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Applications of Double Layered Hydroxides in Cosmetics

Yıl 2022, , 417 - 422, 31.12.2022
https://doi.org/10.29048/makufebed.1151182

Öz

Since ancient Egypt cosmetics have been a part of our life. Cosmetic products appeal to a large variety of areas ranging from perfume, hair dyes and care products, toothpastes, dermal care products, face-eye make-up materials. Cosmetic products contain biological active components. These active compounds generally are sensitive to parameters such as light, pH, temperature and air oxidation and they are not stable. This also causes unwanted possibilities such as degradation of cosmetic products. Layered double hydroxides (LDHs), which are two-dimensional (2D) nanostructures, due to their extraordinary physicochemical properties may be a good alternative for to overcome these drawbacks. LDHs have found wide application areas such as removal of heavy metals, radio nucleotides, organic pollutants, oil pollution, hydrogen production and they are used in super capacitors, cells, solar cells, catalysis and in biomaterials for environmental, energy and catalysis. Moreover, nanostructured LDHs have been used as successful carriers for cosmetic products due to their wide surface areas, expandable interlayers that can host active molecules, biocompatibility, high water retention capacity, high swelling ability and cost-effectiveness. This study provides good practices of LDHs in cosmetics for UV protection, skin care and antimicrobial properties.

