Su Arıtımı İçin Deniz Kaynaklı Adsorpsiyon Biyomalzemeleri: Fonksiyonel Balık Kemiği Adsorbanları Kullanılarak Tekstil Boyası Gideriminin Verimliliği ve Kinetiği

Yıl 2025, Cilt: 7 Sayı: 2, 46 - 55

Bayram Kızılkaya

https://doi.org/10.51756/marlife.1745123

Öz

Bu çalışma, endüstriyel atık sularda yaygın olarak bulunan toksik boyar maddelerin gideriminde düşük maliyetli, çevre dostu ve biyolojik kökenli bir adsorban alternatifi sunmaktadır. Balık kemiği gibi atıkların modifikasyonu, sürdürülebilir kaynak kullanımına katkı sağlarken, tekstil, gıda ve kimya endüstrilerinden kaynaklanan boyar madde kirliliğinin azaltılmasında etkin sonuçlar vermektedir. Kinetik ve difüzyon modelleriyle desteklenen adsorpsiyon mekanizması analizleri, bu tür malzemelerin tasarım ve optimizasyonu için önemli veriler sağlamaktadır. Balık kemiği partiküllerinin yüzey modifikasyonu iki aşamalı olarak gerçekleştirilmiş; ilk aşamada, kemik partikülleri (H) 3-aminopropil-trietoksisilan (S) ile silanizasyon işlemi uygulanarak HS ürünü elde edilmiş, ikinci aşamada ise aldehit (2-Ethyl-2H-pyrazole-3-carbaldehyde, A) fonksiyonel grubunun yüzeye bağlanmasıyla HSA formu oluşturulmuştur. Adsorpsiyon deneyleri, farklı başlangıç konsantrasyonlarında (6.76, 3.38, 1.69 ve 0.676 mg/L) fuksin çözeltisi kullanılarak yürütülmüş ve adsorpsiyon kapasitesi (q_e), giderim verimi (%) ile kinetik parametreler detaylı olarak değerlendirilmiştir. Elde edilen sonuçlar, başlangıç konsantrasyonunun artmasıyla birlikte adsorpsiyon kapasitesinde (0.08–0.94 mg/g) belirgin bir artış gözlemlenirken, kinetik analizler, adsorpsiyon sürecinin Pseudo-second-order kinetik modele yüksek derecede uyum sağladığını ve kimyasal etkileşimlerin adsorpsiyonda baskın bir mekanizma olabileceğini göstermiştir.

Anahtar Kelimeler

Balık kılçığı , yüzey modifikasyonu , fuksin , adsorpsiyon , kinetik modelleme

Proje Numarası

TUBİTAK, Project number: 213M200

Marine-Derived Adsorption Biomaterials for Water Treatment: Efficiency and Kinetics of Textile Dye Removal Using Functionalized Fish Bone Adsorbents

Öz

This study offers a low-cost, environmentally friendly, and biologically derived adsorbent alternative for the removal of toxic dyes commonly found in industrial wastewater. The modification of waste materials such as fish bones contributes to sustainable resource utilization while achieving effective results in reducing dye pollution originating from the textile, food, and chemical industries. Adsorption mechanism analyses supported by kinetic and diffusion models provide valuable insights for the design and optimization of such materials. The surface modification of fish bone particles was carried out in two stages: in the first stage, silanizaion of bone particles (H) with 3-aminopopyltriethoysilane (S) was performed to obtain the HS product; in the second stage, the HSA form was created by binding an aldehyde functional group (2-Ethyl-2H-pyrazole-3-carbaldehyde, A) to the surface. Adsorption experiments were conducted using fuchsine solution at different initial concentrations (6.76, 3.38, 1.69, and 0.676), and adsorption capacity (qₑ), removal efficiency (%), and kinetic parameters were comprehensively evaluated. The results showed a noticeable increase in adsorption capacity (0.08–0.94 mg/g) with increasing initial concentration, while kinetic analyses indicated that the adsorption process followed the pseudo-second-order kinetic model with a high degree of correlation, suggesting that chemical interactions may play a dominant role in the adsorption mechanism.

Anahtar Kelimeler

Fish bone , surface modification , fuchsin , adsorption , kinetic modeling

Etik Beyan

For this type of study, formal consent is not required.

Destekleyen Kurum

TUBİTAK

Proje Numarası

TUBİTAK, Project number: 213M200

Kaynakça

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