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Yıl 2013, Cilt: 1 Sayı: 1, 27 - 37, 01.06.2013

Nevin TURAN Turan Zuhal Karagöz Naki Çolak Hanifi Körkoca Memet Şekerci

Öz

The new Pb(II), UO2(II), Cu(II), Ni(II), Co(II) and Zn(II) complexes were synthesized with the ligand containing the diazenyl group 4-[(dicyanomethyl)diazenyl]benzoic acid (L) which were prepared by the reaction of hydroxybenzaldehyde with 3-aminopropyltrimethoxysilane. The structure of the ligand and its complexes were determined by using elemental analysis, UV-visible, IR, H-NMR, 13C-NMR, TGA, DTA and magnetic measurements. The Co(II) and Ni(II) complexes are paramagnetic with octahedral structure; the Zn(II) complex is diamagnetic with octahedral structure; the Cu(II) complex is paramagnetic and have square planar structure; UO2(II) and Pb(II) complexes are diamagnetic and have square planar structure. All of the complexes were tested for their antibacterial activities against Escherichia coli ATCC-25922, Enterococcus faecalis ATCC 29212, Staphylococcus aureus ATCC 25923 and Salmonella typhimurium CCM 583. The test results were also evaluated. It was found that only Ni(II) and Zn(II) complexes are able to inhibit the growth of Staphylococcus aureus

Anahtar Kelimeler

Spectroscopy diazenyl; acetate salts; thermo gravimetric analysis; square planar; antibacterial activities

Kaynakça

  • Zollinger, H., Color Chemistry: Syntheses, Properties, and Applications of Organic Dyes and Pigments, Weinheim, Wiley-VCH, 2003.
  • Groselj, U., Bevk, D., Jakse, R., Meden, A., Stanovnik, B., and Svete, J., Tetrahedron: Asymmetr, 16, 2927-2945, 2005.
  • Ersanlı, C.C., Albayrak, Ç., Odabaşoğlu, M., Kazak, C., Erdönmez, A., Acta Cryst., 60, 455-457, 2004.
  • Calino, S.C., Farris, R.E., Azo Dyes in Kirk-Olhmer Cnnci.se Erieydopaedia of Chemical Technology, cdilcd by M. Grayson, New York, John Wiley and Sons, 1985.
  • Gregory, R., Ctylorunts for High Technology. Colour Chemistry: The Design and Synthesis of Organic Dyes anti Pigments. Edited by A. T. Peters & H. S. Freeman, London/New York, 1991.
  • Antonov, L., Kawauchi, S.M., Satoh, Komiyama, J., Dyes Pigments, 40, 163-170, 1999.
  • Nevin, T., Esin, K., Bayram, G., Naki, Ç., Hanifi, K., Fiber Polym., 13(4), 415-424, 2012.
  • Amer, A.M., El-Bermaui, M.A., Ahmed, A.F.S., Soliman, S.M., Monatsh. Chem., 130, 1409-1418, 1999.
  • Jignesh, P.R., Purvesh, R.P., Nilesh, H.P., Pradip, S.P., Vasishta, D.B., Ketul, N.P., Int.l J. ChemTech Res., 1(3), 610-615, 2009.
  • Racane, L., Tralić-Kulenović, V., Karminski-Zamola, G., Fišer-Jakić, L., Monatsh Chem., 126, 1375-1381, 1995.
  • Carubelli, C.R., Massabni, A.M.G., de A. Leite, S.R., J. Braz. Chem. Soc., 8, 597, 1997.
  • Sener, A., Kasimogullari, R., Sener, M.K., Genc, H., Chem. Heterocycl. Comp., 40(8), 1039-1046, 2004.
  • Maurya, R.C., Patel, P., Rajput, S., Synth. React. Inorg. Met-Org. Chem., 33(5), 37 801–816, 2003.
  • Raman, N., Dhaveethu Raja, J., Sakthivel, A., J. Chem. Sci., 119(4), 303-310, 2007.
  • Lv, Q-Y., Lei, W-J., Liu, Y-L., Zhan, S-Z., Ye, J-S., Polyhedron, 29, 2780-2786, 2010.
  • Masoud, M.S., Amira, M.F., Ramadan, A.M. and El-Ashry, G.M., Spectrochim. Acta A., 69(1), 230, 2008.
  • Mohamed, G.G., Sharaby, C.M., Spectrochim. Acta Part A: Mol Biomol Spectros., 65(4-5), 949, 2007.
  • Hu, F., Yın, X., Lu, J., Mi, Y., Zhuang, J., Luo, W.J., Coord. Chem., 63(2), 263, 2010.
  • Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York, pp. 232, 1970.
  • Maurya, R.C., Jayaswal, M.N., Verma, R., Synth. React. Inorg. Met.-Org. Chem. 28, 1265-1281, 1998.
  • Dey, K., Bhowmick, R., Biswas, S., Koner, D., Synth. React. Inorg. Met-Org. Nan- Met. Chem., 35, 285-294, 2005.
  • Jouad, E.M., Riou, A., Allain, M., Khan, M.A., Bouet, G.M., Polyhedron, 20, 67, 2001.
  • Tuncel, M., Serin, S., Synth. React. Inorg. Met-Org. Nan-Met. Chem., 35, 203-212, 2005.
  • Lever, A.B.P., Inorganic Electronic Spectroscopy, 2nd Ed., Elsevier, New York, 1968, pp. 256-265.
  • Turan, N., Ergin, Z., Şekerci, M., J. Chem. Soc. Pakistan., 32(5), 630-637, 2010.
  • Sönmez, M., Levent, A., Şekerci, M., Russian J. Coord. Chem., 30, 655-659, 2004.
  • Sırinivassan, R., Sougandi, I., Venkatesan, R., Sanbasiva, P., Pıroc Indian Acat. Sci. Chem., 115, 91, 2003.
  • Abu-El-Wafa, S.M., El-Wakiel, N.A., Issa, R.M., Mansour, R.A., J. Coord. Chem., 58(8), 683-694, 2005.
  • Chandra, R., Synth. React. Inorg. Met.-Org. Chem., 20, 645-659, 1990.
  • Maurya, R.C., Maurya, M.R., Rev. Inorg. Chem., 15, 1-107, 1995.
  • Chandraleka, S., Chandramohan, G., Saha, S., Dhanasekaran, D., Panneerselvam, A., Chandraleka S., et al, Drug Invention Today, 2(1), 8-12, 2010.
  • Turan, N., Sekerci, M., Heteroatom Chem., 21, 14-23, 2010.

BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ

Yıl 2013, Cilt: 1 Sayı: 1, 27 - 37, 01.06.2013

Nevin TURAN Turan Zuhal Karagöz Naki Çolak Hanifi Körkoca Memet Şekerci

Öz

3-Aminopropiltrimetoksisilan ve hidroksibenzaldehitin reaksiyonu sonucu diazenil grubu içeren 4-[(disiyanometil)diazenil]benzoikasit sentezlenerek yeni Pb(II), UO2(II), Cu(II), Ni(II), Co(II) ve Zn(II) kompleksleri sentezlendi. Ligand ve komplekslerin yapıları elemental analiz, UV-vis., IR, 1H-NMR, 13C-NMR, TGA, DTA ve magnetik ölçümler kullanılarak belirlendi. Co(II) ve Ni(II) kompleksler paramagnetik olup oktahedral, Zn(II) kompleksi diamagnetik olup oktahedral, Cu(II) kompleksi paramagnetic olup kare düzlem, UO2(II) ve Pb(II) kompleksler diamagnetic olup karedüzlem yapıya sahiptirler. Tüm komplekslerin antibakteriyel aktiviteleri Escherichia coli ATCC- 25922, Enterococcus faecalis ATCC 29212, Staphylococcus aureus ATCC 25923 ve Salmonella typhimurium CCM 583’e karşı testedildi. Test sonuçları değerlendirildi. Bu sonuçlardan sadece Ni(II) and Zn(II) komplekslerinin Staphylococcus aureus’un büyümesini inhibe ettiği görülmüştür.