Kaynakça

  • Ammala, A. (2013). Biodegradable polymers as encapsulation materials for cosmetics and personal care markets. International Journal of Cosmetic Science, 35(2): 113-124.
  • Ballarin, B., Mignani, A., Mogavero, F., Gabbanini, S., Morigi, M. (2015). Hybrid material based on ZnAl hydrotalcite and silver nanoparticles for deodorant formulation. Applied Clay Science, 114: 303-308.
  • Bastianini, M., Faffa, C., Sisani, M., Petracci, A. (2018). Caffeic acid-layered double hydroxide hybrid: a new raw material for cosmetic applications. Cosmetics, 5(3): 51; DOI:10.3390/COSMETICS5030051.
  • Borowska, S., Brzóska, M. M. (2015). Metals in cosmetics: implications for human health. Journal of Applied Toxicology, 35(6): 551-572.
  • Choy, J. H., Choi, S. J., Oh, J. M., Park, T. (2007). Clay minerals and layered double hydroxides for novel biological applications. Applied Clay Science, 36(1-3): 122-132.
  • Conterosito, E., Palin, L., Antonioli, D., Viterbo, D., Mugnaioli, E., Kolb, U., Gianotti, V. (2015). Structural Characterisation of Complex Layered Double Hydroxides and TGA‐GC‐MS Study on Thermal Response and Carbonate Contamination in Nitrate‐and Organic‐Exchanged Hydrotalcites. Chemistry–A European Journal, 21(42): 14975-14986.
  • Cursino, A. C. T., da Silva Lisboa, F., dos Santos Pyrrho, A., de Sousa, V. P., Wypych, F. (2013). Layered double hydroxides intercalated with anionic surfactants/benzophenone as potential materials for sunscreens. Journal of Colloid and Interface Science, 397: 88-95.
  • Gao, X., Chen, L., Xie, J., Yin, Y., Chang, T., Duan, Y., Jiang, N. (2014). In vitro controlled release of vitamin C from Ca/Al layered double hydroxide drug delivery system. Materials Science and Engineering: C, 3: 56-60.
  • Gasser, M. S. (2009). Inorganic layered double hydroxides as ascorbic acid (vitamin C) delivery system-Intercalation and their controlled release properties. Colloids and Surfaces B: Biointerfaces, 73(1): 103–109.
  • He, Q., Yin, S., Sato, T. (2004). Synthesis and photochemical properties of zinc–aluminum layered double hydroxide/organic UV ray absorbing molecule/silica nanocomposites. Journal of Physics and Chemistry of Solids, 65(2-3): 395-402.
  • Kesavan Pillai, S., Kleyi, P., de Beer, M., Mudaly, P. (2020). Layered double hydroxides: An advanced encapsulation and delivery system for cosmetic ingredients-an overview. Applied Clay Science, 199(5): 105868; DOI:10.1016/j.clay.2020.105868.
  • Khan, S. B., Liu, C., Jang, E. S., Akhtar, K., Han, H. (2011). Encapsulation of organic UV ray absorbents into layered double hydroxide for photochemical properties. Materials Letters, 65(19-20): 2923-2926.
  • Kovalenko, V., Kotok, V., Yeroshkina, A., Zaychuk, A. (2017). Synthesis and characterisation of dye-intercalated nickel-aluminium layered-double hydroxide as a cosmetic pigment. Восточно-Европейский журнал передовых технологий, 5(12): 27-33.
  • Li, S., Shen, Y., Xiao, M., Liu, D., Fa, L., Wu, K. (2014). Intercalation of 2,4-dihydroxybenzophenone-5-sulfonate anion into Zn/Al layered double hydroxides for UV absorption properties. Journal of Industrial and Engineering Chemistry, 20(4): 1280-1284.
  • Li, Y., Tang, L. P., Zhou, W., Wang, X. R. (2016). Fabrication of intercalated p-aminobenzoic acid into Zn-Ti layered double hydroxide and its application as UV absorbent. Chinese Chemical Letters, 27(9): 1495-1499.
  • Li, Y., Tang, L., Ma, X., Wang, X., Zhou, W., Bai, D. (2017). Synthesis and characterization of Zn-Ti layered double hydroxide intercalated with cinnamic acid for cosmetic application. Journal of Physics and Chemistry of Solids, 107: 62-67.
  • Marcato, P. D., Parizotto, N. V., Martinez, D. S. T., Paula, A. J., Ferreira, I. R., Melo, P. S., Alves, O. L. (2013). New hybrid material based on layered double hydroxides and biogenic silver nanoparticles: antimicrobial activity and cytotoxic effect. Journal of the Brazilian Chemical Society, 24: 266-272.
  • Mishra, G., Dash, B., Pandey, S. (2018). Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials. Applied Clay Science, 153: 172-186.
  • Mohsin, S. M. N., Hussein, M. Z., Sarijo, S. H., Fakurazi, S., Arulselvan, P., Taufiq-Yap, Y. H. (2014). Optimization of UV absorptivity of layered double hydroxide by intercalating organic UV-absorbent molecules. Journal of biomedical nanotechnology, 10(8): 1490-1500.
  • Mosangi, D., Moyo, L., Pillai, S. K., Ray, S. S. (2016). Acetyl salicylic acid–ZnAl layered double hydroxide functional nanohybrid for skin care application. RSC advances, 6(107): 105862-105870.
  • Özçelik, H., Bebekli, Ö. (2015). Cosmetics Industry Overview. Anamas Dergisi, 3(4): 3-12.
  • Pagano, C., Calarco, P., Ceccarini, M. R., Beccari, T., Ricci, M., Perioli, L. (2019). Development and characterization of new topical hydrogels based on alpha lipoic acid-Hydrotalcite hybrids. Cosmetics, 6(2): 35; DOI:10.3390/COSMETICS6020035.
  • Patel, H. A., Bajaj, H. C. (2010). Natural and synthetic layered materials as cosmetic ingredients. Focus on Aminoacids, Peptıdes Hı-Tech Ingredients, 4: 31-36.
  • Perera, J., Weerasekera, M., Kottegoda, N. (2015). Slow release anti-fungal skin formulations based on citric acid intercalated layered double hydroxides nanohybrids. Chemistry Central Journal, 9(1): 1-7; DOI:10.1186/s13065-015-0106-3.
  • Perioli, L., Ambrogi, V., Rossi, C., Latterini, L., Nocchetti, M., Costantino, U. (2006). Use of anionic clays for photoprotection and sunscreen photostability: hydrotalcites and phenylbenzimidazole sulfonic acid. Journal of Physics and Chemistry of Solids, 67(5-6): 1079-1083.
  • Perioli, L., Nocchetti, M., Ambrogi, V., Latterini, L., Rossi, C., Costantino, U. (2008). Sunscreen immobilization on ZnAl-hydrotalcite for new cosmetic formulations. Microporous and mesoporous materials, 107(1-2):180-189.
  • Perioli, L., Pagano, C., Nocchetti, M., Latterini, L. (2015). Development of smart semisolid formulations to enhance retinoic acid topical application. Journal of Pharmaceutical Sciences, 104(11): 3904-3912.
  • Silva, T. A. D., Silva, T. A. D., Nascimento, T. G. D., Yatsuzuka, R. E., Grillo, L. A. M., Dornelas, C.B. (2019). Recent advances in layered double hydroxides applied to photoprotection. Einstein (São Paulo), 17; DOI:10.31744/einstein_journal/2019RW4456.
  • Sun, W., He, Q., Luo, Y. (2007). Synthesis and properties of cinnamic acid series organic UV ray absorbents–interleaved layered double hydroxides. Materials Letters, 61(8-9): 1881-1884.
  • Sun, W., He, Q., Lu, L., Liu, H. (2008). Synthesis and properties of layered double hydroxides intercalated with cinnamic acid series organic UV ray absorbents. Materials chemistry and physics, 107(2-3): 261-265.
  • Tang, L. P., Cheng, H. M., Cui, S. M., Wang, X. R., Song, L. Y., Zhou, W., Li, S. J. (2018). DL-mandelic acid intercalated Zn-Al layered double hydroxide: A novel antimicrobial layered material. Colloids and Surfaces B: Biointerfaces, 165: 111-117.
  • URL-1 (2021). https://www.titck.gov.tr/faaliyetalanlari/kozmetik/kozmetik-mevzuati (Accessed Date: 08.06.2022)
  • Wang, X. R., Li, Y., Tang, L. P., Gan, W., Zhou, W., Zhao, Y. F., Bai, D. S. (2017). Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti4+ and its application as UV absorbent. Chinese Chemical Letters, 28(2): 394-399.
  • Wang, X. R., Cheng, H. M., Gao, X. W., Zhou, W., Li, S. J., Cao, X. L., Yan, D. (2019). Intercalation assembly of kojic acid into Zn-Ti layered double hydroxide with antibacterial and whitening performances. Chinese Chemical Letters, 30(4): 919-923.

