Araştırma Makalesi
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DOĞAL KEMİK TOZLARI KULLANILARAK YER KAROLARININ AŞINMA DİRENCİNİN ARTIRILMASI

Yıl 2025, Cilt: 66 Sayı: 719, 293 - 312, 30.06.2025
https://doi.org/10.46399/muhendismakina.1726355

Öz

Seramik karoları sürekli basma ve aşınmaya maruz kalmaktadır. Seramik malzemeler gevrek bir özellik gösterdiğinden dolayı porselen karoların üstleri devamlı aşınmaya ve yüzey özelliklerinin bozulmasına neden olmaktadır. Porselen karo yüzeyinde gözlenen bu bozulmayı azaltmak amacıyla doğal hayvan kemikleri kullanılarak yer karosu sırlarının aşınma dirençlerinin arttırmaya yönelik bir çalışma yapılmıştır. Doğal hayvan kemiklerinin 38-45 mikron aralığında öğütülüp yer karosu sır reçetesine ağırlıkça %1-8 oranında ilave edilerek yer karosu sırlarına uygulanmıştır. Takviye edilen kemik tozları, sırın viskozitesinde önemli bir artışa neden olmazken daha mat bir görünüme neden olmaktadır. Bu numuneler 1070 oC’de sinterlenerek,, 2X2cm2 boyutlarında hazırlanıp mekanik aşınma özellikleri incelenmiştir.

Aşınma testleri bilya disk aşınma test cihazında, yağsız kuru ortamda ve oda sıcaklığında gerçekleştirilmiştir. Aşınma testleri 0.3 m/s kayma hızında, 5 N yük altında ve 50-100 metre uzunluğunda aşınması yapılarak gerçekleştirilmiştir. Aşınma dayanımları, kemik tozu içermeyen numunelere göre yaklaşık % 20 artmıştır. Aşınma test sonucunda aşınma yerlerinden alınan numunelerden taramalı elektron mikroskobu (SEM) ile mikro yapı özellikleri ve X-ışınları enerji dağılımlı spektroskopi (EDS) analizleri yapılmıştır. Kemik tozu katkıların yüzey bozulma değerleri, aşınma hacmi oranları Taylor-Hobson Rugosimeter Surtronic 25 cihazı ile ölçülmüştür. Aşınma testleri sonucunda % kemik tozu oranlarının artmasıyla porselen yer karosu sırların aşınmaya karşı dirençlerinin arttığı tespit edilmiştir.