Anahtar Kelimeler

Spektroskopi diazenil asetat tuzları termogravimetrik analiz kare düzlem antibacterial aktivite

Kaynakça

  • Zollinger, H., Color Chemistry: Syntheses, Properties, and Applications of Organic Dyes and Pigments, Weinheim, Wiley-VCH, 2003.
  • Groselj, U., Bevk, D., Jakse, R., Meden, A., Stanovnik, B., and Svete, J., Tetrahedron: Asymmetr, 16, 2927-2945, 2005.
  • Ersanlı, C.C., Albayrak, Ç., Odabaşoğlu, M., Kazak, C., Erdönmez, A., Acta Cryst., 60, 455-457, 2004.
  • Calino, S.C., Farris, R.E., Azo Dyes in Kirk-Olhmer Cnnci.se Erieydopaedia of Chemical Technology, cdilcd by M. Grayson, New York, John Wiley and Sons, 1985.
  • Gregory, R., Ctylorunts for High Technology. Colour Chemistry: The Design and Synthesis of Organic Dyes anti Pigments. Edited by A. T. Peters & H. S. Freeman, London/New York, 1991.
  • Antonov, L., Kawauchi, S.M., Satoh, Komiyama, J., Dyes Pigments, 40, 163-170, 1999.
  • Nevin, T., Esin, K., Bayram, G., Naki, Ç., Hanifi, K., Fiber Polym., 13(4), 415-424, 2012.
  • Amer, A.M., El-Bermaui, M.A., Ahmed, A.F.S., Soliman, S.M., Monatsh. Chem., 130, 1409-1418, 1999.
  • Jignesh, P.R., Purvesh, R.P., Nilesh, H.P., Pradip, S.P., Vasishta, D.B., Ketul, N.P., Int.l J. ChemTech Res., 1(3), 610-615, 2009.
  • Racane, L., Tralić-Kulenović, V., Karminski-Zamola, G., Fišer-Jakić, L., Monatsh Chem., 126, 1375-1381, 1995.
  • Carubelli, C.R., Massabni, A.M.G., de A. Leite, S.R., J. Braz. Chem. Soc., 8, 597, 1997.
  • Sener, A., Kasimogullari, R., Sener, M.K., Genc, H., Chem. Heterocycl. Comp., 40(8), 1039-1046, 2004.
  • Maurya, R.C., Patel, P., Rajput, S., Synth. React. Inorg. Met-Org. Chem., 33(5), 37 801–816, 2003.
  • Raman, N., Dhaveethu Raja, J., Sakthivel, A., J. Chem. Sci., 119(4), 303-310, 2007.
  • Lv, Q-Y., Lei, W-J., Liu, Y-L., Zhan, S-Z., Ye, J-S., Polyhedron, 29, 2780-2786, 2010.
  • Masoud, M.S., Amira, M.F., Ramadan, A.M. and El-Ashry, G.M., Spectrochim. Acta A., 69(1), 230, 2008.
  • Mohamed, G.G., Sharaby, C.M., Spectrochim. Acta Part A: Mol Biomol Spectros., 65(4-5), 949, 2007.
  • Hu, F., Yın, X., Lu, J., Mi, Y., Zhuang, J., Luo, W.J., Coord. Chem., 63(2), 263, 2010.
  • Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York, pp. 232, 1970.
  • Maurya, R.C., Jayaswal, M.N., Verma, R., Synth. React. Inorg. Met.-Org. Chem. 28, 1265-1281, 1998.
  • Dey, K., Bhowmick, R., Biswas, S., Koner, D., Synth. React. Inorg. Met-Org. Nan- Met. Chem., 35, 285-294, 2005.
  • Jouad, E.M., Riou, A., Allain, M., Khan, M.A., Bouet, G.M., Polyhedron, 20, 67, 2001.
  • Tuncel, M., Serin, S., Synth. React. Inorg. Met-Org. Nan-Met. Chem., 35, 203-212, 2005.
  • Lever, A.B.P., Inorganic Electronic Spectroscopy, 2nd Ed., Elsevier, New York, 1968, pp. 256-265.
  • Turan, N., Ergin, Z., Şekerci, M., J. Chem. Soc. Pakistan., 32(5), 630-637, 2010.
  • Sönmez, M., Levent, A., Şekerci, M., Russian J. Coord. Chem., 30, 655-659, 2004.
  • Sırinivassan, R., Sougandi, I., Venkatesan, R., Sanbasiva, P., Pıroc Indian Acat. Sci. Chem., 115, 91, 2003.
  • Abu-El-Wafa, S.M., El-Wakiel, N.A., Issa, R.M., Mansour, R.A., J. Coord. Chem., 58(8), 683-694, 2005.
  • Chandra, R., Synth. React. Inorg. Met.-Org. Chem., 20, 645-659, 1990.
  • Maurya, R.C., Maurya, M.R., Rev. Inorg. Chem., 15, 1-107, 1995.
  • Chandraleka, S., Chandramohan, G., Saha, S., Dhanasekaran, D., Panneerselvam, A., Chandraleka S., et al, Drug Invention Today, 2(1), 8-12, 2010.
  • Turan, N., Sekerci, M., Heteroatom Chem., 21, 14-23, 2010.
Toplam 32 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Araştırma Makalesi
Yazarlar