Çift Katmanlı Hidroksitlerin Kozmetikte Uygulamaları

Yıl 2022, , 417 - 422, 31.12.2022
https://doi.org/10.29048/makufebed.1151182

Öz

Yeryüzünde kozmetik kullanımı Mısırlılar zamanından günümüze kadar uzanmaktadır. Kozmetik ürünleri parfüm, saç boya ve bakım ürünleri, diş macunları, cilt bakım ürünleri, yüz-göz makyaj malzemeleri vs. şeklinde geniş bir alana hitap eder. Kozmetik ürünleri bünyesinde biyolojik aktif bileşenler bulundurur. Bu aktif bileşenler genellikle ışık, pH, sıcaklık ve havanın oksidasyonu gibi parametrelere karşı duyarlı olup stabil değildir. Bu durum kozmetik ürünlerinin bozulması gibi istenmeyen olasılıkları beraberinde getirir. Olağanüstü fizyokimyasal özellikleri sayesinde nanoyapılı iki boyutlu (2D) katmanlı çift hidroksitler (LDH’ler) bu olumsuzluklara bir çözüm alternatifidir. LDH’lerin özellikle ağır metal çıkarma, radyonüklid yakalama, organik kirletici arıtma, petrol kirliliğinin giderilmesi, hidrojen üretimi, süper kapasitörler, piller, güneş pilleri, kataliz ve biyomateryal dahil çevre, enerji, kataliz ve biyomateryaller ile ilgili çok çeşitli alanlarda uygulamaları mevcuttur. Ayrıca nanoyapılı LDH’ler; sahip oldukları geniş yüzey alanı, aktif molekülleri barındıracak genişleyebilir ara katmanı, biyouyumluluk özelliği, yüksek su tutma kapasitesi, şişme özellikleri ve düşük maliyetleri nedeniyle kozmetik taşıyıcılar olarak kullanılır. Bu çalışmada LDH’lerin kozmetik amaçlı (UV koruması, cilt bakımı ve antimikrobiyal özellikler gibi) uygulamalarından örneklemeler yapılacaktır.