Kaynakça

  • Acikbas, G., Calis Acikbas, N., Dizge, N., Belibagli, P. (2024) Multi-functional ceramic glazes with nano ZnO/Cu–ZnO incorporation Ceramics International Volume 50, Issue 21, Part C, 1 November, Pages 43800-43810, https://doi.org/10.1016/j.ceramint.2024.08.233
  • Alzahrani,A.S. (2022) A Review of Glass and Crystallizations of Glass-Ceramics Advances in Materials Physics and Chemistry Vol.12 No.11, November 2022 DOI: 10.4236/ampc.2022.1211018
  • Bao, Z., Wang, S., Miao, L., Xu, Y., Cheng, Z., Wang, X. (2024) Preparation, properties and formation mechanism of transparent anorthite-based glass-ceramic glaze with high hardness Ceramics International Volume 50, Issue 14, 15 July, Pages 26182-26192 https://doi.org/10.1016/j.ceramint.2024.04.359
  • Bolellia, G., Cannilloa, V., Lusvarghia, L., Manfredinia, T., Siligardia, C., Bartulib, C., Loretob, A., Valenteb, T. (2005). Plasma-sprayed glass-ceramic coatings on ceramic tiles: microstructure, chemical resistance and mechanical propertiesJournal of the European Ceramic Society 25 1835–1853, https://doi.org/10.1016/j.jeurceramsoc.2004.06.018
  • Cheng, X,, S.Ke, Q., Wang, H.Wang., A.Shui., P. Liu. (2012) Characterization of transparent glaze for single - crystalline anorthite porcelain, Ceramics International.38(6,) 4901- 4908 https://doi.org/10.1016/j.ceramint.2012.02.081
  • Cho, Y.S., Kim, H.K., Ghim, M.S., Hong, M.W., Kim, Y.Y., Cho, Y.S. (2020) Evaluation of the antibacterial activity and cell response for 3D-printed polycaprolactone/ nanohydroxyapatite scaffold with zinc oxide coating, Polymers 12 2193, https://doi.org/10.3390/polym12102193
  • Elmas, S., Tarhan, İ. (2019) The Effect of Combınatıon of Boric Acıd and Lithıum Carbonate on Sıntering And Mıcrostructure in Single Firing Wall Tile Journal of Scientific Perspectives Cilt: 3 Sayı: 2, 86 - 98, 30.04.2019 https://doi.org/10.26900/jsp.3.010
  • El-Raghy, T.P., Blau, M.W. (2000). Barsoum, Effect of grain size on friction and wear be-havior of Ti3SiC2, Wear 238 125–130,,http://dx.doi.org/10.1016/S0043-1648(99)00348-8. Esteban Tejeda, L., Malpartida, F., Esteban Cubillo, A., Pecharromán, C., Moya, J.S. (2009) Antibacterial and antifungal activity of a soda-lime glass containing copper nanoparticles Nanotechnology, p. 20, 10.1088/0957-4484/20/50/505701, DOI 10.1088/0957-4484/20/50/505701
  • Fortanet, E., Gabaldon, S., Bakali, J., Nunez, I., Perio, M., & Carda, J.B. (2006) Developing of new glass-ceramic glazes that improve anti slip properties, Qualicer P.BC, 56-59.
  • Fischer, T.H. (1990). Friction and Wear of Ceramics” Scripta Metalurgica et Materialia, V.24, pp: 833838, https://doi.org/10.1016/0956-716X(90)90121-V
  • Firas, A.F., Sulaiman, E., Kutty, G.K. (2018). Ceramics Application of zirconia surface coating to improve fracture resistance and stress distribution of zirconia ceramic restorations Ceramics International 44; 21633–21640 , https://doi.org/10.1016/j.ceramint.2018.08.246
  • Glease, W.A. (1995). Friction and Wear of Ceramics”, ASM Handbook, V. 18, pp: 812815,
  • Gunes, İ. (2013). Wear Behaviour of Plasma Paste Boronized of AISI 8620 Steel with Borax and B2O3 Paste Mixtures, Journal of Material Scientific Technol, 29, 662, https://doi.org/10.1016/j.jmst.2013.04.005
  • Hanxue, X., Wenqian, C., Yiting, C., Yang, H., Yuanjing, C., Guodong, Q. (2023) Preparation and characterization of enamel glaze containing metal oxide nanocrystals for antibacterial application, Journal of Non–Crystalline Solids Volume 619, 1 November 2023,122561 https://doi.org/10.1016/j.jnoncrysol.2023.122561
  • Kara, A., Stevens, R. (2002). Interactions between an ABS type leadless glaze and a biscuit fired bone china body during glost firing. Part I: preparation of experimental phases, J. Eur. Ceram. Soc. 22 (7) 1095–1102. DOI:10.1016/S0955-2219(01)00419-8
  • Li,Y.X., Zhao, P.X., Li, Q., Gong, Y.L., Zhang, C.B., Xu, Q., Liang, W.L., Leng, Y.X. (2024) Revealing the wear mechanisms of Mn-doped zirconia-toughened alumina ceramics in physiological solutions, Ceramics International, https://doi.org/10.1016/j.ceramint..11.308.
  • Liu, H., Chen, Q., Song, L., Ye, R., Lu, J., and Li, H. (2008).Ag–Doped Antibacterial Porous Materials with Slow Release of Silver Ions, Journal of Non–Crystalline Solids, 354 (12–13), 1314–1317, https://doi.org/10.1016/j.jnoncrysol.2007.02.098
  • Oku, T., Shigeru, T. (2009) Antibacterial Mildewproof Glaze Composition for Ceramic Products, Patent US7250178B2. 2015.Nanotechnology 20, https://doi.org/10.1088/0957-4484/ 20/50/505701.
  • Pei, X., Du, Y., Wang, H., Hu, M., Li, Y., Zhou, W., Wang, H. (2024) Attaining exceptional wear resistance in an in-situ ceramic phase reinforced NbMoWTa refractory high entropy alloy composite by Spark plasma sintering Wear Volumes 558–559, 15 December, 205572 https://doi.org/10.1016/j.wear.2024.205572
  • Rasteiro, M.G., Gassman, T., Santos, R., & Auntes, E. (2006) Crystalline phase characterization of glass - ceramic glazes, Ceramic International (33) 345 -354 https://doi.org/10.1016/j.ceramint.2005.10.002
  • Reinosa, J.J., Enríquez, E., Fuertes, V., Liu, S., Men´endez, J., Fernandez, J.F. (2022) The challenge of antimicrobial glazed ceramic surfaces Ceramics International Volume 48, Issue 6, 15 March Pages 7393-7404,https://doi.org/10.1016/j.ceramint.2021.12.121
  • Stoimenov, P. K., Klinger, R. L., Marchin, G. L., and Klabunde, K. J. (2002) Metal Oxide Nanoparticles as Bactericidal Agents, ACS Publications Langmuir, 18 (17),6679−6686. http://dx.doi.org/10.1021/la0202374
  • Yangzi, L,, Sijia, S., Hao D., Zhang, H., Zhang, Ha., Li, W. (2024) Preparation of TiO2–SiO2–CaCO3 composite opacifier by hydrophobic agglomeration and mechanism of inhibiting glaze yellowing Ceramics International volume 50, ıssue 13, part b,1 july pages 24195 - 24204, https://doi.org/10.1016/j.ceramint.2024.04.151
  • Yekta, B. E., Alizadeh, P., & Rezazadeh L. (2006) Floor tile glass- ceramic glaze for improvement of glaze surface properties, Journal of European Ceramic Society (5918), 1-2. https://doi.org/10.1016/J.JEURCERAMSOC.2005.12.016

