elektron Mikroskobu (SEM), Fourier Dönüşümlü Kızılötesi Spektroskopisi (FTIR), X-Işını Fluoresans (XRF) ve Atomik Adsorpsiyon Spektrometresi (AAS) analizleri ile sentezlenen zeolitler karakterize edilmiştir. Sugözü uçucu külleri ile (1:2 oranda) sentezlenen zeolitler 136,93 meq/100 g KDK’ne sahipken aynı oranda Çatalağzı uçucu külleri ile sentezlenen zeolitlerin 247,88 meq/100 g KDK’ne sahip oldukları belirlenmiştir. Sonuç olarak F sınıfı 2 ayrı uçucu kül kullanarak atıksu arıtıcı, enerji depolayıcı, katalist ve separator olarak kullanılabilecek zeolitler sentezlenmiştir.
In this study, Faujasite (Na-LSX) (3.5(Ca0.3)3.5(Na0.6)3.5(Mg0.1)Al7Si17O48•32(H2O)) type zeolites and Ca-Filipsite (CaK0.6Na0.4Si5.2Al2.8O16•6(H2O)) type zeolites were produced from Sugözü Thermal Power Plant and Çatalağzı Thermal Power Plant fly ashes by alkali fusion method followed by water leaching, respectively. In these methods, fly ashes and sodium hydroxide (NaOH) were mixed in certain proportions and sintered at 600 °C in ash furnace. Then, zeolites were obtained from the ground materials after water leaching and solid/liquid separation, respectively. Cation Exchange Capacity (CEC), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier-Transform Infrared Spectroscopy (FTIR), X-Ray Fluorescence (XRF) and Atomic Absorption Spectrometer (AAS) analyses were used to characterize the synthesized zeolites. The zeolites synthesized with Sugözü fly ashes in a ratio of 1:2 had 136.93 meq/100 g CEC, whereas the CEC of synthesized zeolite from Çatalağzı fly ashes was found to be 247.88 meq/100 g. As a result, zeolites, which can be used as wastewater treatment agent, energy storage material, catalyst and separator, were synthesized by using 2 different Class F fly ash.
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Birincil Dil en
Konular Mühendislik, Ortak Disiplinler
Bölüm Araştırma Makalesi
Yazarlar

Orcid: 0000-0003-3486-4184
Yazar: Soner TOP (Sorumlu Yazar)
Kurum: ABDULLAH GÜL ÜNİVERSİTESİ
Ülke: Turkey


Orcid: 0000-0003-4438-3982
Yazar: Hüseyin VAPUR
Kurum: MÜHENDİSLİK FAKÜLTESİ
Ülke: Turkey


Tarihler

Yayımlanma Tarihi : 1 Mart 2020

Bibtex @araştırma makalesi { madencilik705486, journal = {Bilimsel Madencilik Dergisi}, issn = {2564-7024}, address = {Selanik Cad. No: 19/4 06650 Kızılay-Çankaya / ANKARA - TURKEY}, publisher = {TMMOB Maden Mühendisleri Odası}, year = {2020}, volume = {59}, pages = {7 - 14}, doi = {10.30797/madencilik.705486}, title = {ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS}, key = {cite}, author = {TOP, Soner and VAPUR, Hüseyin} }
APA TOP, S , VAPUR, H . (2020). ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS. Bilimsel Madencilik Dergisi , 59 (1) , 7-14 . DOI: 10.30797/madencilik.705486
MLA TOP, S , VAPUR, H . "ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS". Bilimsel Madencilik Dergisi 59 (2020 ): 7-14 <https://dergipark.org.tr/tr/pub/madencilik/issue/53216/705486>
Chicago TOP, S , VAPUR, H . "ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS". Bilimsel Madencilik Dergisi 59 (2020 ): 7-14
RIS TY - JOUR T1 - ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS AU - Soner TOP , Hüseyin VAPUR Y1 - 2020 PY - 2020 N1 - doi: 10.30797/madencilik.705486 DO - 10.30797/madencilik.705486 T2 - Bilimsel Madencilik Dergisi JF - Journal JO - JOR SP - 7 EP - 14 VL - 59 IS - 1 SN - 2564-7024- M3 - doi: 10.30797/madencilik.705486 UR - https://doi.org/10.30797/madencilik.705486 Y2 - 2019 ER -
EndNote %0 Bilimsel Madencilik Dergisi ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS %A Soner TOP , Hüseyin VAPUR %T ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS %D 2020 %J Bilimsel Madencilik Dergisi %P 2564-7024- %V 59 %N 1 %R doi: 10.30797/madencilik.705486 %U 10.30797/madencilik.705486
ISNAD TOP, Soner , VAPUR, Hüseyin . "ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS". Bilimsel Madencilik Dergisi 59 / 1 (Mart 2020): 7-14 . https://doi.org/10.30797/madencilik.705486
AMA TOP S , VAPUR H . ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS. Madencilik. 2020; 59(1): 7-14.
Vancouver TOP S , VAPUR H . ZEOLITE SYNTHESIS BY ALKALI FUSION METHOD USING TWO DIFFERENT FLY ASHES DERIVED FROM TURKISH THERMAL POWER PLANTS. Bilimsel Madencilik Dergisi. 2020; 59(1): 14-7.