Kaynakça

  • Ammala, A. (2013). Biodegradable polymers as encapsulation materials for cosmetics and personal care markets. International Journal of Cosmetic Science, 35(2): 113-124.
  • Ballarin, B., Mignani, A., Mogavero, F., Gabbanini, S., Morigi, M. (2015). Hybrid material based on ZnAl hydrotalcite and silver nanoparticles for deodorant formulation. Applied Clay Science, 114: 303-308.
  • Bastianini, M., Faffa, C., Sisani, M., Petracci, A. (2018). Caffeic acid-layered double hydroxide hybrid: a new raw material for cosmetic applications. Cosmetics, 5(3): 51; DOI:10.3390/COSMETICS5030051.
  • Borowska, S., Brzóska, M. M. (2015). Metals in cosmetics: implications for human health. Journal of Applied Toxicology, 35(6): 551-572.
  • Choy, J. H., Choi, S. J., Oh, J. M., Park, T. (2007). Clay minerals and layered double hydroxides for novel biological applications. Applied Clay Science, 36(1-3): 122-132.
  • Conterosito, E., Palin, L., Antonioli, D., Viterbo, D., Mugnaioli, E., Kolb, U., Gianotti, V. (2015). Structural Characterisation of Complex Layered Double Hydroxides and TGA‐GC‐MS Study on Thermal Response and Carbonate Contamination in Nitrate‐and Organic‐Exchanged Hydrotalcites. Chemistry–A European Journal, 21(42): 14975-14986.
  • Cursino, A. C. T., da Silva Lisboa, F., dos Santos Pyrrho, A., de Sousa, V. P., Wypych, F. (2013). Layered double hydroxides intercalated with anionic surfactants/benzophenone as potential materials for sunscreens. Journal of Colloid and Interface Science, 397: 88-95.
  • Gao, X., Chen, L., Xie, J., Yin, Y., Chang, T., Duan, Y., Jiang, N. (2014). In vitro controlled release of vitamin C from Ca/Al layered double hydroxide drug delivery system. Materials Science and Engineering: C, 3: 56-60.
  • Gasser, M. S. (2009). Inorganic layered double hydroxides as ascorbic acid (vitamin C) delivery system-Intercalation and their controlled release properties. Colloids and Surfaces B: Biointerfaces, 73(1): 103–109.
  • He, Q., Yin, S., Sato, T. (2004). Synthesis and photochemical properties of zinc–aluminum layered double hydroxide/organic UV ray absorbing molecule/silica nanocomposites. Journal of Physics and Chemistry of Solids, 65(2-3): 395-402.
  • Kesavan Pillai, S., Kleyi, P., de Beer, M., Mudaly, P. (2020). Layered double hydroxides: An advanced encapsulation and delivery system for cosmetic ingredients-an overview. Applied Clay Science, 199(5): 105868; DOI:10.1016/j.clay.2020.105868.
  • Khan, S. B., Liu, C., Jang, E. S., Akhtar, K., Han, H. (2011). Encapsulation of organic UV ray absorbents into layered double hydroxide for photochemical properties. Materials Letters, 65(19-20): 2923-2926.
  • Kovalenko, V., Kotok, V., Yeroshkina, A., Zaychuk, A. (2017). Synthesis and characterisation of dye-intercalated nickel-aluminium layered-double hydroxide as a cosmetic pigment. Восточно-Европейский журнал передовых технологий, 5(12): 27-33.
  • Li, S., Shen, Y., Xiao, M., Liu, D., Fa, L., Wu, K. (2014). Intercalation of 2,4-dihydroxybenzophenone-5-sulfonate anion into Zn/Al layered double hydroxides for UV absorption properties. Journal of Industrial and Engineering Chemistry, 20(4): 1280-1284.
  • Li, Y., Tang, L. P., Zhou, W., Wang, X. R. (2016). Fabrication of intercalated p-aminobenzoic acid into Zn-Ti layered double hydroxide and its application as UV absorbent. Chinese Chemical Letters, 27(9): 1495-1499.
  • Li, Y., Tang, L., Ma, X., Wang, X., Zhou, W., Bai, D. (2017). Synthesis and characterization of Zn-Ti layered double hydroxide intercalated with cinnamic acid for cosmetic application. Journal of Physics and Chemistry of Solids, 107: 62-67.
  • Marcato, P. D., Parizotto, N. V., Martinez, D. S. T., Paula, A. J., Ferreira, I. R., Melo, P. S., Alves, O. L. (2013). New hybrid material based on layered double hydroxides and biogenic silver nanoparticles: antimicrobial activity and cytotoxic effect. Journal of the Brazilian Chemical Society, 24: 266-272.
  • Mishra, G., Dash, B., Pandey, S. (2018). Layered double hydroxides: A brief review from fundamentals to application as evolving biomaterials. Applied Clay Science, 153: 172-186.