INCREASİNG THE ABRASİON RESİSTANCE OF FLOOR TİLES BY USİNG NATURAL BONE POWDERS

Yıl 2025, Cilt: 66 Sayı: 719, 293 - 312, 30.06.2025
https://doi.org/10.46399/muhendismakina.1726355

Öz

Ceramic tiles are subjected to constant compression and abrasion. Since ceramic materials are brittle, the surfaces of porcelain tiles are subject to continuous abrasion and deterioration of surface properties. In order to reduce this deterioration observed on the porcelain tile surface, a study was conducted to increase the abrasion resistance of floor tile glazes using natural animal bones. Natural animal bones were ground in the range of 38-45 microns and added to the floor tile glaze recipe at a rate of 1-8% by weight and applied to floor tile glazes. While the reinforced bone powders do not cause a significant increase in the viscosity of the glaze, they cause a more matte appearance. These samples were sintered at 1070 oC, prepared in 2X2cm2 sizes and their mechanical wear properties were investigated.

Abrasion tests were carried out on a ball disc abrasion tester in a dry environment without oil and at room temperature. Abrasion tests were carried out at a sliding speed of 0.3 m/s, under a load of 5 N and 50-100 meters in length. The abrasion resistance increased by about 20% compared to the specimens without bone dust. As a result of the abrasion test, microstructure properties were analyzed by scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS). Surface distortion values and wear volume ratios of bone powder additives were measured with Taylor-Hobson Rugosimeter Surtronic 25 device. As a result of the destructive tests, It was found that the resistance to abrasion of porcelain floor tile glazes increased with the increase in bone dust content.

Destekleyen Kurum

Support: In our study, floor tiles and glaze preparation unit Umpaş Seramik Sanayi ve Ticaret A Ş. It was obtained from the enterprises.