Nevin TURAN Turan

Zuhal Karagöz Bu kişi benim

Naki Çolak

Hanifi Körkoca

Memet Şekerci

Yayımlanma Tarihi 1 Haziran 2013
Yayımlandığı Sayı Yıl 2013 Cilt: 1 Sayı: 1

Kaynak Göster

APA Turan, N. T., Karagöz, Z., Çolak, N., Körkoca, H., vd. (2013). BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ. Muş Alparslan Üniversitesi Fen Bilimleri Dergisi, 1(1), 27-37. https://doi.org/10.18586/msufbd.69982
AMA Turan NT, Karagöz Z, Çolak N, Körkoca H, Şekerci M. BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ. MAUN Fen Bil. Dergi. Haziran 2013;1(1):27-37. doi:10.18586/msufbd.69982
Chicago Turan, Nevin TURAN, Zuhal Karagöz, Naki Çolak, Hanifi Körkoca, ve Memet Şekerci. “BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ”. Muş Alparslan Üniversitesi Fen Bilimleri Dergisi 1, sy. 1 (Haziran 2013): 27-37. https://doi.org/10.18586/msufbd.69982.
EndNote Turan NT, Karagöz Z, Çolak N, Körkoca H, Şekerci M (01 Haziran 2013) BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ. Muş Alparslan Üniversitesi Fen Bilimleri Dergisi 1 1 27–37.
IEEE N. T. Turan, Z. Karagöz, N. Çolak, H. Körkoca, ve M. Şekerci, “BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ”, MAUN Fen Bil. Dergi., c. 1, sy. 1, ss. 27–37, 2013, doi: 10.18586/msufbd.69982.
ISNAD Turan, Nevin TURAN vd. “BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ”. Muş Alparslan Üniversitesi Fen Bilimleri Dergisi 1/1 (Haziran 2013), 27-37. https://doi.org/10.18586/msufbd.69982.
JAMA Turan NT, Karagöz Z, Çolak N, Körkoca H, Şekerci M. BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ. MAUN Fen Bil. Dergi. 2013;1:27–37.
MLA Turan, Nevin TURAN vd. “BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ”. Muş Alparslan Üniversitesi Fen Bilimleri Dergisi, c. 1, sy. 1, 2013, ss. 27-37, doi:10.18586/msufbd.69982.
Vancouver Turan NT, Karagöz Z, Çolak N, Körkoca H, Şekerci M. BİR DİAZENİL LİGAND: 4-[(DİSİYANOMETİL)]BENZOİKASİT: İLE METAL ASETAT KOMPLEKSLERİNİN SPEKTROSKOPİK KARAKTERİZASYONU VE ANTİBAKTERİYAL AKTİVİTESİ. MAUN Fen Bil. Dergi. 2013;1(1):27-3.