  • Mohsin, S. M. N., Hussein, M. Z., Sarijo, S. H., Fakurazi, S., Arulselvan, P., Taufiq-Yap, Y. H. (2014). Optimization of UV absorptivity of layered double hydroxide by intercalating organic UV-absorbent molecules. Journal of biomedical nanotechnology, 10(8): 1490-1500.
  • Mosangi, D., Moyo, L., Pillai, S. K., Ray, S. S. (2016). Acetyl salicylic acid–ZnAl layered double hydroxide functional nanohybrid for skin care application. RSC advances, 6(107): 105862-105870.
  • Özçelik, H., Bebekli, Ö. (2015). Cosmetics Industry Overview. Anamas Dergisi, 3(4): 3-12.
  • Pagano, C., Calarco, P., Ceccarini, M. R., Beccari, T., Ricci, M., Perioli, L. (2019). Development and characterization of new topical hydrogels based on alpha lipoic acid-Hydrotalcite hybrids. Cosmetics, 6(2): 35; DOI:10.3390/COSMETICS6020035.
  • Patel, H. A., Bajaj, H. C. (2010). Natural and synthetic layered materials as cosmetic ingredients. Focus on Aminoacids, Peptıdes Hı-Tech Ingredients, 4: 31-36.
  • Perera, J., Weerasekera, M., Kottegoda, N. (2015). Slow release anti-fungal skin formulations based on citric acid intercalated layered double hydroxides nanohybrids. Chemistry Central Journal, 9(1): 1-7; DOI:10.1186/s13065-015-0106-3.
  • Perioli, L., Ambrogi, V., Rossi, C., Latterini, L., Nocchetti, M., Costantino, U. (2006). Use of anionic clays for photoprotection and sunscreen photostability: hydrotalcites and phenylbenzimidazole sulfonic acid. Journal of Physics and Chemistry of Solids, 67(5-6): 1079-1083.
  • Perioli, L., Nocchetti, M., Ambrogi, V., Latterini, L., Rossi, C., Costantino, U. (2008). Sunscreen immobilization on ZnAl-hydrotalcite for new cosmetic formulations. Microporous and mesoporous materials, 107(1-2):180-189.
  • Perioli, L., Pagano, C., Nocchetti, M., Latterini, L. (2015). Development of smart semisolid formulations to enhance retinoic acid topical application. Journal of Pharmaceutical Sciences, 104(11): 3904-3912.
  • Silva, T. A. D., Silva, T. A. D., Nascimento, T. G. D., Yatsuzuka, R. E., Grillo, L. A. M., Dornelas, C.B. (2019). Recent advances in layered double hydroxides applied to photoprotection. Einstein (São Paulo), 17; DOI:10.31744/einstein_journal/2019RW4456.
  • Sun, W., He, Q., Luo, Y. (2007). Synthesis and properties of cinnamic acid series organic UV ray absorbents–interleaved layered double hydroxides. Materials Letters, 61(8-9): 1881-1884.
  • Sun, W., He, Q., Lu, L., Liu, H. (2008). Synthesis and properties of layered double hydroxides intercalated with cinnamic acid series organic UV ray absorbents. Materials chemistry and physics, 107(2-3): 261-265.
  • Tang, L. P., Cheng, H. M., Cui, S. M., Wang, X. R., Song, L. Y., Zhou, W., Li, S. J. (2018). DL-mandelic acid intercalated Zn-Al layered double hydroxide: A novel antimicrobial layered material. Colloids and Surfaces B: Biointerfaces, 165: 111-117.
  • URL-1 (2021). https://www.titck.gov.tr/faaliyetalanlari/kozmetik/kozmetik-mevzuati (Accessed Date: 08.06.2022)
  • Wang, X. R., Li, Y., Tang, L. P., Gan, W., Zhou, W., Zhao, Y. F., Bai, D. S. (2017). Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti4+ and its application as UV absorbent. Chinese Chemical Letters, 28(2): 394-399.
  • Wang, X. R., Cheng, H. M., Gao, X. W., Zhou, W., Li, S. J., Cao, X. L., Yan, D. (2019). Intercalation assembly of kojic acid into Zn-Ti layered double hydroxide with antibacterial and whitening performances. Chinese Chemical Letters, 30(4): 919-923.
Toplam 34 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Derleme Makale
Yazarlar

Emine Kutlu 0000-0003-0211-1006

Fatih Emen 0000-0002-4974-2940

Ruken Esra Demirdöğen 0000-0003-1274-7905

Yayımlanma Tarihi 31 Aralık 2022
Kabul Tarihi 12 Kasım 2022
Yayımlandığı Sayı Yıl 2022

Kaynak Göster

APA Kutlu, E., Emen, F., & Demirdöğen, R. E. (2022). Applications of Double Layered Hydroxides in Cosmetics. Mehmet Akif Ersoy Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 13(Ek (Suppl.) 1), 417-422. https://doi.org/10.29048/makufebed.1151182