Kaynakça

  • Acikbas, G., Calis Acikbas, N., Dizge, N., Belibagli, P. (2024) Multi-functional ceramic glazes with nano ZnO/Cu–ZnO incorporation Ceramics International Volume 50, Issue 21, Part C, 1 November, Pages 43800-43810, https://doi.org/10.1016/j.ceramint.2024.08.233
  • Alzahrani,A.S. (2022) A Review of Glass and Crystallizations of Glass-Ceramics Advances in Materials Physics and Chemistry Vol.12 No.11, November 2022 DOI: 10.4236/ampc.2022.1211018
  • Bao, Z., Wang, S., Miao, L., Xu, Y., Cheng, Z., Wang, X. (2024) Preparation, properties and formation mechanism of transparent anorthite-based glass-ceramic glaze with high hardness Ceramics International Volume 50, Issue 14, 15 July, Pages 26182-26192 https://doi.org/10.1016/j.ceramint.2024.04.359
  • Bolellia, G., Cannilloa, V., Lusvarghia, L., Manfredinia, T., Siligardia, C., Bartulib, C., Loretob, A., Valenteb, T. (2005). Plasma-sprayed glass-ceramic coatings on ceramic tiles: microstructure, chemical resistance and mechanical propertiesJournal of the European Ceramic Society 25 1835–1853, https://doi.org/10.1016/j.jeurceramsoc.2004.06.018
  • Cheng, X,, S.Ke, Q., Wang, H.Wang., A.Shui., P. Liu. (2012) Characterization of transparent glaze for single - crystalline anorthite porcelain, Ceramics International.38(6,) 4901- 4908 https://doi.org/10.1016/j.ceramint.2012.02.081
  • Cho, Y.S., Kim, H.K., Ghim, M.S., Hong, M.W., Kim, Y.Y., Cho, Y.S. (2020) Evaluation of the antibacterial activity and cell response for 3D-printed polycaprolactone/ nanohydroxyapatite scaffold with zinc oxide coating, Polymers 12 2193, https://doi.org/10.3390/polym12102193
  • Elmas, S., Tarhan, İ. (2019) The Effect of Combınatıon of Boric Acıd and Lithıum Carbonate on Sıntering And Mıcrostructure in Single Firing Wall Tile Journal of Scientific Perspectives Cilt: 3 Sayı: 2, 86 - 98, 30.04.2019 https://doi.org/10.26900/jsp.3.010
  • El-Raghy, T.P., Blau, M.W. (2000). Barsoum, Effect of grain size on friction and wear be-havior of Ti3SiC2, Wear 238 125–130,,http://dx.doi.org/10.1016/S0043-1648(99)00348-8. Esteban Tejeda, L., Malpartida, F., Esteban Cubillo, A., Pecharromán, C., Moya, J.S. (2009) Antibacterial and antifungal activity of a soda-lime glass containing copper nanoparticles Nanotechnology, p. 20, 10.1088/0957-4484/20/50/505701, DOI 10.1088/0957-4484/20/50/505701
  • Fortanet, E., Gabaldon, S., Bakali, J., Nunez, I., Perio, M., & Carda, J.B. (2006) Developing of new glass-ceramic glazes that improve anti slip properties, Qualicer P.BC, 56-59.
  • Fischer, T.H. (1990). Friction and Wear of Ceramics” Scripta Metalurgica et Materialia, V.24, pp: 833838, https://doi.org/10.1016/0956-716X(90)90121-V
  • Firas, A.F., Sulaiman, E., Kutty, G.K. (2018). Ceramics Application of zirconia surface coating to improve fracture resistance and stress distribution of zirconia ceramic restorations Ceramics International 44; 21633–21640 , https://doi.org/10.1016/j.ceramint.2018.08.246
  • Glease, W.A. (1995). Friction and Wear of Ceramics”, ASM Handbook, V. 18, pp: 812815,
  • Gunes, İ. (2013). Wear Behaviour of Plasma Paste Boronized of AISI 8620 Steel with Borax and B2O3 Paste Mixtures, Journal of Material Scientific Technol, 29, 662, https://doi.org/10.1016/j.jmst.2013.04.005
  • Hanxue, X., Wenqian, C., Yiting, C., Yang, H., Yuanjing, C., Guodong, Q. (2023) Preparation and characterization of enamel glaze containing metal oxide nanocrystals for antibacterial application, Journal of Non–Crystalline Solids Volume 619, 1 November 2023,122561 https://doi.org/10.1016/j.jnoncrysol.2023.122561
  • Kara, A., Stevens, R. (2002). Interactions between an ABS type leadless glaze and a biscuit fired bone china body during glost firing. Part I: preparation of experimental phases, J. Eur. Ceram. Soc. 22 (7) 1095–1102. DOI:10.1016/S0955-2219(01)00419-8
  • Li,Y.X., Zhao, P.X., Li, Q., Gong, Y.L., Zhang, C.B., Xu, Q., Liang, W.L., Leng, Y.X. (2024) Revealing the wear mechanisms of Mn-doped zirconia-toughened alumina ceramics in physiological solutions, Ceramics International, https://doi.org/10.1016/j.ceramint..11.308.
  • Liu, H., Chen, Q., Song, L., Ye, R., Lu, J., and Li, H. (2008).Ag–Doped Antibacterial Porous Materials with Slow Release of Silver Ions, Journal of Non–Crystalline Solids, 354 (12–13), 1314–1317, https://doi.org/10.1016/j.jnoncrysol.2007.02.098
  • Oku, T., Shigeru, T. (2009) Antibacterial Mildewproof Glaze Composition for Ceramic Products, Patent US7250178B2. 2015.Nanotechnology 20, https://doi.org/10.1088/0957-4484/ 20/50/505701.
  • Pei, X., Du, Y., Wang, H., Hu, M., Li, Y., Zhou, W., Wang, H. (2024) Attaining exceptional wear resistance in an in-situ ceramic phase reinforced NbMoWTa refractory high entropy alloy composite by Spark plasma sintering Wear Volumes 558–559, 15 December, 205572 https://doi.org/10.1016/j.wear.2024.205572
  • Rasteiro, M.G., Gassman, T., Santos, R., & Auntes, E. (2006) Crystalline phase characterization of glass - ceramic glazes, Ceramic International (33) 345 -354 https://doi.org/10.1016/j.ceramint.2005.10.002
  • Reinosa, J.J., Enríquez, E., Fuertes, V., Liu, S., Men´endez, J., Fernandez, J.F. (2022) The challenge of antimicrobial glazed ceramic surfaces Ceramics International Volume 48, Issue 6, 15 March Pages 7393-7404,https://doi.org/10.1016/j.ceramint.2021.12.121
  • Stoimenov, P. K., Klinger, R. L., Marchin, G. L., and Klabunde, K. J. (2002) Metal Oxide Nanoparticles as Bactericidal Agents, ACS Publications Langmuir, 18 (17),6679−6686. http://dx.doi.org/10.1021/la0202374
  • Yangzi, L,, Sijia, S., Hao D., Zhang, H., Zhang, Ha., Li, W. (2024) Preparation of TiO2–SiO2–CaCO3 composite opacifier by hydrophobic agglomeration and mechanism of inhibiting glaze yellowing Ceramics International volume 50, ıssue 13, part b,1 july pages 24195 - 24204, https://doi.org/10.1016/j.ceramint.2024.04.151
  • Yekta, B. E., Alizadeh, P., & Rezazadeh L. (2006) Floor tile glass- ceramic glaze for improvement of glaze surface properties, Journal of European Ceramic Society (5918), 1-2. https://doi.org/10.1016/J.JEURCERAMSOC.2005.12.016
Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Makine Mühendisliği (Diğer)
Bölüm Araştırma Makalesi
Yazarlar

Yavuz Ergün 0000-0001-5883-2078

Erken Görünüm Tarihi 30 Haziran 2025
Yayımlanma Tarihi 30 Haziran 2025
Gönderilme Tarihi 25 Temmuz 2024
Kabul Tarihi 7 Şubat 2025
Yayımlandığı Sayı Yıl 2025 Cilt: 66 Sayı: 719

Kaynak Göster

APA Ergün, Y. (2025). INCREASİNG THE ABRASİON RESİSTANCE OF FLOOR TİLES BY USİNG NATURAL BONE POWDERS. Mühendis ve Makina, 66(719), 293-312. https://doi.org/10.46399/muhendismakina.1726355

Derginin DergiPark'a aktarımı devam ettiğinden arşiv sayılarına https://www.mmo.org.tr/muhendismakina adresinden erişebilirsiniz.

ISSN : 1300-3402

E-ISSN : 2667-7520